Lithium-stuffed garnet electrolytes with secondary phase inclusions
US-10347937-B2 · Jul 9, 2019 · US
US10774004B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10774004-B2 |
| Application number | US-201716085949-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 13, 2017 |
| Priority date | Mar 18, 2016 |
| Publication date | Sep 15, 2020 |
| Grant date | Sep 15, 2020 |
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A solid electrolyte capable of securing grain boundary resistance even when sintering is performed at a relatively low temperature and a lithium ion battery using the solid electrolyte are provided. The solid electrolyte includes a first electrolyte which contains a lithium composite metal compound containing one kind of first metal element selected from group 13 elements in period 3 or higher, and a second electrolyte which contains Li and at least two kinds of second metal elements selected from group 5 elements in period 5 or higher or group 15 elements in period 5 or higher.
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The invention claimed is: 1. A solid electrolyte comprising: a first electrolyte which contains a lithium composite metal compound containing Ga; and a second electrolyte which contains Li, Sb and at least one kind of second metal element selected from group 5 elements in period 5 or higher or group 15 elements in period 5 or higher. 2. The solid electrolyte according to claim 1 , wherein an atomic crystal radius of the second metal element is 78 pm or more. 3. The solid electrolyte according to claim 1 , wherein the one kind of the second metal element is selected from Nb, Ta, and Bi. 4. The solid electrolyte according to claim 1 , further comprising: a third electrolyte which is amorphous and is formed of an oxide containing Li and B. 5. A lithium ion battery comprising: a solid electrolyte layer formed of the solid electrolyte according to claim 1 ; an electrode provided on one surface of the solid electrolyte layer; and a current collector provided on a side of the solid electrolyte layer opposite to the one surface of the solid electrolyte layer. 6. The lithium ion battery according to claim 5 , wherein the electrode is formed of metal lithium, and wherein a positive electrode active material layer containing Li is provided between the other surface of the solid electrolyte layer and the current collector.
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