Copper alloy sputtering target and manufacturing method of copper alloy sputtering target

Patent metadata

Field	Value
Publication number	US-10770274-B2
Application number	US-201715480733-A
Country	US
Kind code	B2
Filing date	Apr 6, 2017
Priority date	Jul 31, 2013
Publication date	Sep 8, 2020
Grant date	Sep 8, 2020

Abstract

Ca; casting the molten metal so as to obtain an ingot; and performing stress relieving annealing after performing hot rolling to the ingot.

First claim

What is claimed is:

1. A manufacturing method of a copper alloy sputtering target, the sputtering target formed by a copper alloy containing: the content of Ca being 0.3 to 1.7% by mass; the total content of Mg and Al being 5 ppm or less by mass; the content of oxygen being 20 ppm or less by mass; and the remainder is Cu and inevitable impurities, the manufacturing method comprising the steps of:
preparing a copper having purity of 99.99% or more by mass;
melting the copper by a high frequency induction heating in a crucible in an inert gas atmosphere or a reducing gas atmosphere so as to obtain a molten copper;
controlling component so as to obtain a molten metal having a predetermined component compositions by the addition of Ca having purity of 98.5% or more by mass into the molten copper and by melting the Ca;
casting the molten metal having the predetermined component compositions in a cooled casting mold so as to obtain an ingot; and
performing stress relieving annealing after performing hot-rolling to the ingot,
and wherein the copper alloy sputtering target causes no abnormal discharge when sputtering for 8 hours at an output of 600 W by using direct current system as a power supply,
wherein the abnormal discharge is counted using an arc counter provided in the power supply, and
wherein the sputtering is performed under conditions of evacuating a vacuum chamber of a sputtering apparatus to a vacuum pressure of 4×10 −5 Pa or less, and then supplying an oxygen-Ar mixed gas including pure Ar gas or oxygen in a proportion of 10% by volume into the vacuum chamber as a sputtering gas to set a pressure of a sputtering atmosphere to 0.67 Pa.

2. The manufacturing method of the copper alloy sputtering target according to claim 1 , wherein
in the step of the controlling the components, additive materials for the Ca are used by selecting Ca additives in which the content of Mg and Al is 50 ppm or less by mass respectively and the total content of Mg and Al is 100 ppm or less by mass.

3. The manufacturing method of the copper alloy sputtering target according to claim 1 , wherein
the casting method in the casting so as to obtain the ingot is a semi-continuous casting method in which melting materials are melted using a batch furnace and casting only is continuously performed in a predetermined length or a fully-continuous casting method in which melting materials are continuously melted and casting is continuously performed in length unlimited in principle.

4. A manufacturing method of a copper alloy sputtering target, the sputtering target formed by a copper alloy containing: the content of Ca being 0.3 to 1.7% by mass; the total content of Mg and Al being 5 ppm or less by mass; the content of oxygen being 20 ppm or less by mass; and the remainder is Cu and inevitable impurities, with Fe, Mn and Si being contained as the inevitable impurities in the copper alloy sputtering target, and the content of Fe is 1 ppm or less by mass, the content of Mn is 1 ppm or less by mass, and the content of Si is 1 ppm or less by mass, the manufacturing method comprising the steps of:
preparing a copper having purity of 99.99% or more by mass;
melting the copper by a high frequency induction heating in a crucible in an inert gas atmosphere or a reducing gas atmosphere so as to obtain a molten copper;
controlling component so as to obtain a molten metal having a predetermined component compositions by the addition of Ca having purity of 98.5% or more by mass into the molten copper and by melting the Ca;
casting the molten metal having the predetermined component compositions in a cooled casting mold so as to obtain an ingot; and
performing stress relieving annealing after performing hot-rolling to the ingot,
and wherein the copper alloy sputtering target causes no abnormal discharge when sputtering for 8 hours at an output of 600 W by using direct current system as a power supply,
wherein the abnormal discharge is counted using an arc counter provided in the power supply, and
wherein the sputtering is performed under conditions of evacuating a vacuum chamber of a sputtering apparatus to a vacuum pressure of 4×10 −5 Pa or less, and then supplying an oxygen-Ar mixed gas including pure Ar gas or oxygen in a proportion of 10% by volume into the vacuum chamber as a sputtering gas to set a pressure of a sputtering atmosphere to 0.67 Pa.

5. The manufacturing method of the copper alloy sputtering target according to claim 4 , wherein in the step of the controlling the components, additive materials for the Ca are used by selecting Ca additives in which the content of Mg and Al is 50 ppm or less by mass respectively and the total content of Mg and Al is 100 ppm or less by mass.

6. The manufacturing method of the copper alloy sputtering target according to claim 2 , wherein the casting method in the casting so as to obtain the ingot is a semi-continuous casting method in which melting materials are melted using a batch furnace and casting only is continuously performed in a predetermined length or a fully-continuous casting method in which melting materials are continuously melted and casting is continuously performed in length unlimited in principle.

7. The manufacturing method of the copper alloy sputtering target according to claim 4 , wherein the casting method in the casting so as to obtain the ingot is a semi-continuous casting method in which melting materials are melted using a batch furnace and casting only is continuously performed in a predetermined length or a fully-continuous casting method in which melting materials are continuously melted and casting is continuously performed in length unlimited in principle.

8. The manufacturing method of the copper alloy sputtering target according to claim 5 , wherein the casting method in the casting so as to obtain the ingot is a semi-continuous casting method in which melting materials are melted using a batch furnace and casting only is continuously performed in a predetermined length or a fully-continuous casting method in which melting materials are continuously melted and casting is continuously performed in length unlimited in principle.

9. A manufacturing method of a copper alloy sputtering target, the sputtering target being the copper alloy sputtering target, the manufacturing method comprising the steps of:
preparing a copper having purity of 99.99% or more by mass;
melting the copper by a high frequency induction heating in a crucible in an inert gas atmosphere or a reducing gas atmosphere so as to obtain a molten copper;
controlling component so as to obtain a molten metal having a predetermined component compositions by the addition of Ca having purity of 98.5% or more by mass into the molten copper and by melting the Ca;
casting the molten metal having the predetermined component compositions in a cooled casting mold so as to obtain an ingot; and
performing stress relieving annealing after performing hot-rolling to the ingot,
and wherein the copper alloy sputtering target causes no abnormal discharge when sputtering for 8 hours at an output of 600 W by using direct current system as a power supply,
wherein the abnormal discharge is counted using an arc counter provided in the power supply, and
wherein the sputtering is performed under conditions of evacuating a vacuum chamber of a sputtering apparatus to a vacuum pressure of 4×10 −5 Pa or less, and then supplying an oxygen-Ar mixed gas including pure Ar gas or oxygen in a proportion of 10% by volume into the vacuum chamber as a sputtering gas to set a pressure of a sputtering atmosphere to 0.67 Pa.

10. The manufacturing method of the copper alloy sputtering target according to claim 1 , wherein
the copper i

Assignees

• Mitsubishi Materials Corp

Inventors

• Mori Satoru
• Sakamoto Toshio
• Ookubo Kiyoyuki

Classifications

• C23C14/3414 Primary

  Metallurgical or chemical aspects of target preparation, e.g. casting, powder metallurgy · CPC title

• H01J37/3491

  Manufacturing of targets · CPC title

• B22D7/02

  Casting compound ingots of two or more different metals in the molten state, i.e. integrally cast · CPC title

• C22C9/00 Primary

  Alloys based on copper · CPC title

• H01J37/3429 Primary

  Plural materials · CPC title