Selective etching process for SiGe and doped epitaxial silicon
US-12062571-B2 · Aug 13, 2024 · US
US10755995B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10755995-B2 |
| Application number | US-201916402042-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 2, 2019 |
| Priority date | Jun 28, 2018 |
| Publication date | Aug 25, 2020 |
| Grant date | Aug 25, 2020 |
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A method is provided. A bottom passivation layer is formed on a dielectric layer over a semiconductor substrate. Then, a first opening is formed in the bottom passivation layer to expose a portion of the dielectric layer. Next, a metal pad is formed in the first opening. Afterwards, a first oxide-based passivation layer is formed over the metal pad. Then, a second oxide-based passivation layer is formed over the first oxide-based passivation layer. The second oxide-based passivation layer has a hardness less than a hardness of the first oxide-based passivation layer.
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What is claimed is: 1. A method, comprising: forming a bottom passivation layer on a dielectric layer over a semiconductor substrate; forming a first opening in the bottom passivation layer to expose a portion of the dielectric layer; forming a metal pad in the first opening; forming a first oxide-based passivation layer over the metal pad; and forming a second oxide-based passivation layer over the first oxide-based passivation layer, the second oxide-based passivation layer having a hardness less than a hardness of the first oxide-based passivation layer. 2. The method of claim 1 , further comprising forming a third oxide-based passivation layer over the metal pad prior to forming the first oxide-based passivation layer. 3. The method of claim 2 , wherein the first and second oxide-based passivation layers are formed using different chemical vapor deposition processes. 4. The method of claim 2 , wherein the first and third oxide-based passivation layers are formed using different chemical vapor deposition processes. 5. The method of claim 2 , wherein the second and third oxide-based passivation layers are formed using a same chemical vapor deposition process. 6. The method of claim 2 , wherein the first oxide-based passivation layer is formed using a high density plasma chemical vapor deposition (HDPCVD). 7. The method of claim 2 , wherein the second and third oxide-based passivation layers are formed using plasma enhanced chemical vapor deposition (PECVD). 8. The method of claim 1 , further comprising: removing portions of the first and second oxide-based passivation layers to expose the metal pad; forming a post passivation interconnect (PPI) layer on the metal pad; forming a buffer layer over the PPI layer; forming a second opening in the buffer layer; forming an under bump metallurgy (UBM) layer in the second opening of the buffer layer and in contact with the PPI layer; and forming a solder ball on the UBM layer. 9. A method, comprising: forming a bottom passivation layer on a dielectric layer over a semiconductor substrate; forming a first opening in the bottom passivation layer to expose a portion of the dielectric layer; forming a metal pad in the first opening and over the bottom passivation layer; depositing a first oxide-based passivation layer over the metal pad at a first deposition rate; and depositing a second oxide-based passivation layer over the first oxide-based passivation layer at a second deposition rate faster than the first deposition rate. 10. The method of claim 9 , wherein depositing the second oxide-based passivation layer is performed such that the second oxide-based passivation layer has a thickness less than a thickness of the first oxide-based passivation layer. 11. The method of claim 9 , further comprising: prior to depositing the first oxide-based passivation layer, depositing a third oxide-based passivation layer over the metal pad at a third deposition rate faster than the first deposition rate. 12. The method of claim 11 , wherein depositing the first oxide-based passivation layer is performed such that a thickness of the first oxide-based passivation layer is greater than a thickness of the third oxide-based passivation layer. 13. The method of claim 11 , wherein depositing the second and third oxide-based passivation layers is performed by using silane and N 2 O as precursors. 14. The method of claim 9 , wherein depositing the first oxide-based passivation layer is performed using silane and O 2 as precursors. 15. The method of claim 9 , further comprising: forming a nitride-based passivation layer over the second oxide-based passivation layer. 16. A semiconductor die, comprising: a semiconductor substrate; a dielectric layer over the semiconductor substrate; a metal structure in the dielectric layer; a first metal pad over the metal structure; a first oxide-based passivation layer over the first metal pad; a second oxide-based passivation layer over the first oxide-based passivation layer and having a hardness less than a hardness of the first oxide-based passivation layer; and a bump electrically connected to the first metal pad. 17. The semiconductor die of claim 16 , further comprising a nitride-based passivation layer over the second oxide-based passivation layer. 18. The semiconductor die of claim 16 , wherein a thickness of the first oxide-based passivation layer is greater than a thickness of the second oxide-based passivation layer. 19. The semiconductor die of claim 17 , further comprising: a third oxide-based passivation layer between the first metal pad and the first oxide-based passivation layer and having a hardness less than the hardness of the first oxide-based passivation layer. 20. The semiconductor die of claim 16 , further comprising: a second metal pad under the first oxide-based passivation layer and separated from the first metal pad, the second metal pad having a bottom higher than a bottom of the first metal pad.
the compound being a silane, e.g. disilane, methylsilane or chlorosilane · CPC title
deposition by cyclic CVD, e.g. ALD, ALE or pulsed CVD · CPC title
in the presence of a plasma [PECVD] · CPC title
Bond pads specially adapted therefor · CPC title
the encapsulations being multilayered · CPC title
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