Coalescing agent derived from succinate ester

Patent metadata

Field	Value
Publication number	US-10807942-B2
Application number	US-201716089630-A
Country	US
Kind code	B2
Filing date	Mar 29, 2017
Priority date	Mar 29, 2016
Publication date	Oct 20, 2020
Grant date	Oct 20, 2020

Abstract

The present invention relates to a coalescing agent and a coating composition containing the coalescing agent as represented in structure (I);

wherein; n is integer from 1 to 8; R 1 and R 2 independently represents group selected from alkyl, alkenyl, alkynyl, phenyl, or benzyl groups; and X represents group selected from hydroxy or amine. The coalescing agent according to this invention contains low amount of volatile organic compounds, has no pungent odour, and environmental friendly. Moreover, it provides good efficacy when being used as coating component.

First claim

The invention claimed is:

1. A coalescing agent as represented in structure (I);

wherein;
n is integer from 1 to 8;
R 1 and R 2 are independently selected from alkyl, alkenyl, alkynyl, phenyl, or benzyl groups; and
X is selected from hydroxy or amine.

2. The coalescing agent according to claim 1 , wherein n is integer from 1 to 4.

3. The coalescing agent according to claim 1 , wherein R 1 and R 2 are independently selected from linear alkyl group having 1 to 4 carbon atoms.

4. The coalescing agent according to claim 1 , wherein X is hydroxy group.

5. The coalescing agent according to claim 1 , wherein said coalescing agent is prepared from a reaction between a diacid compound selected from malonic acid, malonic anhydride, succinic acid, succinic anhydride, glutaric acid, glutaric anhydride, adipic acid, adipic anhydride, or mixtures thereof; a monoalcohol compound selected from methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, isobutanol, tert-butanol, or mixtures thereof; and a dialcohol compound selected from propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-heptanediol, 1,2-octanediol, or mixtures thereof.

6. The coalescing agent according to claim 1 , wherein the coalescing agent is ethyl 2-hydroxypropyl succinate.

7. A coating composition, comprising:
a) at least one coalescing agent as represented in structure (I);

wherein;
n is integer from 1 to 8;
R 1 and R 2 are independently selected from alkyl, alkenyl, alkynyl, phenyl, or benzyl groups; and
X is selected from hydroxy or amine
b) binder; and
c) solvent.

8. The coating composition according to claim 7 , wherein n is integer from 1 to 4.

9. The coating composition according to claim 7 , wherein R 1 and R 2 are independently selected from linear alkyl group with 1 to 4 carbon atoms.

10. The coating composition according to claim 7 , wherein X is hydroxy group.

11. The coating composition according to claim 7 , wherein said coalescing agent is prepared from a reaction between a diacid compound selected from malonic acid, malonic anhydride, succinic acid, succinic anhydride, glutaric acid, glutaric anhydride, adipic acid, adipic anhydride, or mixtures thereof; a monoalcohol compound selected from methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, isobutanol, tert-butanol, or mixtures thereof; and a dialcohol compound selected from propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-heptanediol, 1,2-octanediol, or mixtures thereof.

12. The coating composition according to claim 7 , wherein the coalescing agent is ethyl 2-hydroxypropyl succinate.

13. The coating composition according to claim 7 , wherein the amount of coalescing agent is in the range from 3 to 8% by weight and wherein the amount of binder is in the range from 45 to 75% by weight.

14. The coating composition according to claim 7 , wherein said binder is selected from alkyd, acrylic, vinyl-acrylic, vinyl acetate/ethylene, polyurethane, epoxy, styrenic, styrenic-acrylic copolymer, styrene alkene copolymer groups, derivatives thereof, or mixtures thereof.

15. The coating composition according to claim 7 , wherein said solvent is selected from water, alcohol, petroleum distillate, ester, glycol, glycol ether, or mixtures thereof.

16. The coating composition according to claim 7 , wherein the coating composition further comprises an additive selected from pigment, pigment extender, colorant, surfactant, rheology modifier, texturing agent, defoamer, biocide, wetting agent, dispersing agent, crosslinker, thickener, antifreezing agent, stabilizer, or mixtures thereof.

Assignees

• Ptt Global Chemical Public Co Ltd

Inventors

• Pimolsiriphol Vorapong
• Prai-In Yingrak
• Panyathanmaporn Thammarat

Classifications

• C09D7/45

  Anti-settling agents · CPC title

• C09D7/20

  Diluents or solvents · CPC title

• C09D133/08

  Homopolymers or copolymers of acrylic acid esters · CPC title

• C08K5/11

  of acyclic polycarboxylic acids · CPC title

• C09D5/14

  Paints containing biocides, e.g. fungicides, insecticides or pesticides (C09D5/16 takes precedence) · CPC title