Base metal catalyst for treatment of ozone and volatile organic compounds present in air supply

Patent metadata

Field	Value
Publication number	US-10780397-B2
Application number	US-201916249494-A
Country	US
Kind code	B2
Filing date	Jan 16, 2019
Priority date	Oct 30, 2014
Publication date	Sep 22, 2020
Grant date	Sep 22, 2020

Abstract

Disclosed herein are base metal catalyst devices for removing ozone, volatile organic compounds, and other pollutants from an air flow stream. A catalyst device includes a housing, a solid substrate disposed within the housing, and a catalyst layer disposed on the substrate. The catalyst layer includes a first base metal catalyst at a first mass percent, a second base metal catalyst at a second mass percent, and a support material impregnated with at least one of the first base metal catalyst or the second base metal catalyst.

First claim

What is claimed is:

1. A catalyst composition comprising:
a first base metal catalyst;
a second base metal catalyst; and
a support material impregnated with at least one of the first base metal catalyst or the second base metal catalyst, the support material comprising one or more of ceria, alumina, titania, silica, zirconia, metal organic framework, clay, or zeolite, wherein the support material has a surface area of at least about 50 m 2 /g.

2. The catalyst composition of claim 1 , wherein the first base metal catalyst and the second base metal catalyst are each independently selected from Cu, Fe, Co, Ni, Cr, Mn, Nd, Ba, Ce, La, Pr, Mg, Ca, Zn, Nb, Zr, Mo, Sn, Ta, and Sr, with the proviso that the first base metal catalyst and the second base metal catalyst are different.

3. The catalyst composition of claim 1 , wherein the first base metal catalyst comprises copper oxide, and wherein the copper oxide is present from about 1% to about 30% by mass based on a total mass of the catalyst composition.

4. The catalyst composition of claim 3 , wherein the second base metal catalyst comprises manganese oxide, and wherein the manganese oxide is present from about 1% to about 30% by mass based on a total mass of the catalyst composition.

5. The catalyst composition of claim 1 , wherein the support material is an oxygen donating support.

6. The catalyst composition of claim 1 , wherein the support material has a pore volume from about 0.1 cc/g to about 10 cc/g.

7. A catalytic device adapted for purifying an air supply of ozone and volatile organic compounds, the catalytic device comprising:
a substrate; and
a catalyst layer formed on the substrate, the catalyst layer comprising:
a first base metal catalyst;
a second base metal catalyst; and
a support material impregnated with at least one of the first base metal catalyst or the second base metal catalyst, the support material comprising one or more of ceria, alumina, titania, silica, zirconia, metal organic framework, clay, or zeolite, wherein the support material has a pore volume from about 0.1 cc/g to about 10 cc/g.

8. The catalytic device of claim 7 , wherein the first base metal catalyst comprises copper oxide, and wherein the copper oxide is present from about 1% to about 30% by mass based on a total mass of the catalyst layer.

9. The catalytic device of claim 8 , wherein the second base metal catalyst comprises manganese oxide, and wherein the manganese oxide is present from about 1% to about 30% by mass based on a total mass of the catalyst layer.

10. The catalytic device of claim 7 , wherein the support material is an oxygen donating support.

11. The catalytic device of claim 7 , wherein the support material has a surface area of at least about 50 m 2 /g.

12. The catalytic device of claim 7 , wherein a density of the catalyst layer is between about 0.015 g/in 2 and about 0.062 g/in 2 .

13. A method of forming a catalyst layer, the method comprising:
providing a slurry, the slurry comprising a first base metal catalyst, a second base metal catalyst, a binder material, and a support material comprising one or more of ceria, alumina, titania, silica, zirconia, metal organic framework, clay, or zeolite;
depositing the slurry onto a surface of a solid substrate; and
calcining the deposited slurry to form the catalyst layer disposed on the surface of the solid substrate, wherein a density of the catalyst layer is between about 0.015 g/in 2 and about 0.062 g/in 2 .

14. The method of claim 13 , wherein the first base metal catalyst comprises copper oxide, and wherein the copper oxide is present from about 1% to about 30% by mass based on a total mass of the catalyst layer.

15. The method of claim 14 , wherein the second base metal catalyst comprises manganese oxide, and wherein the manganese oxide is present from about 1% to about 30% by mass based on a total mass of the catalyst layer.

16. The method of claim 13 , wherein the support material is an oxygen donating support.

17. The method of claim 13 , wherein the support material has a surface area of at least about 50 m 2 /g, and wherein the support material has a pore volume from about 0.1 cc/g to about 10 cc/g.

Assignees

• Basf Corp

Inventors

• Robinson David M
• Buelow Mark T
• Alden Laif R
• Durilla Michael

Classifications

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J35/23

  in a colloidal state · CPC title

• F24F8/99

  for treating air sourced from urban areas, e.g. from streets · CPC title

• F24F8/167

  using catalytic reactions · CPC title