Coated article resistant to corrosion with nano-crystalline layer
US-2018312976-A1 · Nov 1, 2018 · US
US10752999B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10752999-B2 |
| Application number | US-201715458489-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 14, 2017 |
| Priority date | Apr 18, 2016 |
| Publication date | Aug 25, 2020 |
| Grant date | Aug 25, 2020 |
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An article that includes a structured substrate having a macro-porous structure that defines a plurality of pores, and a metallic nano-crystalline coating on at least a portion of the structured substrate, where the metallic nano-crystalline coating defines an average grain size less than about 20 nanometers.
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What is claimed is: 1. An article comprising: a structured substrate having a macro-porous structure that defines a plurality of pores; and a metallic nano-crystalline coating on at least a portion of the structured substrate, wherein the metallic nano-crystalline coating defines an average grain size less than about 20 nanometers, wherein the metallic nano-crystalline coating comprises an overall thickness measured normal to an exterior surface of the structured substrate, and wherein the overall thickness is selectively varied on different regions of the structured substrate. 2. The article of claim 1 , wherein the article comprises an aerospace component comprising at least one of a compressor vane, a turbine blade, a rotor, a disc, a housing element, a bracket, a chevron ventilation outlet, a vane box plume tab, a variable vane actuator arm, a nose cone, an airfoil, a flap, an accessory gear, or an air-flow surface. 3. The article of claim 1 , wherein the structured substrate comprises a metal-based foam, a lattice structure, or a truss structure. 4. The article of claim 1 , wherein the structured substrate comprises one or more metals selected from the group consisting of aluminum, titanium, stainless steel, nickel, or cobalt. 5. The article of claim 1 , wherein the structured substrate comprises a polymer selected from the group consisting of a polyether ether ketone (PEEK), a polyamide (PA), a polyimide (PI), a bis-maleimide (BMI), an epoxy, a phenolic polymer, a polyester, a polyurethane, or a silicone rubber. 6. The article of claim 1 , further comprising a polymeric material, wherein the polymeric material at least partially fills the plurality of pores. 7. The article of claim 1 , wherein the metallic nano-crystalline coating comprises: a first layer comprising nano-crystalline cobalt defining a first thickness; and a second layer comprising nano-crystalline nickel defining a second thickness, wherein the first thickness is greater than the second thickness. 8. An article comprising: a structured substrate comprising a metal-based foam or a lattice structure, wherein the structured substrate comprises at least one of: a metal selected from the group consisting of aluminum, titanium, stainless steel, nickel, or cobalt, or a polymer selected from the group consisting of a polyether ether ketone (PEEK), a polyamide (PA), a polyimide (PI), a bis-maleimide (BMI), an epoxy, a phenolic polymer, a polyester, a polyurethane, or a silicone rubber; and a metallic nano-crystalline coating on at least a portion of the structured substrate, wherein the metallic nano-crystalline coating defines an average grain size less than about 20 nanometers, and wherein the metallic nano-crystalline coating includes one or more layers comprising a nano-crystalline metal selected from the group consisting of cobalt, nickel, copper, iron, cobalt-based alloy, nickel-based alloy, copper-based alloy, or iron-based alloy. 9. The article of claim 8 , wherein the structured substrate comprises the metal-based foam comprising a plurality of pores, the article further comprising a polymeric material deposited on the metal-based foam, wherein the polymeric material at least partially fills the plurality of pores. 10. The article of claim 9 , wherein the polymeric material forms a layer on the metal-based foam between the metallic nano-crystalline coating and the metal-based foam. 11. The article of claim 8 , wherein the structured substrate comprises the lattice structure, the article further comprising a metallic nano-crystalline layer deposited on an interior portion of the lattice structure. 12. The article of claim 11 , the article further comprising a polymeric material deposited in an interior portion of the lattice structure. 13. The article of claim 8 , wherein the metallic nano-crystalline coating comprises: a first metallic nano-crystalline layer defining a first thickness; and a second metallic nano-crystalline layer defining a second thickness, wherein the first thickness is different than the second thickness. 14. A method for forming an aerospace component comprising: forming a structured substrate having a macro-porous structure that defines a plurality of pores; depositing a polymeric material on the structured substrate, wherein the polymeric material at least partially fills the plurality of pores; and depositing a metallic nano-crystalline coating on at least one of at least a portion of the structured substrate or at least a portion the polymeric material, wherein the metallic nano-crystalline coating defines an average grain size less than about 20 nanometers. 15. The method of claim 14 , wherein forming a structured substrate comprises: combining a molten metal or a molten metal alloy and a foaming agent to form a metal-based foam. 16. The method of claim 14 , wherein forming a structured substrate comprises: forming a lattice structure, and depositing a metallic nano-crystalline layer on an interior portion of the lattice structure. 17. The method of claim 14 , further comprising selectively varying a thickness of the metallic nano-crystalline coating as measured normal to an exterior surface of the structured substrate.
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