Dry erase article

Patent metadata

Field	Value
Publication number	US-10787589-B2
Application number	US-201816484518-A
Country	US
Kind code	B2
Filing date	Feb 19, 2018
Priority date	Feb 15, 2017
Publication date	Sep 29, 2020
Grant date	Sep 29, 2020

Abstract

Dry erase articles are described comprising a writable surface layer comprising a cured hardcoat composition comprising the reaction product of certain low surface energy compound(s). In one embodiment, the compound(s) comprise a C18-C36 hydrocarbon group and an ethylenically unsaturated group. In another embodiment, a mixture of compounds is utilized, the mixture comprising first compounds comprising a C18-C36 hydrocarbon group and an ethylenically unsaturated group and second compounds comprising a C8-C17 hydrocarbon group and an ethylenically unsaturated group, wherein the first and second compound are present at a weight ratio of 3:2 to 4:1.

First claim

What is claimed is:

1. A dry erase article comprising:
a writable surface layer comprising a cured hardcoat composition comprising at least 2.8 wt.-% and less than 9.5 wt.-% of
i) the reaction product of a compound comprising a C18-C36 hydrocarbon group and an ethylenically unsaturated group; or
ii) the reaction product of a mixture of compounds comprising first compounds comprising a C18-C36 hydrocarbon group and an ethylenically unsaturated group and second compounds comprising a C8-C17 hydrocarbon group and an ethylenically unsaturated group wherein the first and second compound are present at a weight ratio of 3:2 to 4:1.

2. The dry erase article of claim 1 wherein at least one of the compounds comprising a C18-C36 hydrocarbon group has the formula
R 1 -L-R 2
wherein R 1 is a C18-36 hydrocarbon group;
L is a covalent bond, a divalent atom, or a hydrophobic divalent liking group;
R 2 is an ethylenically unsaturated group.

3. The dry erase article of claim 1 wherein at least one C18-36 hydrocarbon group is a linear alkylene group.

4. The dry erase article of claim 1 wherein at least one ethylenically unsaturated group is a (meth)acrylate group or a vinyl group.

5. The dry erase article of claim 1 wherein at least one compound comprising the C18-C36 hydrocarbon group is solid at 25° C.

6. The dry erase board of claim 1 wherein the hardcoat comprises the reaction product of one or more polymerizable materials.

7. The dry erase article of claim 6 wherein the hardcoat comprises at least 60 wt.-% of polymerized units of ethylenically unsaturated monomer having at least two ethylenically unsaturated groups and a Tg of at least 75° C.

8. The hardcoat of claim 7 wherein the hardcoat is free of inorganic oxide particles.

9. The dry erase article of claim 7 wherein the hardcoat comprises at least 60 wt.-% of polymerized units of ethylenically unsaturated monomer having at least two ethylenically unsaturated groups and a Tg of at least 75° C.

10. The hardcoat of claim 9 wherein the hardcoat is free of inorganic oxide particles.

11. The dry erase article of claim 6 wherein the hardcoat comprises at least 60 wt.-% of polymerized units of ethylenically unsaturated oligomers having at least two ethylenically unsaturated groups.

12. The dry erase article of claim 6 wherein the oligomers are selected from polyester acrylate oligomers or urethane acrylate oligomers.

13. The dry erase board of claim 1 wherein the hardcoat comprises at least 30 wt.-% of polymerized units of ethylenically unsaturated monomer or oligomers having at least two ethylenically unsaturated groups and a Tg of at least 75° C. and inorganic oxide particles.

14. The dry erase article of claim 1 wherein permanent marker can be completely removed from the surface layer when tested according to the Test for Permanent Marker Erasability.

15. The dry erase article of claim 1 wherein the writable surface layer is disposed upon an organic polymeric base member.

16. The dry erase article of claim 15 wherein the organic polymeric base member is a film.

17. The dry erase article of claim 15 wherein the base member is transparent or translucent.

18. The dry erase article of claim 1 wherein the surface layer further comprises silicone monomers, oligomers, or polymers.

19. A dry erase article comprising:
a writable surface layer comprising a cured hardcoat composition comprising the reaction product of a mixture of compounds comprising first compounds comprising a C18-C36 hydrocarbon group and an ethylenically unsaturated group and second compounds comprising a C8-C17 hydrocarbon group and an ethylenically unsaturated group wherein the first and second compound are present at a weight ratio of 3:2 to 4:1.

20. The dry erase article of claim 19 wherein the mixture of compounds is present in an amount ranging from at least 2.8 wt.-% and less than 9.5 wt.-% of the cured hardcoat composition.

21. The dry erase board of claim 19 wherein the hardcoat comprises at least 30 wt.-% of polymerized units of ethylenically unsaturated monomer or oligomers having at least two ethylenically unsaturated groups and a Tg of at least 75° C. and inorganic oxide particles.

22. The dry erase article of claim 19 wherein the writable surface layer is disposed upon an organic polymeric base member.

23. The dry erase article of claim 22 wherein the base member is transparent or translucent.

24. The dry erase article of claim 19 wherein the surface layer further comprises silicone monomers, oligomers, or polymers.

Assignees

• 3M Innovative Properties Co

Inventors

• Jing Naiyong
• Ma Jun
• Saffer Erika
• Mahli David M
• Damte Gezahegn D

Classifications

• C09D135/02 Primary

  Homopolymers or copolymers of esters (C09D135/06, C09D135/08 take precedence) · CPC title

• C08F222/105

  of pentaalcohols · CPC title

• B43L1/002 Primary

  chemical details · CPC title

• C08F220/343

  in the form of urethane links · CPC title

• C08F222/104

  of tetraalcohols, e.g. pentaerythritol tetra(meth)acrylate · CPC title