Primary Carbide Refinement In Hypereutectic High Chromium Cast Irons
US-2024052462-A1 · Feb 15, 2024 · US
US9222154B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9222154-B2 |
| Application number | US-55750904-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 21, 2004 |
| Priority date | May 22, 2003 |
| Publication date | Dec 29, 2015 |
| Grant date | Dec 29, 2015 |
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A casting of a white cast iron alloy which includes the following alloy composition, in weight %: chromium: 12-25%; carbon: 1.5-6%; manganese: 2-7%; silicon: up to 1.5%; molybdenum: up to 2; nickel: up to 4%; microalloying elements selected from the group of titanium, zirconium, niobium, boron, vanadium, and tungsten: up to 2% of each of one or more of the elements; and iron: balance. The microstructure of the casting has 15-60 vol % eutectic carbides and primary carbides dispersed in a ferrous matrix of martensite and is at least substantially free of pearlite.
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The invention claimed is: 1. A casting of a white cast iron alloy that comprises: 20 to 23 wt. % chromium; 3.3 to 6 wt. % carbon; greater than 4 up to 7 wt. % manganese; up to 1.5 wt. % silicon; and the balance iron; and having a microstructure comprising martensite, retained austenite and less than 2 vol. % pearlite and includes M 7 C 3 carbides, where “M” is a metal and “C” is carbon. 2. The casting of claim 1 , wherein the casting comprises greater than 4 up to 5.5 wt % manganese. 3. The casting of claim 1 , wherein the casting is free of nickel and molybdenum. 4. The casting of claim 1 , wherein the casting has a hardness of 700 HV 50. 5. The casting of claim 1 , wherein the casting is free of pearlite. 6. A hardened casting of a white cast iron alloy, hardened at 950° C. to 1000° C. for at least 4 hours, comprising: 20 to 23 wt. % chromium; 3.3 to 6 wt. % carbon; greater than 4 up to 7 wt. % manganese; up to 1.5 wt. % silicon; and the balance iron; and having a microstructure comprising martensite, retained austenite and less than 2 vol. % pearlite and includes M 7 C 3 carbides, where “M” is a metal and “C” is carbon. 7. The hardened casting of claim 6 , wherein the casting comprises greater than 4 up to 5.5 wt % manganese. 8. The hardened casting of claim 6 , wherein the casting is free of nickel and molybdenum. 9. The hardened casting of claim 6 , wherein the casting has a hardness of 700 HV 50. 10. The hardened casting of claim 6 , wherein the casting is free of pearlite. 11. The hardened casting of claim 6 , wherein the casting has a hardness of from 700-719 HV 50. 12. The hardened casting of claim 6 , wherein the microstructure of the hardened casting further comprises 32.4 to 60 vol. % eutectic carbides and primary carbides dispersed in a ferrous matrix that comprises martensite. 13. A method for producing a hardened white cast iron alloy casting, comprising: a) pouring a molten melt of a white cast iron alloy to form a casting; b) cooling the casting to room temperature; and c) hardening the casting by heating the casting to a temperature of from 950° C. to 1000° C. and holding the casting at 950° C. to 1000° C. for at least 4 hours to destabilize austenite to form the hardened white cast iron alloy casting composed of: 20 to 23 wt. % chromium; 3.3 to 6 wt. % carbon; greater than 4 up to 7 wt. % manganese; up to 1.5 wt. % silicon; and the balance iron; and having a microstructure comprising martensite, retained austenite and less than 2 vol. % pearlite and includes M 7 C 3 carbides, where “M” is a metal and “C” is carbon. 14. The method of claim 13 , wherein the white cast iron alloy is free of nickel and molybdenum. 15. The method of claim 13 , wherein the white cast iron alloy comprises greater than 4 up to 5.5 wt % manganese. 16. The method of claim 13 , wherein the microstructure of the hardened white cast iron alloy casting further comprises 32.4 to 60 vol. % eutectic carbides and primary carbides dispersed in a ferrous matrix that comprises martensite. 17. The method of claim 13 , wherein the hardened white cast iron alloy casting has a hardness of 700 HV 50. 18. The method of claim 13 , wherein the casting is free of pearlite. 19. The method of claim 13 , wherein the casting has a hardness of from 700-719 HV 50.
Dispersions; Precipitations · CPC title
of white cast-iron · CPC title
containing aluminium or silicon · CPC title
with nickel · CPC title
containing chromium · CPC title
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