Gasification co-generation process of coal powder in a Y-type entrained flow bed

Patent metadata

Field	Value
Publication number	US-10711209-B2
Application number	US-201916671461-A
Country	US
Kind code	B2
Filing date	Nov 1, 2019
Priority date	Nov 2, 2018
Publication date	Jul 14, 2020
Grant date	Jul 14, 2020

Abstract

A gasification co-generation process of coal powder in a Y-type entrained flow bed, comprising: spraying coal water slurry or coal powder, gasification agent and water vapor into a gasification furnace through a top nozzle and a plurality of side nozzles for performing combustion and gasification with a residence time of 10 s or more; chilling the resulting slag with water, and subjecting the chilled slag to a dry method slagging to obtain gasification slag used as cement clinker; discharging the produced crude syngas carrying fine ash from the Y-type entrained flow bed to perform ash-slag separation.

First claim

What is claimed is:

1. A gasification co-generation process of coal powder in a Y-type entrained flow bed, comprising the following steps:
(1) mixing coal with lime powder to obtain coal powder, or mixing the coal, lime powder and water to obtain coal water slurry; in the coal water slurry or coal powder, the weight ratio of calcium to aluminum is 2-4:1, the weight ratio of calcium to silicon is 1-4:1, and the weight ratio of calcium to iron is 1-3:1;
(2) introducing the coal water slurry or coal powder, gasification agent and water vapor into a gasification furnace of a Y-type entrained flow bed, and performing combustion and gasification at a temperature range of 1,300-2,000° C., so as to produce a crude syngas and slag at a temperature range of 1300-2000° C., the gasification furnace comprising a furnace wall;
wherein the coal water slurry or coal powder, gasification agent and water vapor are sprayed into the gasification furnace through a top nozzle and a plurality of side nozzles of the gasification furnace, and collide, ignite and turbulently mix with each other at a combustion chamber center of the gasification furnace, to form a rotational strike and high temperature reaction zone; the residence time of a residual ash generated by the combustion and gasification in the rotational strike and high temperature reaction zone is 10 s or more;
the residual ash is thrown toward the furnace wall of the gasification furnace and swirled downward, and solidified on the furnace wall of the gasification furnace to form a slag layer;
(3) introducing the crude syngas and slag into a chilling chamber to carry out chilling with water, wherein the slag is cooled and solidified into a solid slag with a temperature of 500-950° C.; the solid slag passes through a solid discharge pipe with a perforated segmented conical head and flows into a fluidized bed heat extractor, and then its temperature is reduced to 120-500° C. under the action of a fluidized vapor and an atomized water mist or a heat extraction sleeve to obtain gasification slag, in the meanwhile, the fluidized vapor carries a fine ash having a high content of residual carbon and flows upward to pass through a perforated conical head, so as to further fluidize and sort the fine ash in the solid slag, then obtained fluidized vapor containing fine ash mixes with the crude syngas; the gasification slag is discharged from the fluid bed heat extractor, and is further cooled to a temperature less than 80° C. and subjects to a dry method slagging to produce a cement clinker;
the crude syngas is cooled by the chilling with water to a temperature range of 500-950° C., and carries the fine ash and is discharged from the chilling chamber to separate the fine ash from the gasification slag;
(4) discharging the crude syngas carrying fine ash from the chilling chamber, and further performing a gas-solid separation by means of a gas-ash separator to obtain a separated and purified syngas, the separated and purified syngas enter into a convective waste pot for heat recovery and is then ready for use; a separated fine ash passes through an ash exhaust port and is discharged into a moving bed heat exchanger, and is cooled to a temperature less than 500° C. and discharged and then returned to step (1) and mixed into the coal.

2. The process according to claim 1 , wherein the weight ratio of raw materials ejected from the top nozzle and raw materials ejected from the side nozzles is 1-4:1.

3. The process according to claim 1 , wherein the weight ratio of the coal powder, the gasification agent and the water vapor is 1,000:(120-360):(100-200), or the weight ratio of the coal water slurry and the gasification agent is 1,000:(120-360).

4. The process according to claim 1 , wherein the gasification furnace and the chilling chamber are separated by the perforated segmented conical head, and the fluidized bed heat extractor is underneath the chilling chamber; wherein
the gasification furnace comprises a top center provided with a top nozzle, and the upper portion of the gasification furnace is provided with three or more side nozzles which are disposed radially inclined along the circumferential direction;
the segmented conical head is disposed at the bottom of the gasification furnace, the segmented conical head has a central opening and a gasification product exhaust port underneath the opening, wherein the gasification product exhaust port is communicated with the chilling chamber;
the upper portion of the chilling chamber is provided with a crude syngas outlet connected to the gas-ash separator;
a plurality of independent cooled water atomization heat extraction nozzles and a heat extraction sleeve are disposed on an upper portion of the fluidized bed heat extractor, and a slag exhaust port is disposed at a bottom of the fluidized bed heat extractor.

5. The process according to claim 4 , wherein the radially inclined side nozzle has an arrangement condition comprising: an included angle between an axial direction of the side nozzles and an axial direction of the gasification furnace is within a range of 75°-90°; the side nozzles having a central axis that is not coplanar with the central axis of the gasification furnace; the central axis of the side nozzles is offset from a cross section passing through an intersection point between the central axis of the side nozzles and the circumference of said gasification furnace by an angle ranging from 5°-75°.

6. The process according to claim 4 , wherein the gasification furnace has a height/diameter ratio of 2-5:1; the distance between the spout of the side nozzle and the top of said gasification furnace is within a range of 500-2,500 mm.

7. The process according to claim 4 , wherein gasification furnace comprises a housing and the housing is provided with an insulation material layer, a cooling sleeve and a refractory layer sequentially from the outside to the inside;
a coolant inlet communicating with the cooling sleeve is disposed at the bottom of the gasification furnace, and a coolant outlet communicating with the cooling sleeve is disposed at the top of the gasification furnace;
the refractory layer of the gasification furnace is formed by casting a silicon carbide or magnesium aluminum spinel material.

8. The process according to claim 4 , wherein the chilling chamber has a height/diameter ratio of 2-8:1;
the chilling chamber is formed by casting a heat-insulating and wear-resistant material;
the distance between the crude syngas outlet in the chilling chamber and the top of the chilling chamber is within a range of 100-1,000 mm;
the perforated conical head has an opening ratio of 3%-25%.

9. The process according to claim 4 , wherein the lower portion of the fluidized bed heat extractor is provided with a distributor for water vapor or an inert gas; the distance between the solid discharge pipe and the distributor is within a range of 100-500 mm;
in the heat extraction sleeve, an inlet pipe is connected to an inlet pipe of the heat extraction sleeve through an inlet valve, and the outlet pipe is communicated with a steam pocket through an outlet valve.

10. The process according to claim 4 , wherein a moving bed heat exchanger and a two-level lock bucket material discharger are sequentially provided at an outlet of the fluidized bed heat extractor and an outlet of the gas-ash separator, respectively.

Assignees

• Univ China Petroleum East China

Inventors

• Tian Yuanyu
• Qiao Yingyun
• Xie Kechang
• Zhang Jinhong
• Zong Peijie
• Jiang Yuan

Classifications

• C10J2300/0996

  Calcium-containing inorganic materials, e.g. lime · CPC title

• C10J2300/1807

  Recycle loops, e.g. gas, solids, heating medium, water · CPC title

• C10J2300/1631

  Ash recycling · CPC title

• C10J3/80

  with arrangements for preheating the blast or the water vapour · CPC title

• C10J3/76

  Water jackets; Steam boiler-jackets · CPC title