Method of fabricating a ceramic from a chemical reaction

Patent metadata

Field	Value
Publication number	US-10723658-B2
Application number	US-201616064544-A
Country	US
Kind code	B2
Filing date	Dec 20, 2016
Priority date	Dec 21, 2015
Publication date	Jul 28, 2020
Grant date	Jul 28, 2020

Abstract

A method of fabricating a ceramic material, the method including forming a ceramic material by performing a first chemical reaction at least between a first powder of an intermetallic compound and a reactive gas phase, a liquid phase being present around the grains of the first powder during the first chemical reaction, the liquid gas phase being obtained from a second powder of a metallic compound by melting the second powder or as a result of a second chemical reaction between at least one element of the first powder and at least one metallic element of the second powder, a working temperature being imposed during the formation of the ceramic material, which temperature is low enough to avoid melting the first powder.

First claim

The invention claimed is:

1. A method of fabricating a turbomachine element including a step of fabricating a ceramic material to form said turbomachine element, the ceramic material being fabricated by performing a method comprising
forming the ceramic material by performing a first chemical reaction at least between a first powder of a metallic disilicide MSi 2 where M is a transition metal and a reactive gas phase, the first chemical reaction being a nitriding reaction and the reactive gas phase comprising the element N or the first chemical reaction being a carburizing reaction and the reactive gas phase comprising the element C, a liquid phase obtained from a second powder being present around the grains of the first powder during the first chemical reaction, a working temperature being imposed during the formation of the ceramic material, which temperature is low enough to avoid melting the first powder, and one of the two following characteristics being true:
the second powder is a powder of nickel and the liquid phase is obtained as a result of a second chemical reaction between at least one element of the first powder and the nickel of the second powder, and when M is Ti, the ceramic material comprises a Ni 4 Ti 4 Si 7 phase, and is free of free silicon, TiSi 2 or NiSi/NiSi 2 , or
the second powder is a powder of an alloy of aluminum and of silicon AlSi13 comprising substantially 13% by weight silicon and the liquid phase is obtained by melting by said alloy of aluminum and of silicon.

2. A method according to claim 1 , wherein the first powder is a powder of TiSi 2 , a powder of CrSi 2 , a powder of ZrSi 2 , or a powder of VSi 2 .

3. A method according to claim 2 , wherein the first powder is a powder of TiSi 2 and the second powder is a powder of nickel.

4. A method according to claim 2 , wherein the first powder is a powder of ZrSi 2 and the second powder is a powder of the alloy of aluminum and of silicon AlSi13.

5. A method according to claim 1 , wherein, prior to beginning the first chemical reaction, the quantity of material of the first powder is greater than the quantity of material of the second powder.

6. A method according to claim 5 , wherein, prior to starting the first chemical reaction, the following conditions are satisfied:
the ratio of (the quantity of material of the first powder) divided by (the quantity of material of the first powder plus the quantity of material of the second powder) is greater than 0.825 and less than 0.925; and
the ratio of (the quantity of material of the second powder) divided by (the quantity of material of the first powder plus the quantity of material of the second powder) is greater than 0.075 and less than 0.175.

7. A method according to claim 1 , wherein the reactive gas phase comprises at least one of the following gases: NH 3 , N 2 , a gaseous hydrocarbon, or tetramethylsilane.

8. A method according to claim 1 , wherein the working temperature is less than or equal to 1150° C. and/or the first chemical reaction is performed at a pressure lying in the range 3 mbar to 10 bar.

9. A method according to claim 1 , wherein the turbomachine element is a ceramic matrix composite material part and wherein the ceramic material is formed in the pores of a fiber preform.

10. A method according to claim 1 , wherein the turbomachine element is a ceramic material block.

11. A method according to claim 1 , wherein the ceramic material forms a coating present on a surface of the turbomachine element.

12. A ceramic material essentially comprising TiN, Si 3 N 4 , and Ni 4 Ti 4 Si 7 , and presenting a weight content of residual free silicon less than or equal to 1% the ceramic material obtained by carrying out a method comprising:
forming the ceramic material by performing a first chemical reaction at least between a first powder of a metallic disilicide MSi 2 where M is a transition metal and a reactive gas phase, the first chemical reaction being a nitriding reaction and the reactive gas phase comprising the element N or the first chemical reaction being a carburizing reaction and the reactive gas phase comprising the element C, a liquid phase obtained from a second powder being present around the grains of the first powder during the first chemical reaction, a working temperature being imposed during the formation of the ceramic material, which temperature is low enough to avoid melting the first powder, the second powder being a powder of nickel and the liquid phase is obtained as a result of a second chemical reaction between at least one element of the first powder and the nickel of the second powder; and when M is Ti, the ceramic material comprises a Ni 4 Ti 4 Si 7 phase, and is free of free silicon, TiSi 2 or NiSi/NiSi 2 .

13. A ceramic matrix composite material part comprising:
fiber reinforcement; and
a matrix present in the pores of the fiber reinforcement, the matrix comprising a ceramic material according to claim 12 .

14. A turbomachine including a ceramic material according to claim 12 .

15. A turbomachine including a part according to claim 13 .

Assignees

• Safran Ceram
• Centre Nat Rech Scient

Inventors

• Maille Laurence
• Roger Jérôme
• Le Petitcorps Yann
• Reignier Bernard

Classifications

• C04B35/80

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• C04B35/62863

  Silicon carbide · CPC title

• C04B35/58007

  based on refractory metal nitrides · CPC title

• F05D2300/177

  Ni - Si alloys · CPC title

• C04B2235/5454

  nanometer sized, i.e. below 100 nm · CPC title