Method and apparatus for recycling lithium-ion batteries

Patent metadata

Field	Value
Publication number	US-9834827-B2
Application number	US-201313855994-A
Country	US
Kind code	B2
Filing date	Apr 3, 2013
Priority date	Apr 4, 2012
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

Cathode material from exhausted lithium ion batteries are dissolved in a solution for extracting the useful elements Co (cobalt), Ni (nickel), Mn (manganese), Li (lithium), and Fe (iron) to produce active cathode materials for new batteries. The solution includes compounds of desirable materials such as cobalt, nickel and manganese dissolved as compounds from the exhausted cathode material of spent cells. Depending on a desired proportion, or ratio, of the desired materials, raw materials are added to the solution to achieve the desired ratio of the commingled compounds for the recycled cathode material for new cells. The desired materials precipitate out of solution without extensive heating or separation of the desired materials into individual compounds or elements. The resulting active cathode material has the predetermined ratio for use in new cells, and avoids high heat typically required to separate the useful elements because the desired materials remain commingled in solution.

First claim

What is claimed is:

1. A method of recycling batteries comprising:
removing solid battery components including casing and electrode materials from exhausted lithium ion batteries (LIBs) by physical separation resulting in a granular mass of spent charge materials including manganese, cobalt, and nickel;
combining sulfuric acid and hydrogen peroxide with the granular mass to obtain a solution having a pH in the range of 3-5 to precipitate impurities including Fe(OH) 3 ;
adding NiSO 4 , MnSO 4 , CoSO 4 to the solution; and
adding a strong base to the solution to coprecipitate hydroxides of Ni, Mn and Co for a cathode material precursor.

2. The method of claim 1 further comprising maintaining a temperature of the solution sufficiently low to maintain a structure of the cathode material precursor for the recycled battery.

3. The method of claim 1 wherein adding the CoSO 4 , NiSO 4 , MnSO 4 includes adding quantities of the CoSO 4 , NiSO 4 , MnSO 4 without separately precipitating the Mn, Co, Ni present in the solution.

4. The method of claim 1 wherein adjusting the pH includes adding sodium hydroxide to the solution for raising the pH to permit precipitation of hydroxides including Ni, Mn and Co, for use as cathode material.

5. The method of claim 3 wherein substantially pure forms of the CoSO 4 , NiSO 4 , MnSO 4 are added.

6. The method of claim 1 wherein coprecipitation of the hydroxides of Ni, Mn and Co occurs at temperatures below 80 degrees C.

7. The method of claim 1 wherein the hydroxides of Mn, Co, Ni are in a 1:1 molar ratio of Li to Ni 1/3 Mn 1/3 Co 1/3 .

8. The method of claim 1 wherein sintering the hydroxides of Ni, Mn and Co with lithium carbonate results in LiNi 1/3 Mn 1/3 Co 1/3 O 2 .

9. The method of claim 1 , wherein the strong base raises the pH of the solution to a range between 10.5-13.0.

10. The method of claim 1 further comprising sintering the cathode material precursor with lithium carbonate to obtain charge material for the recycled battery.

11. In a battery recycling environment having exhausted lithium ion batteries for recycling into charge material for recycled batteries, the exhausted lithium ion batteries having charge materials including at least nickel, manganese and cobalt, a method for forming a charge material precursor for a recycled battery, the method comprising:
removing solid battery components including casing and electrode materials from exhausted lithium ion batteries by physical separation resulting in a granular mass of spent charge materials;
combining sulfuric acid and hydrogen peroxide with the granular mass to obtain a solution having a pH in the range of 3-5 to precipitate impurities including Fe(OH) 3 ;
adding NiSO 4 , MnSO 4 , CoSO 4 ; and
adding sodium hydroxide to the solution to coprecipitate a cathode material precursor in the form of hydroxides of Co, Ni and Mn by raising the pH to a range between 10.5-13.0; and
sintering the cathode material precursor with lithium carbonate to obtain cathode material.

Assignees

• Wang Yan
• Apelian Diran
• Zou Haiyang
• Worcester Polytech Inst

Inventors

• Wang Yan
• Apelian Diran
• Zou Haiyang

Classifications

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title

• C22B7/006

  Wet processes · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• C22B3/02 Primary

  Apparatus therefor · CPC title