Gas diffusion layer for metal-air battery, metal-air battery including the gas diffusion layer, and method of manufacturing the metal-air battery

Patent metadata

Field	Value
Publication number	US-10707495-B2
Application number	US-201815947997-A
Country	US
Kind code	B2
Filing date	Apr 9, 2018
Priority date	Jul 26, 2017
Publication date	Jul 7, 2020
Grant date	Jul 7, 2020

Abstract

A metal-air battery includes: at least one positive electrode layer, which is configured for using oxygen as an active material and includes a first surface and a second surface opposite the first surface; a gas diffusion layer on the first surface of the positive electrode layer and including a plurality of carbon fibers; an electrolyte layer on the second surface of the positive electrode layer; and a negative electrode metal layer on the electrolyte layer, wherein the positive electrode layer includes a plurality of grooves, and wherein portions of the plurality of carbon fibers are in the grooves.

First claim

What is claimed is:

1. A metal-air battery comprising:
at least one positive electrode layer, which is configured for using oxygen as an active material and comprises a first surface and a second surface opposite the first surface;
a gas diffusion layer on the first surface of the positive electrode layer and comprising a plurality of carbon fibers;
an electrolyte layer on the second surface of the positive electrode layer; and
a negative electrode metal layer on the electrolyte layer,
wherein the positive electrode layer comprises a plurality of grooves formed in the first surface,
wherein portions of the plurality of carbon fibers are in the grooves, and
wherein the portions of the plurality of carbon fibers extends in a substantially same direction in which the grooves extend.

2. The metal-air battery of claim 1 , wherein an average depth of the plurality of grooves is about 20% to about 60% of a diameter of a carbon fiber of the plurality of carbon fibers.

3. The metal-air battery of claim 1 , wherein an average width of the plurality of grooves is about 80% to about 100% of a diameter of a carbon fiber of the plurality of carbon fibers.

4. The metal-air battery of claim 1 , wherein an average length of each of the plurality of grooves is greater than or equal to about 3 millimeters.

5. The metal-air battery of claim 1 , wherein an average distance between adjacent grooves of the plurality of grooves is about 30 micrometers to about 1,000 micrometers.

6. The metal-air battery of claim 1 , wherein a diameter of each of the plurality of carbon fibers is about 5 micrometers to about 10 micrometers.

7. The metal-air battery of claim 1 , wherein a weight per unit area of the gas diffusion layer is less than or equal to about 0.5 milligrams per square centimeter.

8. The metal-air battery of claim 7 , wherein the weight per unit area of the gas diffusion layer is greater than or equal to about 0.007 milligrams per square centimeter.

9. A metal-air battery comprising:
at least one positive electrode layer, which is configured for using oxygen as an active material and comprises a first surface and a second surface opposite the first surface;
a gas diffusion layer on the first surface of the positive electrode layer and comprising a plurality of carbon fibers;
an electrolyte layer on the second surface of the positive electrode layer; and
a negative electrode metal layer on the electrolyte layer,
wherein the positive electrode layer comprises a plurality of grooves formed in the first surface,
wherein portions of the plurality of carbon fibers are in the grooves, and
wherein the gas diffusion layer comprises:
a first carbon fiber layer comprising a plurality of carbon fibers arranged on the positive electrode layer, and
a second carbon fiber layer on the first carbon fiber layer and comprising a plurality of carbon fibers extending in a direction intersecting a direction in which each of the plurality of carbon fibers of the first carbon fiber layer extends.

10. A metal-air battery comprising:
at least one positive electrode layer, which is configured for using oxygen as an active material and comprises a first surface and a second surface opposite the first surface;
a gas diffusion layer on the first surface of the positive electrode layer and comprising a plurality of carbon fibers;
an electrolyte layer on the second surface of the positive electrode layer; and
a negative electrode metal layer on the electrolyte layer,
wherein the positive electrode layer comprises a plurality of grooves formed in the first surface,
wherein portions of the plurality of carbon fibers are in the grooves, and
wherein the gas diffusion layer is a single layer and comprises a fold.

11. The metal-air battery of claim 10 , wherein the gas diffusion layer comprises a plurality of carbon fiber layers comprising a plurality of carbon fibers, and the plurality of carbon fiber layers comprises less than or equal to four layers.

12. A metal-air battery comprising:
at least one positive electrode layer, which is configured for using oxygen as an active material and comprises a first surface and a second surface opposite the first surface;
a gas diffusion layer on the first surface of the positive electrode layer and comprising a plurality of carbon fibers;
an electrolyte layer on the second surface of the positive electrode layer; and
a negative electrode metal layer on the electrolyte layer,
wherein the positive electrode layer comprises a plurality of grooves formed in the first surface,
wherein portions of the plurality of carbon fibers are in the grooves,
wherein the gas diffusion layer is partially on the positive electrode layer, and
wherein the negative electrode metal layer, the electrolyte layer, and the positive electrode layer are bent over the gas diffusion layer such that the positive electrode layer contacts at least three surfaces of the gas diffusion layer, and a first surface of the gas diffusion layer is exposed.

13. A method of manufacturing a metal-air battery, the method comprising:
arranging a plurality of carbon fibers on a first surface of a positive electrode layer, which is configured for using oxygen as an active material;
pressing the plurality of carbon fibers toward the positive electrode layer such that portions of the plurality of carbon fibers are inserted into the first surface of the positive electrode layer to form grooves, to thereby form a gas diffusion layer; and
providing an electrolyte layer on a second surface of the positive electrode layer and a negative electrode metal layer on the electrolyte layer to form the metal-air battery of claim 1 ,
wherein the grooves extend in a substantially same direction in which the portions of the plurality of carbon fibers extends.

14. The method of claim 13 , wherein the pressing of the plurality of carbon fibers comprises pressing the plurality of carbon fibers such that an average depth of the grooves is about 20% to about 60% of a diameter of a carbon fiber of the plurality of carbon fibers.

15. The method of claim 13 , wherein the pressing of the plurality of carbon fibers comprises pressing the plurality of carbon fibers such that an average width of the grooves is about 80% to about 100% of a diameter of a carbon fiber of the plurality of carbon fibers.

16. The method of claim 13 , wherein the arranging of the plurality of carbon fibers comprises arranging the plurality of carbon fibers such that an average distance between adjacent carbon fibers of the plurality of carbon fibers is about 30 micrometers to about 1,000 micrometers.

17. The method of claim 13 , wherein a weight per unit area of the gas diffusion layer is less than or equal to about 0.5 milligrams per square centimeter.

18. The method of claim 17 , wherein the weight per unit area of the gas diffusion layer is greater than or equal to about 0.007 milligrams per square centimeter.

19. A gas diffusion layer comprising:
a plurality of carbon fibers arranged on a first surface of a positive electrode layer which is configured for using oxygen as an active material,
wherein portions of the plurality of carbon fibers are in grooves formed in the first surface of the positive electrode layer,
wherein the portions of the plurality of carbon fibers extends in a substantially same direction in which the grooves extend.

20. The gas diffusion layer of claim 19 , wherein the gas diffusion layer does not comprise a binder.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Park Jungock
• Kim Mokwon
• Kim Joonhee
• Im Dongmin

Classifications

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M12/06

  with one metallic and one gaseous electrode · CPC title

• H01M8/0234

  Carbonaceous material · CPC title

• H01M4/96

  Carbon-based electrodes · CPC title

• H01M4/8657 Primary

  layered · CPC title