Gel-form composition and water absorption inhibitor

Patent metadata

Field	Value
Publication number	US-10808124-B2
Application number	US-201716098321-A
Country	US
Kind code	B2
Filing date	Apr 25, 2017
Priority date	May 2, 2016
Publication date	Oct 20, 2020
Grant date	Oct 20, 2020

Abstract

This gel-form composition contains (A) an organoalkoxysilane of the following formula and/or a partially hydrolyzed condensate of the organoalkoxysilane, R 1 a Si(OR 2 ) 4-a (R 1 and R 2 are monovalent hydrocarbon groups, and a is 1, 2, or 3), (B) an aluminum dicarboxylate of the following formula (R 3 COO) 2 Al(OH) (R 3 is a monovalent hydrocarbon group), (C) a C6-24 fatty acid, (D) a C6-30 dicarboxylic acid, and (E) an aluminum oligomer and/or aluminum alkoxide selected from aluminum oxide organoxides and aluminum oxide acylates. It is thereby possible to: obtain a water absorption inhibitor that imparts an excellent water absorption-inhibiting property to the surfaces of porous materials; and provide a method for imparting a water absorption-inhibiting property by applying the water absorption inhibitor to the surface of a porous material, and a porous material that is surface-treated by the water absorption inhibitor.

First claim

The invention claimed is:

1. A gel composition comprising:
(A) 100 parts by weight of an organoalkoxysilane having the formula (1):
R 1 a Si(OR 2 ) 4-a   (1)

wherein R 1 is each independently a C 1 -C 20 monovalent hydrocarbon group, R 2 is each independently a C 1 -C 8 monovalent hydrocarbon group, and a is 1, 2, or 3, and/or a partial hydrolytic condensate of the organoalkoxysilane,
(B) 0.3 to 20 parts by weight of an aluminum dicarboxylate having the formula (2):
(R 3 COO) 2 Al(OH)  (2)

wherein R 3 is each independently a C 1 -C 25 monovalent hydrocarbon group,
(C) 0.3 to 20 parts by weight of a C 6 -C 24 fatty acid,
(D) 0.01 to 10 parts by weight of a C 6 -C 30 dicarboxylic acid, and
(E) 0.01 to 10 parts by weight of an aluminum oligomer selected from aluminum oxide organoxides and aluminum oxide acylates and/or an aluminum alkoxide.

2. The composition of claim 1 , further comprising (F) a polyorganosiloxane in which the number of dimethylsiloxane units is at least 20% relative to the total number of siloxane units, in an amount of 0.1 to 50 parts by weight per 100 parts by weight of component (A).

3. The composition of claim 2 wherein component (F) is a compound having the formula (4):
(R 6 3 SiO 0.5 ) p (R 6 2 SiO) q (R 6 SiO 1.5 ) r (SiO 2 ) s   (4)

wherein R 6 is each independently hydrogen, hydroxyl, a substituted or unsubstituted C 1 -C 10 monovalent hydrocarbon group which may contain an oxygen atom, or a C 1 -C 6 alkoxy group, p, r, and s are integers of at least 0, q is an integer of at least 1, and the sum of p+q+r+s is such a number that the polyorganosiloxane may have a weight-average molecular weight of 500 to 5,000, with the proviso that the number of dimethylsiloxane units: (CH 3 ) 2 SiO is at least 20% relative to the total number of siloxane units represented by R 6 m SiO (4-m)/2 wherein m is an integer of 0 to 3.

4. The composition of claim 1 , which is free of water and organic solvent.

5. A water absorption inhibitor comprising the composition of claim 1 .

6. A method of imparting water absorption inhibitory properties to a porous material, comprising coating the water absorption inhibitor of claim 5 to the surface of the porous material.

7. The method of claim 6 wherein the porous material is an inorganic porous material.

8. A porous material having a surface treated with the water absorption inhibitor of claim 5 .

Assignees

• Shinetsu Chemical Co

Inventors

• HAMAJIMA Yuta
• Aoki Shunji

Classifications

• C04B41/64 Primary

  Compounds having one or more carbon-to-metal of carbon-to-silicon linkages · CPC title

• C08K5/057

  Metal alcoholates {(metal enolates C08K5/0091)} · CPC title

• C08K5/5415

  containing at least one Si—O bond · CPC title

• C08K5/092

  Polycarboxylic acids · CPC title

• C09K3/18

  for application to surfaces to minimize adherence of ice, mist or water thereto (rendering particulate materials free flowing, in general, e.g. making them hydrophobic B01J2/30); Thawing or antifreeze materials for application to surfaces (used in liquids for heat-transfer, heat-exchange or heat-storage or for the production of heat or cold other than by combustion, e.g. radiator liquids, C09K5/00) · CPC title