Lubricating oil compositions with engine wear protection

Patent metadata

Field	Value
Publication number	US-10738262-B2
Application number	US-201816151481-A
Country	US
Kind code	B2
Filing date	Oct 4, 2018
Priority date	Oct 30, 2017
Publication date	Aug 11, 2020
Grant date	Aug 11, 2020

Abstract

A method for improving wear control of a steel surface lubricated with a lubricating oil through the generation of thick tribofilms. The method includes: (i) using as the lubricating oil a formulated oil, the formulated oil having a composition comprising at least one lubricating oil base stock as a major component; and at least one lubricating oil additive, as a minor component; and (ii) forming a tribofilm on the steel surface. In time-step tribofilm formation measurements of the lubricating oil by a mini-traction machine (MTM) at constant slide-to-roll ratio (SRR), the saturation traction coefficient (f s ), which correlates to tribofilm thickness on the steel surface, is greater than about 0.11. In the method of this disclosure, elongation of timing chain due to wear of chain link pins is less than about 0.07%, as determined by Ford Chain Wear (FCW) test conducted in accordance with ILSAC GF-6 specification. The lubricating oils are useful in internal combustion engines.

First claim

The invention claimed is:

1. A method for improving wear control of a steel surface lubricated with a lubricating oil, said method comprising: (i) using as the lubricating oil a formulated oil, said formulated oil having a composition comprising at least one lubricating oil base stock as a major component; and at least one lubricating oil additive, as a minor component; and (ii) forming a tribofilm on the steel surface having a saturation traction coefficient (f s ), which correlates to the tribofilm thickness on the steel surface, of greater than about 0.11, as measured in a ball-on-disk tribological test by a mini-traction machine (MTM) at constant slide-to-roll ratio (SRR), wherein the at least one lubricating oil base stock has an aniline point greater than about 10° C., or a mixed aniline point greater than about 35° C., as determined by ASTM D611.

2. The method of claim 1 wherein elongation of timing chain due to wear of chain link pins is less than about 0.07%, as determined by Ford Chain Wear (FCW) test in accordance with ILSAC GF-6 specification.

3. The method of claim 1 wherein the lubrication regime at the steel surface comprises boundary- and mixed-layer lubrication contacts.

4. The method of claim 1 wherein the steel surface comprises the surface of a timing chain.

5. The method of claim 1 for improving soot-induced wear control of a steel surface.

6. The method of claim 1 wherein the at least one lubricating oil additive comprises a dispersant, a detergent, or mixtures thereof.

7. The method of claim 6 wherein the dispersant comprises a borated or non-borated, hydrocarbyl-substituted succinic acid, a borated or non-borated, hydrocarbyl-substituted succinic anhydride derivative, or mixtures thereof.

8. The method of claim 6 wherein the dispersant comprises a borated succinimide, a non-borated succinimide, or mixtures thereof.

9. A method for improving wear control of a steel surface lubricated with a lubricating oil, said method comprising:
(i) using as the lubricating oil a formulated oil, said formulated oil having a composition comprising at least one lubricating oil base stock as a major component; and at least one borated dispersant, as a minor component; and
(ii) forming a tribofilm on the steel surface having a saturation traction coefficient (f s ), which correlates to the tribofilm thickness on the steel surface, of greater than about 0.11, as measured in a ball-on-disk tribological test by a mini-traction machine (MTM) at constant slide-to-roll ratio (SRR),
wherein the at least one lubricating oil base stock has an aniline point greater than about 10° C., or a mixed aniline point greater than about 35° C., as determined by ASTM D611, and wherein the borated dispersant is present in an amount sufficient to provide a total boron concentration of about 200 to about 800 parts per million in the lubricating oil.

10. The method of claim 6 wherein the detergent comprises an alkaline earth metal salicylate, an alkaline earth metal sulfonate, or mixtures thereof.

