Aqueous cleaning composition with tertiary amine ionic liquid and quaternary ammonium antimicrobial surfactant

Patent metadata

Field	Value
Publication number	US-10808204-B2
Application number	US-201716342360-A
Country	US
Kind code	B2
Filing date	Oct 17, 2017
Priority date	Oct 26, 2016
Publication date	Oct 20, 2020
Grant date	Oct 20, 2020

Abstract

An aqueous cleaning composition, which may be suitable for use in cleaning hard surfaces, is described. The aqueous cleaning composition includes an N,N-dialkyl-N-aliphatic ammonium hydroxycarboxylate salt, a nonionic surfactant and/or anionic surfactant and a substantial amount of water. Other than an optional fragrance component, the cleaning composition is substantially free of volatile organic compounds. The cleaning compositions may also include a disinfecting quaternary surfactant and/or a chelating agent, such as an aminopolycarboxylate chelating agent.

First claim

What is claimed is:

1. An aqueous cleaning composition comprising:
(a) N,N-dialkyl-N-aliphatic ammonium hydroxy carboxylate salt;
(b) nonionic surfactant and anionic surfactant; and
(c) at least about 85 wt. % water;
wherein other than an optional fragrance component the composition contains no more than 0.1 wt. % volatile organic compounds.

2. The composition of claim 1 , wherein the composition has a pH of about 4 to 7.

3. The composition of claim 1 , wherein the nonionic surfactant comprises ethoxylated alkanol and/or alkyldimethylamine oxide.

4. The composition of claim 1 , wherein the anionic surfactant comprises alkyl sulfate salt and/or alkyl sulfonate salt.

5. The composition of claim 1 , further comprising antimicrobial quaternary ammonium surfactant.

6. The aqueous cleaning composition of claim 1 comprising:
(a) about 0.05 to 5 wt. % N,N-dimethyl-N-n-decylammonium citrate;
(b) about 0.5 to 5 wt. % sodium octyl sulfate;
(c) about 0.5 to 5 wt. % ethoxylated C 10-15 -alkanol having an average degree of ethoxylation of about 5 to 10; and
(d) at least about 90 wt. % water;
wherein the composition has a pH of about 4 to 6.

7. The composition of claim 6 , further comprising about 0.1 to 0.5 wt. % iminodisuccinate salt.

8. The composition of claim 1 , further comprising an aminopolycarboxylate chelating agent selected from the group consisting of an iminodisuccinate salt (IDSA), an ethylenediaminetetraacetate (EDTA) salt, a hydroxyethylethylenediaminetriacetate (HEEDTA) salt, 2-hydroxyethyliminodiacetate (HEIDA) salt, a nitrilotriacetate (NTA) salt, a glutamate diacetic acid (GDAA) salt, a diethylenetriaminepentaacetic acid (DETAPA) salt, a triethylenetetraminehexaacetic acid (TETAHA) salt, a 1,3-diamino-2-hydroxypropane-N,N,N′,N′-tetraacetic acid salt and/or a 1,2-diaminocyclohexane-N,N,N′,N′-tetraacetic acid salt.

9. The composition of claim 1 , further comprising an aminopolycarboxylate chelating agent, which comprises a sodium iminodisuccinate salt and/or a sodium glutamate diacetic acid salt.

10. The composition of claim 1 , wherein the N,N-dialkyl-N-aliphatic ammonium hydroxy carboxylate salt comprises N,N-di-(C 1-3 )alkyl-N—(C 8-18 )—N-aliphatic ammonium hydroxy carboxylate salt.

11. The aqueous cleaning composition of claim 1 comprising:
(a) about 0.05 to 3 wt. % N,N-dimethyl-N—C 8-12 -alkylammonium citrate;
(b) about 0.5 to 3 wt. % sodium C 6-10 -alkyl sulfate;
(c) about 0.5 to 3 wt. % ethoxylated C 10-15 -alkanol; and
(d) at least about 90 wt. % water;
wherein the composition has a pH of about 4 to 7 and, other than an optional fragrance component, the composition contains no more than 0.1 wt. % volatile organic compounds.

