Negative active material, method of preparing the same, negative electrode for lithium secondary battery including negative active material, and lithium secondary battery including negative electrode
US-9306216-B2 · Apr 5, 2016 · US
US10787726B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10787726-B2 |
| Application number | US-201615142323-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 29, 2016 |
| Priority date | Apr 29, 2016 |
| Publication date | Sep 29, 2020 |
| Grant date | Sep 29, 2020 |
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A ductile iron composition including, by weight: about 3.4% to about 4.0% Si; about 3.0% to about 3.5% C; about 0.5% to about 1.0% Cr; about 0.02% to about 0.05% Mo; up to about 0.01% S; up to about 0.5% Mn; and balance iron and incidental impurities. The composition has a a ferritic body center cubic microstructure and has a graphite nodule density of greater than 100 per mm 2 . A method for forming a ductile iron composition is also disclosed.
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What is claimed is: 1. A ductile iron composition, consisting of, by weight: about 3.4% to about 4.0% Si; about 3.0% to about 3.5% C; about 0.5% to about 1.0% Cr; about 0.02% to about 0.05% Mo; up to about 0.01% S; about 0.3% to about 0.5% Mn; and balance iron and incidental impurities; wherein the ductile iron composition includes a ferritic body center cubic microstructure and has a graphite nodule density of greater than 100 per mm 2 ; and wherein the ductile iron composition is devoid of Ni. 2. The ductile iron composition of claim 1 , wherein the ductile iron composition consists of, by weight: about 3.5% to about 3.9% Si; about 3.1% to about 3.4% C; about 0.6% to about 0.9% Cr; about 0.03% to about 0.04% Mo; up to about 0.01% S; about 0.3% to about 0.4% Mn; and balance iron and incidental impurities. 3. The ductile iron composition of claim 1 , wherein the ductile iron composition includes microstructure containing less than 15 areal % pearlite. 4. The ductile iron composition of claim 1 , wherein the ductile iron composition includes microstructure containing less than 5 areal % pearlite. 5. The ductile iron composition of claim 1 , wherein the ductile iron composition includes microstructure containing carbide volumetric percentage between about 5% and about 20%. 6. The ductile iron composition of claim 1 , wherein the graphite nodule density is greater than 125 per mm 2 . 7. The ductile iron composition of claim 1 , wherein the graphite nodule density is greater than 150 per mm 2 . 8. A component comprising the ductile iron composition, according to claim 1 . 9. The component of claim 8 , comprising a component selected from the group consisting of gearbox components, ring gears, planetary gears, and mining equipment. 10. A method of forming a ductile iron component, the process comprising: forming a melt of a charge alloy; nodularizing the melt with a nodularizing alloy; inoculating the melt with an inoculating composition to nucleate graphite nodules and form the component comprising a ductile iron composition consisting of, by weight: about 3.4% to about 4.0% Si; about 3.0% to about 3.5% C; about 0.5% to about 1.0% Cr; about 0.02% to about 0.05% Mo; up to about 0.01% S; about 0.3% to about 0.5% Mn; and balance iron and incidental impurities; wherein the ductile iron composition includes a ferritic body center cubic microstructure and has a graphite nodule density of greater than 100 per mm 2 ; and wherein the ductile iron composition is devoid of Ni. 11. The method of claim 10 , wherein the nodularizing composition comprises, by weight: a first portion comprising, by weight, of the first portion: about 0.2 to about 2.0% Al; about 0.2 to about 2.0% Ca; about 0.2 to about 2.0% rare earth elements; 2.0 to about 4.0% Mg; and balance essentially FeSi and incidental impurities; and second portion comprising, by weight: about 0.2 to about 2.0% Al; about 0.2 to about 2.0% Ca; less than about 0.1% rare earth elements; 2.0 to about 4.0% Mg; and balance essentially FeSi and incidental impurities. 12. The method of claim 11 , wherein the nodularizing composition comprises, by weight, from about 1.0% to about 1.4% of the charge alloy and nodularizing composition. 13. The method of claim 10 , wherein the inoculating composition includes a ferrosilicon composition comprising, by weight, about 0.2 to about 2.0% Al, about 0.2 to about 2.0% Ca, and about 1.0 to about 2.0% Ce. 14. The method of claim 10 , further comprising heat treating the component at a temperature and for time sufficient to induce formation of carbides in the ductile iron composition. 15. The method of claim 14 , further comprising heat treating the component at a temperature between about 400° C. and 600° C. 16. The method of claim 14 , wherein the ductile iron composition includes microstructure containing carbide volumetric percentage between about 5% and about 20%. 17. The method of claim 10 , wherein the ductile iron composition includes microstructure containing less than 15 areal % pearlite.
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