11. The method of claim 6 wherein the detergent comprises an alkaline earth metal salicylate, a mixture of alkaline earth metal salicylates, an alkaline earth metal sulfonate, a mixture of alkaline earth metal sulfonates, or a mixture of alkaline earth metal salicylates and alkaline earth metal sulfonates, all having the same or different total base number (TBN).

12. The method of claim 6 wherein, for a mixture of alkaline earth metal salicylates and alkaline earth metal sulfonates, all having the same or different total base number (TBN), the weight ratio of alkaline earth metal salicylates to alkaline earth metal sulfonates is from about 1:100 to about 100:1.

13. The method of claim 6 wherein, for a mixture of alkaline earth metal salicylates having the same or different total base number (TBN), the weight ratio of a first alkaline earth metal salicylate to a second alkaline earth metal salicylate is from about 1:100 to about 100:1; or wherein, for a mixture of alkaline earth metal sulfonates having the same or different total base number (TBN), the weight ratio of a first alkaline earth metal sulfonate to a second alkaline earth metal sulfonate is from about 1:100 to about 100:1.

14. The method of claim 6 wherein the total amount of soap delivered by the detergent is about 0.5 weight percent to about 0.8 weight percent of the lubricating oil.

15. The method of claim 1 wherein the at least one lubricating oil base stock comprises an ester base stock, an alkylated naphthalene base stock, or mixtures thereof.

16. The method of claim 1 wherein the lubricating oil base stock further comprises a Group I, Group II, Group III, Group IV or Group V base oil.

17. The method of claim 1 wherein the at least one lubricating oil additive is present in an amount of from about 0.001 weight percent to about 20 weight percent, based on the total weight of the formulated oil.

18. The method of claim 1 wherein the lubricating oil base stock is present in an amount of from about 6 weight percent to about 95 weight percent, based on the total weight of the formulated oil.

19. The method of claim 1 wherein the formulated oil further comprises one or more of an antiwear additive, other viscosity modifiers, antioxidant, other detergent, other dispersant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, and anti-rust additive.

20. The method of claim 1 wherein the lubricating oil is a passenger vehicle engine oil (PVEO).

21. A lubricating oil composition comprising at least one lubricating oil base stock as a major component; and at least one lubricating oil additive, as a minor component; wherein the at least one lubricating oil base stock and the at least one lubricating oil additive are present in an amount to form a tribofilm on a steel surface having a saturation traction coefficient (f s ), which correlates to the tribofilm thickness on the steel surface, of greater than about 0.11, as measured in a ball-on-disk tribological test by a mini-traction machine (MTM) at constant slide-to-roll ratio (SRR).

22. The method of claim 9 wherein elongation of timing chain due to wear of chain link pins is less than about 0.07%, as determined by Ford Chain Wear (FCW) test conducted in accordance with ILSAC GF-6 specification.

23. The method of claim 9 wherein the lubrication regime at the steel surface comprises boundary- and mixed-layer lubrication contacts.

24. The method of claim 9 wherein the steel surface comprises the surface of a timing chain.

25. The method of claim 9 wherein at least one borated dispersant comprises a borated hydrocarbyl-substituted succinic acid, a borated hydrocarbyl-substituted succinic anhydride derivative, or mixtures thereof.

26. The method of claim 9 wherein the at least one borated dispersant comprises a borated succinimide, or mixtures thereof.

27. The method of claim 9 wherein the borated dispersant is present in an amount sufficient to provide a total boron concentration of about 250 to about 750 parts per million in the lubricating oil.

28. The method of claim 9 wherein the lubricating oil base stock further comprises a Group I, Group II, Group III, Group IV or Group V base oil.

29. The method of claim 9 wherein the at least one borated dispersant is present in an amount of from

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Pelligra Candice I
• Dance Smruti A
• Deckman Douglas E
• Kennedy Steven

Classifications

• C10M159/20 Primary

  Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products · CPC title

• C10M129/54

  containing hydroxy groups · CPC title

• C10M2203/1025

  used as base material · CPC title

• C10M2219/044

  Sulfonic acids, Derivatives thereof, e.g. neutral salts · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title