Cleaning composition with a polypropdxylated 2-(trialkylammonio)ethanol ionic liquid

Patent metadata

Field	Value
Publication number	US-9920284-B2
Application number	US-201615095907-A
Country	US
Kind code	B2
Filing date	Apr 11, 2016
Priority date	Apr 22, 2015
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

An aqueous cleaning composition, which may be suitable for use in cleaning hard surfaces, is described. The aqueous cleaning composition includes an ionic liquid solvent, an amino alcohol, and a substantial amount of water. The cleaning compositions may also include a disinfecting quaternary surfactant, a nonionic surfactant, such as an ethoxylated alcohol and/or alkyl polyglycoside, and/or a chelating agent, such as an aminopolycarboxylate chelating agent.

First claim

What is claimed is:

1. An aqueous cleaning composition comprising:
(a) an ionic liquid, which is a polypropoxylated 2-(trialkylammonio)ethanol salt;
(b) an amino alcohol;
(c) a component selected from the group consisting of a quaternary benzyl ammonium surfactant, a nonionic surfactant, an aminopolycarboxylate chelating agent, or mixtures thereof; and
(d) at least about 50 wt. % water.

2. The composition of claim 1 , wherein other than the amino alcohol, the composition is substantially free of volatile organic compounds.

3. The composition of claim 1 , wherein
(a) the polypropoxylated 2-(trialkylammonio)ethanol salt comprises a polypropoxylated 2-(diethylmethylammonio)ethanol halide salt;
(b) the amino alcohol is selected from diisopropanolamine, isopropanolamine, triethanolamine, diethanolamine and/or monoethanolamine; and
the composition comprises the quaternary benzyl ammonium surfactant and the nonionic surfactant.

4. The composition of claim 1 wherein the polypropoxylated 2-(trialkylammonio)ethanol salt comprises a polypropoxylated 2-(diethylmethylammonio)ethanol chloride salt;
the amino alcohol comprises diisopropanolamine and/or monoethanolamine;
the quaternary benzyl ammonium surfactant comprises N-n-C 12-14 -alkyl-N,N-dimethyl benzyl ammonium chloride and/or N-n-C 12-14 -alkyl-N,N-dimethyl ethylbenzyl ammonium chloride; and
the nonionic surfactant comprises a polyethylene glycol ether of a C 8-12 -Guerbet alcohol and/or ethoxylated C 10-15 -fatty alcohol.

5. The composition of claim 1 , wherein polypropoxylated 2-(trialkylammonio)ethanol salt comprises a polypropoxylated 2-(diethylmethylammonio)ethanol chloride.

6. The composition of claim 1 , wherein the aminopolycarboxylate chelating agent is selected from the group consisting of an iminodisuccinate salt, an ethylenediaminetetraacetate (EDTA) salt, a hydroxyethylethylenediaminetriacetate (HEEDTA) salt, 2-hydroxyethyliminodiacetate (HEIDA) salt, a nitrilotriacetate (NTA) salt, or mixtures thereof.

7. An aqueous cleaning concentrate comprising:
(a) about 3-15 wt. % of an ionic liquid, which is a polypropoxylated 2-(trialkylammonio)ethanol salt;
(b) about 3-15 wt. % of an amino alcohol;
(c) a disinfecting quaternary ammonium surfactant;
(d) a nonionic surfactant;
(e) an aminopolycarboxylate chelating agent; and
(f) at least about 50 wt. % water.

8. The composition of claim 1 , wherein the composition contains the aminopolycarboxylate chelating agent; and at least about 85 wt. % water;
wherein other than the amino alcohol component and an optional fragrance component, the composition is substantially free of volatile organic compounds.

9. The composition of claim 1 , wherein the composition comprises about 0.05-3 wt. % of the polypropoxylated 2-(trialkylammonio)ethanol salt; and about 0.05-5 wt. % of the amino alcohol.

10. The composition of claim 7 , wherein the nonionic surfactant comprises ethoxylated C 10-15 linear or branched aliphatic alcohol.

11. An aqueous cleaning composition comprising:
(a) an ionic liquid, which comprises a polypropoxylated 2-(trialkylammonio)ethanol salt;
(b) an amino alcohol;
(c) a disinfecting quaternary ammonium surfactant;
(d) a nonionic surfactant;
(e) an aminopolycarboxylate chelating agent; and
(f) at least about 85 wt. % water.

