Multi-component solid epoxy proppant binder resins

Patent metadata

Field	Value
Publication number	US-10738583-B2
Application number	US-201715672398-A
Country	US
Kind code	B2
Filing date	Aug 9, 2017
Priority date	Aug 21, 2016
Publication date	Aug 11, 2020
Grant date	Aug 11, 2020

Abstract

Methods and materials for sand control in water injection sites are disclosed. Proppant particles may be coated with some particles coated with a solid epoxy and other proppant particles coated with a solid epoxy curative (such as amine, hydroxyl, carboxyl, anhydride) that would bind the particles through an epoxy reaction. The invention may be advantageous for forming underground structures useful in the extraction of hydrocarbons.

First claim

What is claimed:

1. A proppant network structure kit, comprising:
a first container comprising a first resin coated proppant wherein a reactive component in the coating on the first resin coated proppant consists essentially of one or more epoxides; and
a second container comprises a second resin coated proppant wherein a reactive component in the resin coating on the second resin coated proppant consists essentially of one or more amines, amides, imidazoles or combinations thereof,
wherein the ratio of the number of first resin coated proppant particles to second resin coated proppant particles is in the range of 2:1 to 1:2.

2. A slurry, comprising:
a first resin coated proppant, a second resin coated proppant, and a carrier fluid;
wherein a reactive component in the resin coating on the first coated proppant consists essentially of one or more epoxy moieties and wherein a reactive component in the resin coating on the second coated proppant consists essentially of one or more amine, amide, imidazole or combinations thereof,
wherein the ratio of the number of first resin coated proppant particles to second resin coated proppant particles is in the range of 2:1 to 1:2.

3. A resin coated proppant composition, comprising:
first resin coated proppant particles and second resin coated proppant particles;
wherein a reactive component in the resin coating on the first coated proppant consists essentially of one or more epoxy moieties and wherein a reactive component in the resin coating on the second coated proppant consists essentially of one or more amine, amide, imidazole or combinations thereof,
wherein the ratio of the number of first resin coated proppant particles to second resin coated proppant particles is in the range of 2:1 to 1:2.

4. The resin coated proppant composition of claim 3 wherein the first and/or second resin coated proppant particles comprise a water-soluble release coating.

5. The proppant network structure kit of claim 1 wherein the first resin coated proppant comprises epoxy novolacs.

6. The proppant network structure kit of claim 1 wherein the second resin coated proppant is selected from the group consisting of primary amines, secondary amines, and combinations thereof.

7. The proppant network structure kit of claim 1 wherein the resin coatings on the first and second particles have thicknesses in the range of 10 μm to 200 μm.

8. The slurry of claim 2 wherein the slurry comprises hydroxyethyl cellulose (HEC) gel but not crosslinked Guar gel.

9. The slurry of claim 2 wherein the proppants are selected from the group consisting of silica proppants, ceramic proppants, metallic proppants, synthetic organic proppants, sintered bauxite, and combinations thereof.

10. The slurry of claim 2 wherein the proppants comprise naturally occurring particulate materials selected from the group consisting of pebbles, gravel, sand and combinations thereof.

11. The slurry of claim 2 wherein the proppants comprise natural products selected from the group consisting of nut shells, fruit shells and combinations thereof.

12. The resin coated proppant composition of claim 3 wherein the ratio of the number of first resin coated proppant particles to second resin coated proppant particles is within 10% of a 1:1 ratio.

13. The resin coated proppant composition of claim 3 wherein the proppants have a mesh size in the range of 20 to 40.

14. The resin coated proppant composition of claim 3 wherein the resin coatings on the first and second particles have thicknesses in the range of 20 μm to 150 μm.

15. The resin coated proppant composition of claim 3 wherein the resin coating on the first coated proppant comprises an epoxy novolac.

16. The resin coated proppant composition of claim 3 wherein the resin coating on the second coated proppant comprises a polyester.

Assignees

• Battelle Memorial Institute

Inventors

• Elhard Joel D
• Denen Phillip N
• Whitmore Robert S

Classifications

• C08L63/00 Primary

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C08G59/5073

  having two nitrogen atoms in the ring · CPC title

• C09K8/5756

  containing cross-linking agents · CPC title

• C08G59/42

  Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof · CPC title

• C08G59/66

  Mercaptans · CPC title