Phosphor and light-emitting device including the same

Patent metadata

Field	Value
Publication number	US-9725648-B2
Application number	US-201414566614-A
Country	US
Kind code	B2
Filing date	Dec 10, 2014
Priority date	Dec 10, 2013
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

A yellow phosphor is provided. The yellow phosphor includes a crystal formed of a compound that is represented by the following formula (1): Ln 4−x (Eu z M 1−z ) x Si 12−y Al y O 3+x+y N 18−x−y (0.5≦x≦3, 0<z<0.3, 0<y≦4) (1), wherein Ln includes at least one rare earth element, and M includes at least one selected from calcium (Ca), barium (Ba), strontium (Sr), and magnesium (Mg).

First claim

What is claimed is:

1. A yellow phosphor comprising:
a crystal formed of a compound that is represented by the following formula (1):
L n 4−x (Eu z M 1−z ) x Si 12−y Al y O 3+x+y N 18−x−y (0.5 ≦x≦ 3, 0 <z< 0.3, 0 <y≦ 4)  (1),

wherein Ln comprises at least rare earth element, and M comprises at least one selected from calcium (Ca), barium (Ba), strontium (Sr), and magnesium (Mg).

2. The yellow phosphor of claim 1 , wherein Ln comprises at least one selected from lanthanum (La) and Cerium (Ce).

3. The yellow phosphor of claim 1 , wherein M includes at least calcium (Ca).

4. The yellow phosphor of claim 1 , wherein the crystal is monoclinic and has a crystal structure of a space group C2.

5. The yellow phosphor of claim 1 , wherein Ln comprises a combination in which at least 70 mol % of a total amount of Ln comprises Ce and La and a remainder of the total amount of Ln comprises at least one selected from lutetium (Lu), scandium (Sc), gadolinium (Gd), and yttrium (Y).

6. The yellow phosphor of claim 1 , wherein Ln comprises at least one selected from La and Ce, and Ln further comprises at least one selected from a praseodymium ion (Pr 3+ ) and a terbium ion (Tb 3+ ).

7. The yellow phosphor of claim 1 , wherein Ln comprises at least one selected from La and Ce, and Ln further comprises at least one selected from neodymium (Nd), promethium (Pm), samarium (Sm), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), and ytterbium (Yb).

8. The yellow phosphor of claim 1 , wherein M comprises a combination in which at least 90 mol % of a total amount of M comprises Ca and a remainder of the total amount of M comprises at least one selected from Sr, Ba, and Mg.

9. A light-emitting device including a structure combining the yellow phosphor of claim 1 , a red phosphor, and a blue light-emitting diode (LED).

10. The light-emitting device of claim 9 , wherein the red phosphor comprises at least one selected from the group of CaAlSiN 3 :Eu, Sr 2 Si 5 N 8 :Eu, SrSiAl 4 N 7 :Eu, SrLiAl 3 N 4 :Eu, and K 2 SiF 6 :Mn 4+ .

11. The light-emitting device of claim 9 , wherein the light-emitting device is configured to emit light of which (x, y) coordinates of a CIE 1931 colorimetric system are positioned on a line segment, which connects (0.4476, 0.4074), (0.3484, 0.3516), (0.3101, 0.3162), (0.3128, 0.3292), and (0.3333, 0.3333), or in an area surrounded by the line segment and a black-body radiation spectrum.

12. The light-emitting device of claim 9 , wherein the light-emitting device is configured to emit light having a color temperature between 2,000K and 20,000K.

13. A light-emitting device comprising:
a light-emitting diode (LED) chip;
a resin covering at least a portion of the LED chip; and
a yellow phosphor dispersed in the resin,
wherein the yellow phosphor comprises a crystal formed of a compound that is represented by the following formula (1):
L n 4−x (Eu z M 1−z ) x Si 12−y Al y O 3+x+y N 18−x−y (0.5 ≦x< 3, 0 <z< 0.3, 0 <y≦ 4)  (1),

wherein Ln comprises at least one rare earth element, and M comprises at least one selected from calcium (Ca), barium (Ba), strontium (Sr), and magnesium (Mg).

14. The light-emitting device of claim 13 , wherein Ln comprises at least one selected from lanthanum (La) and Cerium (Ce).

15. The light-emitting device of claim 13 , wherein the crystal is monoclinic and has a crystal structure of a space group C2.

16. A light-emitting device comprising:
a light-emitting diode (LED) chip; and
a yellow phosphor disposed in a path of light emission from the LED chip, wherein the yellow phosphor comprises a crystal formed of a compound that is represented by the following formula (1):
L n 4−x (Eu z M 1−z ) x Si 12−y Al y O 3+x+y N 18−x−y (0.5 <x< 3, 0 <z< 0.3, 0 <y< 4)  (1),

wherein Ln comprises at least one rare earth element, and M comprises at least one selected from calcium (Ca), barium (Ba), strontium (Sr), and magnesium (Mg).

17. The light-emitting device of claim 16 , further comprising a lighting unit body including a reflective cup having the LED chip disposed therein and a resin disposed therein to encapsulate LED chip in the reflective cup, wherein the yellow phosphor is disposed between the LED chip and the resin, disposed on the resin or dispersed in the resin.

18. The light-emitting device of claim 16 , wherein the light-emitting device is one of a bulb-type lamp including a socket structure, a rectification circuit; a headlamp; and a backlight unit.

19. The light-emitting device of claim 16 , wherein the light-emitting device is a backlight unit in which the yellow phosphor is formed as part of a phosphorescent film, wherein the phosphorescent film is disposed on a bottom case of the backlight unit, disposed between the LED chip and a light guiding plate of the backlight unit, or disposed on a light-emitting surface of a light guiding panel of the backlight unit.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Izawa Takamasa
• Kim Dohoon
• Yoshino Masahiko
• Seto Takatoshi

Classifications

• H10W90/756

  between a chip and a stacked lead frame, conducting package substrate or heat sink · CPC title

• H10W74/00

  Encapsulations, e.g. protective coatings · CPC title

• H10W72/5363

  the connected ends being wedge-shaped · CPC title

• H10W72/01515

  Forming coatings · CPC title

• H10W72/536

  the connected ends being ball-shaped · CPC title