Process and apparatus for controlling the split of liquid reflux in a divided wall column

Patent metadata

Field	Value
Publication number	US-10792583-B2
Application number	US-201916368310-A
Country	US
Kind code	B2
Filing date	Mar 28, 2019
Priority date	Mar 29, 2018
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

The present invention relates to the fractionation technology that is used to create purified phenol and acetone products. More specifically, the present invention relates to a fractionation technology that is used to create crude acetone and crude phenol streams using a dividing wall column intended to remove cumene, alpha-methyl styrene and water from the product side of the wall.

First claim

The invention claimed is:

1. A fractionation process, comprising:
feeding crude phenol to a dividing wall column, the dividing wall column having a dividing wall forming a feed side and a product side, the crude phenol being fed to the feed side at a point lower than a top of the dividing wall and above a bottom of the dividing wall;
collecting liquid reflux from a tray above the dividing wall, the liquid reflux forming an aqueous phase and an organic phase, wherein the liquid reflux is at least a portion of condensed vapor from the column;
separating the liquid reflux into two streams above the dividing wall, a first stream comprising primarily the aqueous phase and a second stream comprising primarily the organic phase;
passing at least a portion of the first stream to the product side of the dividing wall column at a point lower than the top of the dividing wall and above a bottom of the dividing wall;
dividing the second stream into a first portion and a second portion;
passing the first portion of the second stream to the feed side of the dividing wall column at a point lower than the top of the dividing wall and above the point where the crude phenol is fed;
passing the second portion of the second stream to the product side of the dividing wall column at a point lower than the top of the dividing wall and above the bottom of the dividing wall; and
removing a liquid sidecut stream from an outlet on the product side of the dividing wall column at a point lower than where the first stream and the second portion of the second stream are introduced and above a bottom of the dividing wall, the liquid sidecut stream forming two phases.

2. The process of claim 1 further comprising:
controlling a flow rate of the first stream, a flow rate of the first portion of the second stream, and a flow rate of the second portion of the second stream to maintain a desired flow rate to the feed side of the dividing wall column and a desired flow rate to the product side of the dividing wall column.

3. The process of claim 1 wherein passing the first stream to the product side of the dividing wall column comprises passing all of the first stream to the product side of the dividing wall column.

4. The process of claim 1 wherein passing at least the portion of the first stream to the product side of the dividing wall column comprises;
dividing the first stream into a first portion and a second portion;
wherein passing at least a portion of the first stream to the product side comprises passing the first portion of the first stream to the product side of the dividing wall column; and
passing the second portion of the first stream to the feed side of the dividing wall column at a point lower than the top of the dividing wall and above the point where the crude phenol is fed.

5. The process of claim 4 further comprising:
controlling a flow rate of the first portion of the first stream, a flow rate of the second portion of the first stream, a flow rate of the first portion of the second stream, and a flow rate of the second portion of the second stream to maintain a desired flow to the feed side of the dividing wall column and a desired flow rate to the product side of the dividing wall column.

6. The process of claim 1 further comprising:
separating the liquid sidecut stream into a higher density stream having a first density and a lower density stream having a second density less than the first density.

7. The process of claim 6 wherein separating the liquid sidecut stream into the higher density stream and the lower density stream comprises separating the liquid sidecut stream into the higher density stream and the lower density stream in a settler.

8. The process of claim 1 wherein separating the liquid reflux into two streams comprises separating the liquid reflux into two streams using an internal decanter.

9. The process of claim 1 further comprising:
cooling the liquid sidecut stream before separating the liquid sidecut stream.

10. A fractionation process, comprising:
feeding crude phenol to a dividing wall column, the dividing wall column having a dividing wall forming a feed side and a product side, the crude phenol being fed to the feed side at a point lower than a top of the dividing wall and above a bottom of the dividing wall;
collecting liquid reflux from a tray above the dividing wall, the liquid reflux forming an aqueous phase and an organic phase, wherein the liquid reflux is at least a portion of condensed vapor from the column;
separating the liquid reflux into two streams above the dividing wall, a first stream comprising primarily the aqueous phase and a second stream comprising primarily the organic phase;
passing at least a portion of the first stream to the product side of the dividing wall column at a point lower than the top of the dividing wall and above a bottom of the dividing wall;
dividing the second stream into a first portion and a second portion;
passing the first portion of the second stream to the feed side of the dividing wall column at a point lower than the top of the dividing wall and above the point where the crude phenol is fed;
passing the second portion of the second stream to the product side of the dividing wall column at a point lower than the top of the dividing wall and above the bottom of the dividing wall;
controlling a flow rate of the first stream, a flow rate of the first portion of the second stream, and a flow rate of the second portion of the second stream to maintain a desired flow rate to the feed side of the dividing wall column and a desired flow rate to the product side of the dividing wall column;
removing a liquid sidecut stream from an outlet on the product side of the dividing wall column at a point lower than where the first stream and the second portion of the second stream are introduced and above a bottom of the dividing wall, the liquid sidecut stream forming two phases; and
separating the liquid sidecut stream into a higher density stream having a first density and a lower density stream having a second density less than the first density.

11. The process of claim 1 wherein passing at least the portion of the first stream to the product side of the dividing wall column comprises;
dividing the first stream into a first portion and a second portion;
wherein passing at least a portion of the first stream to the product side comprises passing the first portion of the first stream to the product side of the dividing wall column;
passing the second portion of the first stream to the feed side of the dividing wall column at a point lower than the top of the dividing wall and above the point where the crude phenol is fed; and
controlling a flow rate of the first portion of the first stream, and a flow rate of the second portion of the first stream to maintain a desired flow rate to the feed side of the dividing wall column and a desired flow rate to the product side of the dividing wall column.

12. The process of claim 1 further comprising at least one of:
sensing at least one parameter of the process and generating a signal or data from the sensing;
generating and transmitting a signal; or
generating and transmitting data.

Assignees

• Uop Llc

Inventors

• Schulz Russell C
• Williams Chad A
• Harris James W
• Patel Nikunj Manubhai

Classifications

• C07C39/04

  Phenol · CPC title

• B01D3/4233

  Head- and feed stream · CPC title

• C07C37/52

  by splitting polyaromatic compounds, e.g. polyphenolalkanes · CPC title

• B01D3/141 Primary

  where at least one distillation column contains at least one dividing wall · CPC title

• C07C37/74

  by distillation · CPC title