Forward osmosis apparatus and forward osmosis process

Patent metadata

Field	Value
Publication number	US-9630861-B2
Application number	US-201313827047-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Sep 29, 2010
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

A forward osmosis apparatus includes a diluting means for bringing a feed solution and a draw solution containing a cation source and an anion source in an ionized state into contact through a semi-permeable membrane and diluting the draw solution with water separated from the feed solution by means of the semi-permeable membrane; a separating means for separating the diluted draw solution into the cation source and anion source and into water; and a dissolving means, returning the separated cation source and the separated anion source to, and dissolving the cation source and anion source in, the draw solution that has been diluted. The molecular weight of the cation source in an uncharged state is 31 or greater and the Henry's law constant of each of the anion source and cation source is 1.0×10 4 (Pa/mol·fraction) or greater in a standard state.

First claim

The invention claimed is:

1. A forward osmosis apparatus, comprising
a feed solution;
a draw solution comprising a cation source in an ionized state and an anion source in an ionized state;
a diluting means for bringing the feed solution and the draw solution into contact through a semi-permeable membrane and diluting the draw solution with water separated from the feed solution by means of the semi-permeable membrane;
a separating means for separating the draw solution that has been diluted by the diluting means into the cation source and anion source and into water; and
a dissolving means, for returning the cation source and the anion source that have been separated by the separating means to, and for dissolving the separated cation source and the separated anion source in, the draw solution that has been diluted;
wherein the molecular weight of the cation source in an uncharged state is 31 or greater and the Henry's law constant of each of the anion source and cation source is 1.0×10 4 (Pa/mol·fraction) or greater at 25° C. and 10 5 Pa and wherein the cation source is an amine compound.

2. The forward osmosis apparatus according to claim 1 , wherein the anion source has an acid dissociation constant (pKa) of 6.0 to 7.0 as an uncharged material at 25° C. and 10 5 P.

3. The forward osmosis apparatus according to claim 1 , wherein the cation source has a base dissolution constant (pKb) of 2.0 to 4.5 as an uncharged material at 25° C. and 10 5 P.

4. The forward osmosis apparatus according to claim 1 , wherein at least one selected from the cation source and anion source has a boiling point of less than 100° C. at 1 atm as an uncharged material.

5. The forward osmosis apparatus according to claim 1 , wherein the cation source has a base dissolution constant (pKb) of 4.0 to 4.5 as an uncharged material at 25° C. and 10 5 P.

6. The forward osmosis apparatus according to claim 1 , wherein the cation source has a Henry's law constant of 1.0×10 5 (Pa/mol·raction) or greater at 25° C. and 10 5 P.

7. The forward osmosis apparatus according to claim 1 , wherein the cation source has a Henry's law constant of 3.0×10 5 (Pa/mol·raction) or greater at 25° C. and 10 5 P.

8. The forward osmosis apparatus according to claim 1 , wherein each of the anion source and cation source in the draw solution has a concentration immediately prior to being contacted with the semi-permeable membrane of 2.4 mol or more per kilogram of water.

9. The forward osmosis apparatus according to claim 1 , wherein the anions are at least one selected from carbonic acid anions and hydrogen carbonate ions.

10. The forward osmosis apparatus according to claim 1 , wherein the molar ratio of the anion source and cation source which is anion source:cation source is from 1:1 to 1:2.

11. The forward osmosis apparatus according to claim 1 , wherein the cation source is one or more members selected from the group consisting of trimethyl amine, dimethyl ethyl amine, isopropyl amine, dimethyl amine, and diethyl amine.

12. The forward osmosis apparatus according to claim 1 , wherein the cation source and anion source have a Henry's law constant of each of 1.00×10 5 (Pa/mol·raction) or greater, and the cation source has a molecular weight of a range of from 45 to 74.

13. The forward osmosis apparatus according to claim 1 , wherein the cation source is trimethyl amine or dimethyl ethyl amine, and the anion source is carbon dioxide.

14. The forward osmosis apparatus according to claim 1 , wherein the diluted draw solution is separated into the cation source and anion source and into water by heating to a temperature not exceeding 90° C.

15. The forward osmosis apparatus according to claim 1 , wherein the draw solution fed to the diluting means has a temperature within ±5° C. of the temperature of the feed solution fed to the diluting means.

16. The forward osmosis apparatus according to claim 1 , which comprises a heat exchanger configured to warm the diluted draw solution using, as a heat source, at least one among the water, cation source, and anion source obtained by the separating means.

17. The forward osmosis apparatus according to claim 1 , which comprises a heat exchanger that cools at least one among the cation source and anion source obtained by the apparatus of the dissolving means or the separating means using the feed solution prior to dilution as a cooling source.

18. The forward osmosis apparatus according to claim 1 , wherein the difference between a maximum temperature of the separating means and a minimum temperature of the dissolving means is less than 35° C.

19. The forward osmosis apparatus according to claim 1 , wherein the forward osmosis apparatus is a water purification apparatus that separates the draw solution diluted by the diluting means into a cation source and anion source and into water, and recovers the water component as a target product.

20. The forward osmosis apparatus according to claim 19 , wherein the feed solution is seawater.

21. The forward osmosis apparatus according to claim 1 , wherein the forward osmosis apparatus is a concentrating device that recovers the feed solution that has been concentrated after bringing the feed solution and draw solution into contact through the semi-permeable membrane as a target product.

Assignees

• Fujifilm Corp

Inventors

• Ikeda Morihito
• Miyamoto Kimiaki

Classifications

• C02F1/445 Primary

  by forward osmosis · CPC title

• C02F2209/02

  Temperature · CPC title

• C02F1/20

  by degassing, i.e. liberation of dissolved gases (degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D) · CPC title

• C02F1/447

  by membrane distillation (distillation and evaporation without the use of membranes C02F1/04) · CPC title

• C02F2209/005

  Processes using a programmable logic controller [PLC] · CPC title