Forward osmosis process

Patent metadata

Field	Value
Publication number	US-10703652-B2
Application number	US-201815963753-A
Country	US
Kind code	B2
Filing date	Apr 26, 2018
Priority date	Sep 29, 2010
Publication date	Jul 7, 2020
Grant date	Jul 7, 2020

Abstract

A forward osmosis apparatus includes a diluting component for bringing a feed solution and a draw solution containing a cation source and an anion source in an ionized state into contact through a semi-permeable membrane and diluting the draw solution with water separated from the feed solution by means of the semi-permeable membrane; a separator for separating the draw solution that has been diluted by the diluting component into the cation source and anion source and into water; and a dissolving apparatus, returning the cation source and the anion source that have been separated by the separator to, and dissolving the cation source and anion source in, the draw solution that has been diluted, wherein the molecular weight of the cation source in an uncharged state is 31 or greater and the Henry's law constant of each of the anion source and cation source is 1.0×104 (Pa/mol·fraction) or greater in a standard state.

First claim

What is claimed is:

1. A forward osmosis process, comprising:
bringing a feed solution and a draw solution comprising a dissolved cation source and an anion source into contact through a semi-permeable membrane and diluting the draw solution with a water separated from the feed solution by the semi-permeable membrane;
separating the diluted draw solution into the cation source and anion source and into water; and
returning the separated cation source and anion source to, and dissolving the separated cation source and anion source in, the diluted draw solution;
wherein the cation source has a molecular weight of 31 or greater in an uncharged state, and each of the anion source and the cation source has a Henry's law constant of 1.0×10 4 (Pa/mol·fraction) or greater in water in a standard state.

2. The forward osmosis process according to claim 1 , wherein the anion source has an acid dissociation constant (pKa) of 6.0 to 7.0 as an uncharged material in a standard state.

3. The forward osmosis process according to claim 1 , wherein the cation source has a base dissociation constant (pKb) of 2.0 to 4.5 as an uncharged material in a standard state.

4. The forward osmosis process according to claim 1 , wherein the cation source, and/or anion source, has a boiling point of less than 100° C. at 1 atm as an uncharged material.

5. The forward osmosis process according to claim 1 , wherein the cation source has a base dissociation constant (pKb) of 4.0 to 4.5 as an uncharged material in a standard state.

6. The forward osmosis process according to claim 1 , wherein the cation source has a Henry's law constant of 1.0×10 5 (Pa/mol·raction) or greater in water in a standard state.

7. The forward osmosis process according to claim 1 , wherein the cation source has a Henry's law constant of 3.0×10 5 (Pa/mol·raction) or greater in water in a standard state.

8. The forward osmosis process according to claim 1 , wherein each of the anion source and cation source in the draw solution has a concentration immediately prior to being contacted with the semi-permeable membrane of 2.4 mol or more per kilogram of water.

9. The forward osmosis process according to claim 1 , wherein the anion source comprises anions selected from the group consisting of carbonate ions, hydrogen carbonate ions or a combination thereof.

10. The forward osmosis process according to claim 1 , wherein the molar ratio of the anion source to cation source is from 1:1 to 1:2.

11. The forward osmosis process according to claim 1 , wherein the cation source and anion source each have a Henry's law constant of 1.00×10 5 (Pa/mol·fraction) or greater in water in a standard state, and the cation source has a molecular weight within a range of from 45 to 74.

12. The forward osmosis process according to claim 1 , wherein the diluted draw solution is separated into the cation source and anion source and into water by heating diluted draw solution to a temperature not exceeding 90° C.

13. The forward osmosis process according to claim 1 , wherein in the step of bringing a feed solution and a draw solution into contact, the draw solution has a temperature of ±5° C. of the feed solution.

14. The forward osmosis process according to claim 1 , wherein another part of diluted draw solution which is not introduced to the separating step is warmed in a heat exchanger which uses, as a heat source, at least one among the water, cation source, and anion source obtained in the separating step.

15. The forward osmosis process according to claim 1 , wherein the difference between a maximum temperature of water obtained in the separating step and a minimum temperature of draw solution in the dissolving step is less than 35° C.

16. The forward osmosis process according to claim 1 , wherein the forward osmosis process is a water purification process that separates the diluted draw solution into a cation source and anion source and into water, and recovers the water component as a target product.

17. The forward osmosis process according to claim 1 , wherein the feed solution is seawater.

18. The forward osmosis process according to claim 1 , wherein the forward osmosis process further comprises collecting a concentrated target product that is left over from the feed solution after bringing the feed solution and draw solution into contact through the semi-permeable membrane.

Assignees

• Fujifilm Corp

Inventors

• Ikeda Morihito
• Miyamoto Kimiaki

Classifications

• B01D61/0022

  Apparatus therefor · CPC title

• B01D2311/2626

  Absorption or adsorption · CPC title

• C02F1/445 Primary

  by forward osmosis · CPC title

• C02F2209/02

  Temperature · CPC title

• C07C211/00

  Compounds containing amino groups bound to a carbon skeleton · CPC title