Methods for modification of aramid fibers

Patent metadata

Field	Value
Publication number	US-10738418-B2
Application number	US-201615752955-A
Country	US
Kind code	B2
Filing date	Aug 18, 2016
Priority date	Aug 18, 2015
Publication date	Aug 11, 2020
Grant date	Aug 11, 2020

Abstract

Methods are described for treatment of aramid fibers to modify the surface of the fibers. The treated fibers have improved adhesion to elastomer materials as compared to untreated fibers. Modification methods include irradiating the fibers, compressing and straining the fibers under a constant pull force and immersing the fibers in a coupling agent fluid. The treated fibers can be used with elastomers and provide reinforcement elements in products such as tires.

First claim

What is claimed is:

1. A method for modifying the surface of an aramid fiber, the method comprising:
a. contacting the aramid fiber with an acid solution to modify the surface of the aramid fiber to form a pre-treated aramid fiber;
b. removing the aramid fiber of step (a) from the acid solution and immersing the pre-treated aramid fiber in a liquid;
c. irradiating the immersed pre-treated aramid fiber in the liquid in a microwave oven with microwave energy for a period of at least 15 seconds at a power level of at least 60 Watts to modify the surface of the aramid fiber, wherein the irradiating forms blisters on the surface of the pre-treated aramid fiber; and
d. removing the aramid fiber from the liquid.

2. The method of claim 1 , the aramid fiber being poly(paraphenylene terephthalamide) or poly(metaphenylene isophthalamide).

3. The method of claim 1 , the aramid fiber being in contact with the acid solution for a period of 20 minutes to 2 hours.

4. The method of claim 1 , the liquid of step (b) comprising water.

5. The method of claim 1 , step (c) comprising irradiating the pre-treated aramid fiber at a power level of 100 Watts to 1,000 Watts.

6. The method of claim 1 , further comprising contacting the aramid fiber of step (d) with a coupling agent.

7. The method of claim 6 , the coupling agent being a vinyl-substituted compound.

8. The method of claim 7 , the vinyl-substituted compound being a cyclic compound having two or more vinyl groups.

9. The method of claim 6 , the coupling agent being vinyl-substituted low molecular weight silicone having a molecular weight (M w ) of less than 1000.

10. The method of claim 6 , the coupling agent being a cyclic compound having a branched alkyl substituent.

11. The method of claim 6 , the coupling agent being mixed with a solvent.

12. The method of claim 11 , the solvent being supercritical carbon dioxide.

13. The method of claim 6 , the aramid fiber of step (d) being immersed in the coupling agent fluid for a period of 30 minutes to 2 hours, wherein the aramid fiber has an adhesion greater than 0.8 MPa to a rubber composition as determined by TEST #1.

14. The aramid fiber of claim 1 , the blisters extending outward from the surface of the aramid fiber.

Assignees

• Univ Of Massachusetts Amherst
• Bridgestone Corp

Inventors

• Kanbargi Nihal
• Lesser Alan J
• Zhao Wei
• Agarwal Sheel P
• Rackaitis Mindaugas

Classifications

• D06M2101/36

  Aromatic polyamides · CPC title

• D06M23/105

  Processes in which the solvent is in a supercritical state · CPC title

• D06M13/5135

  Unsaturated compounds containing silicon atoms · CPC title

• D06M13/07 Primary

  Aromatic hydrocarbons · CPC title

• D06M10/08

  Organic compounds · CPC title