Phosphor containing Ce

Patent metadata

Field	Value
Publication number	US-10717657-B2
Application number	US-201916245101-A
Country	US
Kind code	B2
Filing date	Jan 10, 2019
Priority date	Jul 4, 2016
Publication date	Jul 21, 2020
Grant date	Jul 21, 2020

Abstract

A phosphor contains a crystal phase having a chemical composition CexM3-x-yβ6γ11-z. M is one or more elements selected from the group consisting of Sc, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. β contains Si in an amount of 50 mol % or more of a total mol of β. β further contains Al. γ contains N in an amount of 80 mol % or more N of a total mol of γ. x satisfies 0<x≤0.6. y satisfies 0≤y≤1.0. z satisfies 0≤z≤1.0.

First claim

What is claimed is:

1. A phosphor comprising a crystal phase having a chemical composition Ce x M 3-x-y β 6 γ 11-z , where
M is one or more elements selected from the group consisting of Sc, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu;
β contains Si in an amount of 50 mol % or more of a total mol of β;
β further contains Al;
γ contains N in an amount of 80 mol % or more of a total mol of γ;
0<x≤0.6;
0≤y≤1.0; and
0≤z≤1.0.

2. The phosphor according to claim 1 , wherein
the M contains La in an amount of 90 mol % or more of a total mol of M.

3. The phosphor according to claim 1 , wherein
the β contains Al in an amount of (100×/6) mol % or more of the total mol of β.

4. The phosphor according to claim 1 , wherein
the γ further contains O.

5. The phosphor according to claim 1 , wherein
the x satisfies 0.015≤x≤0.3.

6. The phosphor according to claim 1 , wherein
the crystal phase has a 1/e emission lifetime of 100 ns or less.

7. The phosphor according to claim 1 , wherein the crystal phase shows diffraction peaks in
(1) 2θ: 17.8° or more and 18.8° or less;
(2) 2θ: 26.2° or more and 27.2° or less;
(3) 2θ: 27.2° or more and 28.2° or less;
(4) 2θ: 30.5° or more and 31.5° or less
(5) 2θ: 32.8° or more and 33.8° or less; and
(6) 2θ: 35.8° or more and 36.8° or less
in an X-ray diffraction pattern measured with Cu-Kα radiation.

8. The phosphor according to claim 1 , wherein
in an EXAFS radial distribution function spectrum at K-absorption edge of Ce, a first neighbor shell of Ce has a peak having a height lower than that of a peak of a second neighbor shell of Ce.

9. The phosphor according to claim 8 , wherein
the height of the peak of the first neighbor shell is 0.8 times or more and 0.9 times or less the height of the peak of the second neighbor shell.

10. The phosphor according to claim 1 , wherein
in an EXAFS radial distribution function spectrum at K-absorption edge of Ce, the coordination number of a first neighbor shell of Ce is seven.

11. The phosphor according to claim 1 , wherein
the y is 0 and the z is 0.

12. A light-emitting apparatus comprising:
an excitation light source emitting light of a wavelength of 600 nm or less; and
a phosphor that is irradiated with the light emitted by the excitation light source and emits fluorescence having a wavelength longer than a wavelength of the light emitted by the excitation light source, wherein
the phosphor comprises a crystal phase having a chemical composition Ce x M 3-x-y β 6 γ 11-z , where
M is one or more elements selected from the group consisting of Sc, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu;
β contains Si in an amount of 50 mol % or more of a total mol of β;
β further contains Al;
γ contains N in an amount of 80 mol % or more of a total mol of γ;
0<x≤0.6;
0≤y≤1.0; and
0≤z≤1.0.

13. The light-emitting apparatus according to claim 12 , wherein
the excitation light source emits the light having a wavelength of 500 nm or more and 600 nm or less.

14. The light-emitting apparatus according to claim 12 , wherein
the excitation light source emits the light having a wavelength of 420 nm or more and 480 nm or less.

15. The light-emitting apparatus according to claim 12 , wherein
the excitation light source is an LED or an LD.

16. The light-emitting apparatus according to claim 12 , wherein
the phosphor is a first phosphor,
the light-emitting apparatus further comprises a second phosphor that is irradiated with the light emitted by the excitation light source and emits fluorescence having a wavelength longer than a wavelength of the light emitted by the excitation light source, and
the second phosphor shows a maximum peak of an emission spectrum in a wavelength range of 500 nm or more and 600 nm or less.

17. The light-emitting apparatus according to claim 16 , wherein
the second phosphor emits yellow light, and
the light-emitting apparatus further comprises a third phosphor that is irradiated with the light emitted by the excitation light source and emits green light.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Nitta Mitsuru
• Inada Yasuhisa
• Nagao Nobuaki

Classifications

• F21S41/285 Primary

  Refractors, transparent cover plates, light guides or filters not provided in groups F21S41/24 - F21S41/2805 · CPC title

• C09K11/77748

  Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides · CPC title

• C09K11/77747 Primary

  Silicon Nitrides or Silicon Oxynitrides · CPC title

• H01S5/0087

  for illuminating phosphorescent or fluorescent materials, e.g. using optical arrangements specifically adapted for guiding or shaping laser beams illuminating these materials · CPC title

• C01F17/30 Primary

  Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 (C01F17/247 - C01F17/294 take precedence) · CPC title