Method of forming a hydrolysis resistant aqueous emulsion

Patent metadata

Field	Value
Publication number	US-9868866-B2
Application number	US-201414759456-A
Country	US
Kind code	B2
Filing date	Mar 12, 2014
Priority date	Mar 13, 2013
Publication date	Jan 16, 2018
Grant date	Jan 16, 2018

Abstract

A hydrolysis resistant aqueous emulsion includes a hydrolyzable silicon containing compound. This emulsion is formed by a method that includes the step of (A) forming a seed emulsion that includes (1) an emulsifier, (2) water, and (3) a first oil phase. The method also includes the step of (B) adding a second oil phase, including a hydrolyzable silicon containing compound, to the seed emulsion. A weight ratio of the second oil phase including the hydrolyzable silicon containing compound to the first oil phase in the seed emulsion is from 0.5 to 50. Moreover, a total weight of the first and second oil phases in the emulsion is at least 60 weight percent.

First claim

What is claimed is:

1. A method of forming a hydrolysis resistant aqueous emulsion comprising a hydrolyzable silicon containing compound, said method comprising the steps of:
A. forming a seed emulsion comprising;
(1) an emulsifier,
(2) water, and
(3) a first oil phase; and

B. adding a second oil phase comprising a hydrolyzable silicon containing compound to the seed emulsion;

wherein a weight ratio of the second oil phase comprising a hydrolyzable silicon containing compound to the first oil phase of the seed emulsion is from 0.5 to 50, wherein a total weight of the two oil phases in the emulsion is at least 60 weight percent and wherein a ratio of a molar concentration of water to a total molar concentration of the hydrolyzable silicon in the aqueous emulsion is less than 2.

2. The method of claim 1 wherein the first oil phase comprises a hydrolyzable silicon containing compound that may be the same or different from the hydrolyzable silicon containing compound in the second oil phase of (B).

3. The method of claim 1 wherein the hydrolyzable silicon containing compound of the second oil phase is a hydrolyzable silane or a hydrolyzable siloxane.

4. The method of claim 2 wherein the hydrolyzable silicon containing compound of the first oil phase is a hydrolyzable silane or a hydrolyzable siloxane.

5. The method of claim 2 wherein each of the hydrolyzable silicon containing compounds of the first and second oil phases is independently chosen from:
(i) an organohydrogensiloxane having the formula;
R′″R 2 Si—(O—SiRH) a —(O—SiRR′) b —SiR 2 R′″  (I), or

(OSiRH) c (OSiRR′) d   (II),

wherein;
R is an alkyl radical having 1 to 4 carbon atoms;
R′ is an alkyl radical having 1 to 18 carbon atoms;
R′″ is hydrogen or R;
a is a number from 0 to 35;
b is a number from 0 to 32; and
c and d are each independently a number from 1 to 10,

(ii) an alkoxysilane having the formula;

R
x
″

⁢

Si
⁡

(
OZ
)

y

⁢

(
O
)

4
-
x
-
y

2

,

(
III
)

wherein
R″ is an alkyl radical having 1 to 18 carbon atoms or an aryl radical;
Z is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, CH 3 C(O)—, CH 3 CH 2 C(O)—, HOCH 2 CH 2 —, CH 3 OCH 2 CH 2 —, or C 2 H 5 OCH 2 CH 2 —;
x has an average value from 0 to 2,
y has an average value from 0.1 to 4, and
x+y has a value equal to or less than 4.

6. The method of claim 5 wherein c is less than 3, d is equal to or greater than 2 and the sum of c and d is between 4 and 6.

7. The method of claim 1 wherein the first oil phase and/or the second oil phase further comprises a non-hydrolyzable silicon containing compound.

8. The method of claim 2 wherein the hydrolyzable silicon containing compound has a Volatile Organic Content below 100 g/L measured according to ASTM 5095 or below 50 g/L measured according to ASTM 5095.

9. The method of claim 1 wherein the first and/or the second oil phase comprises a silicone oil, a hydrocarbon oil or a fluorocarbon oil, or combinations thereof.

10. The method of claim 1 further comprising the step of adding a second emulsifier to the second oil phase, wherein the second emulsifier which may be the same or different from the emulsifier of the seed emulsion.

11. The method of claim 1 wherein the hydrolysis resistant emulsion is free of a thickener.

12. A hydrolysis resistant aqueous emulsion prepared by the method of claim 1 .

13. A method comprising the step of applying a hydrolysis resistant aqueous emulsion to a substrate, wherein the substrate is chosen from cement, clays, lime, gypsum or natural stone, concrete, mortar, masonry, cement, stucco, natural or artificial stone, ceramic, terracotta bricks, plaster board, fiber cement board, cellulosic substrates, wood, composite particle board, wood plastic composites, oriented strand board, medium density fiber board, and wherein the emulsion is prepared by the method of claim 1 .

14. The method of claim 13 wherein the emulsion is applied to the substrate in a thickness of less than 2 millimeters.

15. The method of claim 14 wherein the substrate is oriented approximately perpendicularly to a support and the emulsion may not flow towards the support more than 5 cm from an original point of application.

Assignees

• Dow Corning

Inventors

• Daoust Jennifer A
• Lecomte Jean-Paul H
• Liles Donald Taylor
• Liu Yihan
• Roggow Ii Timothy Andrew

Classifications

• C08G77/12

  containing silicon bound to hydrogen · CPC title

• C09D7/41

  Organic pigments; Organic dyes · CPC title

• D21J1/08

  Impregnated or coated fibreboard · CPC title

• C04B41/4916

  applied to the substrate as a solventless liquid · CPC title

• C08L83/04

  Polysiloxanes · CPC title