Process for fabricating composite parts by low melting point impregnation

Patent metadata

Field	Value
Publication number	US-10011902-B1
Application number	US-201414906959-A
Country	US
Kind code	B1
Filing date	Jul 15, 2014
Priority date	Jul 23, 2013
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

A method of fabricating a composite material part, the method including making a consolidated fiber preform, the fibers of the preform being carbon or ceramic fibers and being coated with an interphase; obtaining a consolidated and partially densified fiber preform, the partial densification comprising using chemical vapor infiltration to form a first matrix phase on the interphase; and continuing densification of the fiber preform by infiltrating an infiltration composition containing at least silicon and at least one other element suitable for lowering the melting temperature of the infiltration composition to a temperature less than or equal to 1150° C.

First claim

The invention claimed is:

1. A method of fabricating a composite material part, the method comprising:
making a consolidated fiber preform, wherein fibers of the consolidated fiber preform comprising one of: carbon fibers or ceramic fibers, and wherein the fibers are coated with an interphase;
obtaining a consolidated and partially densified fiber preform, wherein the consolidated and partially densified fiber preform is obtained by using chemical vapor infiltration to form a first matrix phase on the interphase of the consolidated fiber preform; and
continuing densification of the consolidated and partially densified fiber preform by infiltrating the consolidated and partially densified fiber preform with an infiltration composition containing at least silicon and nickel suitable for lowering the melting temperature of the infiltration composition to a temperature less than or equal to 1150° C., wherein a first proportion by weight of nickel in the infiltration composition is within a first range of 54% to 75%.

2. A method according to claim 1 , wherein:
the infiltration composition further includes germanium; and
a second proportion by weight of germanium in the infiltration composition is in a second range 89% to 98%.

3. A method according to claim 1 , wherein the infiltration composition includes less than 10% by weight of at least one: aluminum and boron.

4. A method according to claim 1 , wherein the consolidated fiber preform is made of carbon fibers or silicon carbide (SiC) fibers.

5. A method according to claim 1 , wherein the consolidated fiber preform is formed as a fiber structure made as a single part by three-dimensional or multilayer weaving or from a plurality of two-dimensional fiber plies.

6. A method according to claim 1 , wherein the interphase is formed by at least one layer of any one of the following materials: pyrolytic carbon (PyC), boron-doped carbon (BC), and boron nitride (BN).

7. A method according to claim 6 , wherein the first matrix phase comprises at least one layer of a material selected from at least one of the following materials: a self-healing material, silicon nitride (Si 3 N 4 ), and silicon carbide (SiC).

8. A method according to claim 7 , wherein the first matrix phase includes at least one layer of self-healing material selected from a ternary Si—B—C system and boron carbide B 4 C.

9. A method according to claim 1 , wherein the first matrix phase comprises a plurality of layers of self-healing material alternating with one or more layers of material selected from pyrolytic carbon (PyC), boron-doped carbon (BC), and a ceramic material that does not contain boron.

10. A method according to claim 1 , wherein, after partial densification of the consolidated fiber preform and before densification of the consolidated and partially densified fiber preform by infiltration with the infiltration composition, the method further comprises:
modifying an array of pores within the consolidated and partially densified fiber preform by one of:
dispersing a powder of at least one of the following materials within the consolidated and partially densified fiber preform: silicon carbide (SiC); silicon nitride (Si 3 N 4 ); carbon (C); boron (B); boron carbide (B 4 C); and titanium carbide (TiC);
introducing a ceramic or a carbon phase within the consolidated and partially densified preform by impregnating the consolidated and partially densified preform with a polymer, and pyrolyzing the polymer; or
introducing a carbon or ceramic foam within the consolidated and partially densified preform by impregnating the consolidated and partially densified preform with a polymer, and pyrolyzing the polymer.

11. A method of fabricating a composite material part, the method comprising:
making a consolidated fiber preform, wherein fibers of the consolidated fiber preform comprising one of: carbon fibers or ceramic fibers, and wherein the fibers are coated with an interphase;
obtaining a consolidated and partially densified fiber preform, wherein the consolidated and partially densified fiber preform is obtained by using chemical vapor infiltration to form a first matrix phase on the interphase of the consolidated fiber preform; and
continuing densification of the consolidated and partially densified fiber preform by infiltrating the consolidated and partially densified fiber preform with an infiltration composition containing at least silicon and germanium suitable for lowering the melting temperature of the infiltration composition to a temperature less than or equal to 1150° C., wherein a first proportion by weight of germanium in the infiltration composition is within a first range of 89% to 98%.

12. A method according to claim 11 , wherein:
the infiltration composition further comprises nickel having a second proportion by weight in the infiltration composition in a second range of 50% to 75%.

13. A method according to claim 11 , wherein the infiltration composition further includes less than 10% by weight of at least one of: aluminum and boron.

14. A method according to claim 11 , wherein the consolidated fiber preform is made of carbon fibers or silicon carbide (SiC) fibers.

15. A method according to claim 11 , wherein the consolidated fiber preform is formed as a fiber structure made as a single part by three-dimensional or multilayer weaving or from a plurality of two-dimensional fiber plies.

16. A method according to claim 11 , wherein the interphase is formed by at least one layer of any one of the following materials: pyrolytic carbon (PyC), boron-doped carbon (BC), and boron nitride (BN).

17. A method according to claim 16 , wherein:
the first matrix phase comprises at least one layer of a material selected from at least one of the following materials: a self-healing material, silicon nitride (Si 3 N 4 ), and silicon carbide (SiC); and
the first matrix phase includes at least one layer of self-healing material selected from a ternary Si—B—C system and boron carbide B 4 C.

18. A method according to claim 11 , wherein the first matrix phase comprises a plurality of layers of self-healing material alternating with one or more layers of material selected from pyrolytic carbon (PyC), boron-doped carbon (BC), and a ceramic material that does not contain boron.

19. A method according to claim 11 , wherein, after partial densification of the consolidated fiber preform and before densification of the consolidated and partially densified fiber preform by infiltration with the infiltration composition, the method further comprises:
modifying an array of pores within the consolidated and partially densified fiber preform by one of:
dispersing a powder of at least one of the following materials within the consolidated and partially densified fiber preform: silicon carbide (SiC); silicon nitride (Si 3 N 4 ); carbon (C); boron (B); boron carbide (B 4 C); and titanium carbide (TiC);
introducing a ceramic or a carbon phase within the consolidated and partially densified fiber preform by impregnating the consolidated and partially densified fiber preform with a polymer, and pyrolyzing the polymer; or
introducing a carbon or ceramic foam within the consolidated and partially densified fiber preform by impregnating the consolidated and partially densified fiber preform with a polymer, and pyrolyzing the polymer.

Assignees

• Herakles

Inventors

• Philippe Eric
• Bouillon Eric
• Courcot Emilie
• Jimenez Sébastien

Classifications

• C22C47/08

  by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould {(C22C47/16 takes precedence)} · CPC title

• C04B35/573 Primary

  obtained by reaction sintering {or recrystallisation} · CPC title

• C04B2235/72

  Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics · CPC title

• C04B2235/3817

  Carbides · CPC title

• C04B2235/5216

  Inorganic · CPC title