12. An aqueous cleaning composition comprising:
(a) N,N-dialkyl-N—C 8-14 -fatty alkylammonium hydroxy carboxylate salt;
(b) ethoxylated alkanol and/or alkyldimethylamine oxide;
(c) alkyl sulfate salt and/or alkyl sulfonate salt; and
(d) at least about 85 wt. % water;
wherein, other than an optional fragrance component, the composition is substantially free of glycol ether solvents, aliphatic alcohol solvents, polyol solvents and amino alcohol solvents.

13. The composition of claim 12 , further comprising one or more of antimicrobial quaternary ammonium surfactant, fragrance material, aminopolycarboxylate chelating agent and preservative.

14. The composition of claim 12 , wherein the N,N-dialkyl-N—C 8-14 -fatty alkylammonium hydroxy carboxylate salt is selected from the group consisting of N-octyl dimonium citrate, N-decyl dimonium citrate, N-lauryl dimonium citrate, N-myristyl dimonium citrate, N,N-dimethyl-N-n-octyl ammonium lactate, N,N-dimethyl-N-n-decyl ammonium lactate, N,N-dimethyl-N-lauryl ammonium lactate and/or N,N-dimethyl-N-myristyl ammonium lactate.

15. An aqueous cleaning composition comprising:
(a) about 1 to 4 wt. % N,N-dimethyl-N-n-decylammonium citrate;
(b) about 1 to 4 wt. % C 8-12 -alkyl sulfate salt; and
(c) at least about 90 wt. % water;
wherein the composition has a pH of about 4 to 6 and, other than an optional fragrance component, the composition contains no more than 0.1 wt. % volatile organic compounds.

16. The composition of claim 15 , further comprising an ethoxylated C 10-15 -alkanol.

17. The composition of claim 15 , further comprising a sodium iminodisuccinate salt and/or a sodium glutamate diacetic acid salt.

18. The composition of claim 15 , further comprising an antimicrobial quaternary ammonium surfactant, which comprises a quaternary benzyl ammonium salt and/or a quaternary bis(alkyl)dimethylammonium salt.

19. The composition of claim 15 , further comprising about 1 to 3 wt. % of an ethoxylated C 10-15 -alkanol having an average degree of ethoxylation of about 5 to 10;
about 0.1 to 5 wt. % of an aminopolycarboxylate chelating agent, which comprises a sodium iminodisuccinate salt and/or a sodium glutamate diacetic acid salt; and
about 0.1 to 0.4 wt. % of an antimicrobial quaternary ammonium surfactant.

20. The composition of claim 15 , further comprising polycarboxylate chelating agent.

21. The composition of claim 1 , wherein the N,N-dialkyl-N-aliphatic ammonium hydroxy carboxylate salt comprises N,N-dimethyl-N—(C 8-14 )-n-alkyl ammonium citrate;
the nonionic and/or anionic surfactant comprises ethoxylated C 10-15 -alkanol nonionic surfactant and C 6-10 -alkyl sulfate anionic surfactant; and
the composition further comprises polycarboxylate chelating agent.

Assignees

• Johnson & Son Inc S C

Inventors

• Flugge-Berendes Lisa Ann
• Sutton Jr Art Daniels
• Haas Michael Scott

Classifications

• C11D1/65

  Mixtures of anionic with cationic compounds · CPC title

• C11D1/835

  Mixtures of non-ionic with cationic compounds · CPC title

• C11D1/72

  Ethers of polyoxyalkylene glycols · CPC title

• C11D1/143

  Sulfonic acid esters · CPC title

• C11D1/86 Primary

  Mixtures of anionic, cationic, and non-ionic compounds · CPC title