Method of preparing metal diboride dispersions and films

Patent metadata

Field	Value
Publication number	US-10711210-B2
Application number	US-201615775735-A
Country	US
Kind code	B2
Filing date	Nov 11, 2016
Priority date	Nov 12, 2015
Publication date	Jul 14, 2020
Grant date	Jul 14, 2020

Abstract

Some embodiments include a method of producing metal diboride nanomaterials having thickness down to the atomic scale and lateral areas from 10 nm to over 1 μm by preparing a mixture of a metal diboride and a suspending solution. The suspending solution can be an organic solvent or a solution containing water, and optionally can include a dispersion agent, such as a surfactant, a polymer, small molecule, or biopolymer. Further, the method includes exfoliating the metal diboride by exposing the mixture to ultrasonic energy, centrifuging the mixture forming supernatant that includes a dispersion of exfoliated metal diborides, and extracting the dispersion from the supernatant. Some embodiments include extracting the supernatant and casting the solution by diluting the dispersion with a second suspending solution that includes dissolved polymer. This can result in a composite film includes a dispersion of the exfoliated metal diborides and provides improved mechanical properties.

First claim

The invention claimed is:

1. A method of producing metal diboride nanomaterials comprising:
preparing a mixture of at least one metal diboride and a suspending solution, the suspending solution including at least one solvent;
at least partially exfoliating the at least one metal diboride by exposing the mixture to ultrasonic energy comprising ultrasonic vibrations;
centrifuging the mixture and forming at least a lower phase and an adjacent supernatant, the supernatant including a dispersion of exfoliated metal diborides; and
extracting at least a portion of the dispersion from the supernatant;
wherein the at least one solvent is selected from N-methyl-2-pyrrolidone, dimethylformamide, cyclopentanone, cyclohexanone, N-formyl piperidine, vinyl pyrrolidone, 1,3-dimethyl-2-imidazolidinone, bromobenzene, benzonitrile, benzyl benzoate, N,N′-dimethylpropylene urea, y-butrylactone, N-ethylpyrrolidone, dimethylacetamide, cyclohexylpyrrolidone, dimethyl sulfoxide, dibenzyl ether, chloroform, isopropylalcohol, cholobenzene, 1-octyl-2-pyrrolidone, 1-3 dioxolane, ethyl acetate, quinoline, benzaldehyde, ethanolamine, diethyl phthalate, NDodecyl-2-pyrrolidone, pyridine, dimethyl phthalate, formamide, ethanol, vinyl acetate, acetone, ethylene glycol, toluene, heptane, hexane, and pentane.

2. The method of claim 1 , wherein the dispersion of exfoliated metal diborides includes at least one of MgB 2 , AlB 2 , TiB 2 , CrB 2 , ZrB 2 , NbB 2 , HfB 2 , TaB 2 , ScB 2 , VB 2 , MnB 2 , FeB 2 , YB 2 , MoB 2 , ReB 2 , UB 2 , WB 2 , and BeB 2 .

3. The method of claim 1 , wherein the at least one solvent is water and the suspending solution is an aqueous surfactant solution including at least one of sodium cholate, sodium dodecyl sulfate, dodecylbenzene sulfonic acid sodium salt, cationic cetrimonium bromide, myristyltrimethylammonium bromide surfactant, sodium octyl sulfate, sodium tetradecyl sulfate, sodium deoxycholate, sodium taurodeoxycholate, polyoxyethylene-polyoxypropylene block copolymer, poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol), ethylenediamine tetrakis(ethoxylate-block-propoxylate) tetrol and ethylenediamine tetrakis(propoxylate-block-ethoxylate) tetrol.

4. The method of claim 1 , wherein the suspending solution includes riboflavin, ssDNA, dsDNA, BSA, and a peptide or polypeptide.

Assignees

• Univ Arizona State

Inventors

• Green Alexander
• Yousaf Ahmed
• Debnath Abhishek

Classifications

• C08L29/04

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• Y02E50/30

  Fuel from waste, e.g. synthetic alcohol or diesel · CPC title

• Y02C20/40

  of CO2 · CPC title

• C01B35/04 Primary

  Metal borides · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title