Process for the obtainment of a polyolefin composition

Patent metadata

Field	Value
Publication number	US-9738778-B2
Application number	US-201314407204-A
Country	US
Kind code	B2
Filing date	Jun 19, 2013
Priority date	Jun 19, 2012
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

A two steps polymerization process for obtaining a polyolefin composition comprising:
a) from 25 wt % to 70 wt % of a propylene homopolymer or a propylene-ethylene copolymer containing from 0.1 wt % to 10 wt % of ethylene derived units; b) from 27 wt % to 70 wt % of a copolymer of ethylene and at least one C 3 -C 20 alpha olefins, wherein the ethylene derived units content ranges from 15 wt % to 70 wt %; c) from 3 wt % to 20 wt % of polyethylene homopolymer or an ethylene and at least one C 3 -C 20 alpha olefins copolymer; the sum a)+b)+c) being 100, wherein said process comprises: step a) contacting under polymerization conditions propylene, optionally ethylene and the catalyst system in order to obtain component a), step b) contacting under polymerization conditions ethylene and at least one C3-C20 alpha-olefins and the catalyst system in order to obtain components b) and c); wherein the catalyst system comprises a metallocene compound and an iron complex.

First claim

What is claimed is:

1. A process for obtaining a polyolefin composition comprising:
A) contacting in a first polymerization step comprising a pressurized reactor propylene and optionally ethylene optionally in gas phase and a catalyst system to obtain an overall content of a first component (a) ranging from 25-70 wt %, based on the total wt % of the polyolefin composition, wherein the first component (a) is a propylene homopolymer, or a propylene-ethylene copolymer comprising 0.1-10 wt % of ethylene;
B) further contacting in a second polymerization step comprising the pressurized reactor of step A) ethylene and at least one C 3 -C 20 alpha olefin optionally in gas phase and the catalyst system to obtain an overall content of a second component (b) ranging from 27-70 wt %, based on the total wt % of the polyolefin composition, wherein the second component (b) is an ethylene copolymer comprising 15-70 wt % ethylene and at least one C 3 -C 20 alpha-olefin, and an overall content of a third component (c) ranging from 3-20 wt %, based on the total wt % of the polyolefin composition, wherein the third component (c) is polyethylene homopolymer or copolymer comprising 95-99.9 wt % ethylene and at least one C 3 -C 20 alpha-olefin, wherein the at least one C 3 -C 20 alpha-olefin comonomer is the same used in component b) to form a polyolefin composition; and
C) discharging the polyolefin composition:
wherein the catalyst system comprises:
i) a metallocene compound of the general formula (I):

wherein M is selected from the group consisting of titanium, zirconium and hafnium;
X, whether the same or different, is selected from the group consisting of hydrogen, a halide, an —R, —OR, —SO 3 CF 3 , —CO 2 R, —SR, —NR 2 and —PR 2 group, wherein R is selected from the group consisting of a linear or branched, cyclic or acyclic, C 1 -C 40 alkyl, C 2 -C 40 alkenyl, C 2 -C 40 alkynyl, C 6 -C 40 alkylaryl and C 7 -C 40 alkylaryl and C 7 -C 40 arylalkyl radicals; optionally comprising heteroatoms from Groups 13-17 of the Periodic Table of Elements;
R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 , equal to or different from each other, are selected from the group consisting of hydrogen and C 1 -C 40 hydrocarbon radicals optionally comprising heteroatoms from Groups 13-17 of the Periodic Table of Elements; or two or more groups between R 1 , R 2 , R 3 , R 4 , R 5 and R 6 can be fused to form a saturated or unsaturated, 5- or 6-membered rings and optionally comprise C 1 -C 20 alkyl radical substituents;
ii) at least one iron complex of the general formula (II):