12. The composition of claim 7 , wherein the nonionic surfactant comprises ethoxylated C 10-15 -fatty alcohol and/or polyethylene glycol ether of a C 8-12 -Guerbet alcohol.

13. An aqueous cleaning composition comprising:
(a) about 0.05-3 wt. % of a polypropoxylated 2-(trialkylammonio)ethanol salt which includes a polypropoxylated 2-(diethylmethylammonio)ethanol salt;
(b) about 0.05-5 wt. % of an amino alcohol which includes diisopropanolamine;
(c) a disinfecting quaternary ammonium surfactant, which includes N-n-C12-14-alkyl-N,N-dimethyl benzyl ammonium chloride;
(d) a nonionic surfactant, which includes an ethoxylated (C10-C15) linear and/or branched aliphatic alcohol;
(e) an aminopolycarboxylate chelating agent, which includes an iminodisuccinate salt;
(f) at least about 85 wt. % water;
wherein other than the amino alcohol component and an optional fragrance component, the composition is substantially free of volatile organic compounds.

14. The composition of claim 7 , wherein the nonionic surfactant comprises an ethoxylated alcohol nonionic surfactant and the disinfecting quaternary ammonium surfactant comprises a disinfecting quaternary benzyl ammonium surfactant.

15. The composition of claim 7 , wherein polypropoxylated 2-(trialkilammonio)ethanol salt comprises a polypropoxylated 2-(diethylmethylammonio)ethanol chloride and/or methosulfate salt.

16. The composition of claim 15 , wherein the aminopolycarboxylate chelating agent comprises iminodisuccinate salt; the nonionic surfactant comprises ethoxylated (C 10 -C 15 ) linear and/or branched aliphatic alcohol; and the disinfecting quaternary ammonium surfactant comprises N-n-C 12-14 -alkyl-N,N-dimethyl benzyl ammonium chloride.

17. The composition of claim 7 , wherein the aminopolycarboxylate chelating agent comprises iminodisuccinate salt.

18. The composition of claim 1 , comprising about 0.1-3 wt. % of the polypropoxylated 2-(trialkylammonio)ethanol salt; about 0.1-4 wt. % of the amino alcohol; at least about 90 wt. % water; about 0.1-2 wt. % ethoxylated alcohol nonionic surfactant and about 0.1-0.4 wt. % quaternary benzyl ammonium surfactant.

19. The composition of claim 18 , further comprising an aminopolycarboxylate chelating agent; wherein the composition includes no more than about 0.2 wt. % of the aminopolycarboxylate chelating agent.

20. The composition of claim 18 , wherein the ethoxylated alcohol nonionic surfactant comprises ethoxylated (C 10 -C 15 ) linear and/or branched aliphatic alcohol; and quaternary benzyl ammonium surfactant comprises N-alkyl-N,N-dimethyl benzyl ammonium salt and/or N-alkyl-N,N-dimethyl ethylbenzyl ammonium salt.

21. The composition of claim 7 , wherein the polypropoxylated 2-(trialkylammonio)ethanol salt comprises 2-(diethylmethylammonio)ethanol chloride and/or alkylsulfate salt; the amino alcohol comprises diisopropanolamine; the nonionic surfactant comprises ethoxylated alcohol nonionic surfactant; and the disinfecting quaternary ammonium surfactant comprises an N-alkyl-N,N-dimethyl benzyl ammonium salt and/or N-alkyl-N,N-dimethyl ethylbenzyl ammonium salt.

22. The composition of claim 11 , wherein the composition comprises about 0.05-3 wt. % of the ionic liquid; about 0.05-5 wt. % of the amino alcohol; no more than about 0.2 wt. % of the aminopolycarboxylate chelating agent; about 0.1-2 wt. % of the nonionic surfactant; and about 0.1-0.4 wt. % of the disinfecting quaternary ammonium surfactant.

23. The composition of claim 13 , wherein the composition comprises about 0.1-2 wt. % of the nonionic surfactant; no more than about 0.2 wt. % of the aminopolycarboxylate chelating agent; and about 0.1-0.4 wt. % of the disinfecting quaternary surfactant.

Assignees

• Johnson & Son Inc S C

Inventors

• Sutton Jr Art Daniels
• Flugge-Berendes Lisa
• Haas Michael S

Classifications

• C11D3/48

  Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions · CPC title

• C11D3/33

  Amino carboxylic acids · CPC title

• C11D1/62 Primary

  Quaternary ammonium compounds · CPC title

• C11D3/30 Primary

  Amines; Substituted amines {; Quaternized amines} · CPC title