wherein the radical X 1 is selected from the group consisting of hydrogen, a halide, —R, —OR, —SO 3 CF 3 , —CO 2 , —SR, —NR 2 and —PR2 groups, wherein R is selected from a linear, branched, saturated and/or unsaturated C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 alkylaryl and C7-C20 arylalkyl radical, optionally containing heteroatoms from Groups 13-17 of the Periodic Table of Elements; or X 1 can optionally form a substituted or unsubstituted butadienyl radical or an OR′O group, wherein R′ is a divalent radical selected from C 1 -C 20 alkylidene, C 6 -C 40 arylidene, C 7 -C 40 alkylarylidene and C 7 -C 40 arylalkylidene radicals;
D is an uncharged donor; s is 1, 2, 3 or 4,
t ranges from 0 to 4;
R 8 , equal to or different from each other, are selected from the group consisting of hydrogen and C 1 -C 40 hydrocarbon radicals optionally containing heteroatoms belonging to Groups 13-17 of the Periodic Table of Elements;
R 10 , equal to or different from each other, are selected from the group consisting of hydrogen and C 1 -C 40 hydrocarbon radicals optionally containing heteroatoms belonging to Groups 13-17 of the Periodic Table of Elements;
R9, equal to or different from each other, are selected from the group consisting of hydrogen and C 1 -C 40 hydrocarbon radicals optionally containing heteroatoms belonging to Groups 13-17 of the Periodic Table of Elements; and
iii) an alumoxane or a compound capable of forming an alkyl cation with complexes of formula (I) and (II).

2. The polymerization process of claim 1 , wherein the compound of formula (I) has the general formula (Ia):

wherein M, X, R 1 , R 2 , R 4 , R 5 , R 6 and R 7 are defined in claim 1 and R 1a has the general formula (III):

wherein the symbol * marks the bound with the cyclopentadienyl moiety; R13,equal to or different from each other, is a C 1 -C 15 hydrocarbon radical optionally containing heteroatoms belonging to Groups 13-17 of the Periodic Table of Elements;
R 14 is selected from the group consisting of hydrogen and a C 1 -C 15 hydrocarbon radical optionally containing heteroatoms belonging to Groups 13-17 of the Periodic Table of Elements; and
R 11 and R12, equal to or different from each other, are selected from the group consisting of hydrogen and C 1 -C 10 hydrocarbon radicals optionally containing heteroatoms belonging to Groups 13-17 of the Periodic Table of Elements.

3. The polymerization process of claim 1 , wherein the compound of formula (I) has the general formula (Ib):

wherein M, X, R 1 , R 1a , R 7 and R 12 are defined in claims 1 and 2, and R 13 , equal to or different from each other, is selected from the group consisting of hydrogen and a C 1 -C 10 hydrocarbon radical.

4. The polymerization process of claim 1 , wherein the catalyst system is supported on an inert carrier.

5. The polymerization process of claim 1 , wherein the molar ratio of the metallocene compound of formula (I) and the iron complex of formula (II) ranges from 3:1 to 50:1.

6. The polymerization process of claim 1 , wherein the polyolefin composition comprises:
a) 30-50 wt % of a propylene homopolymer;
b) 40-65 wt % of an ethylene/propylene copolymer, wherein the ethylene content ranges from 20-65 wt %; and
c) 3-7 wt % of a polyethylene homopolymer;
wherein the sum of a)+b)+c) is 100 wt %.

7. The polymerization process of claim 6 , wherein the polyolefin composition comprises a polyolefin blend.

8. The polymerization process of claim 6 , wherein the polyolefin composition comprises an extruded article.

9. The polymerization process of claim 8 , wherein the extruded article is selected from the group consisting of a film, a pipe, a fiber and a sheet.

10. The polymerization process of claim 6 , wherein the polyolefin composition comprises a molded article.

11. The polymerization process of claim 6 , wherein the polyolefin composition comprises a thermoformed article.

12. The polymerization process of claim 10 , wherein the molded article is selected from the group consisting of an automotive part, a bumper, a battery case and a container.

Assignees

• Basell Polyolefine Gmbh

Inventors

• Fantinel Fabiana
• Richter Bodo
• Mihan Shahram
• Covezzi Massimo
• Cavalieri Claudio
• Grazzi Michele

Classifications

• C08F2500/21

  Rubbery or elastomeric properties · CPC title

• C08L2314/06

  Metallocene or single site catalysts · CPC title

• Y10T428/139

  Open-ended, self-supporting conduit, cylinder, or tube-type article · CPC title

• C08F2500/17

  Viscosity · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title