Light emitting shell in multi-compartment microcapsules

Patent metadata

Field	Value
Publication number	US-10696899-B2
Application number	US-201715590676-A
Country	US
Kind code	B2
Filing date	May 9, 2017
Priority date	May 9, 2017
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A multi-compartment microcapsule emits photons when subjected to a stimulus. In some embodiments, the multi-compartment microcapsules have first and second compartments separated by an isolating structure adapted to rupture in response to the stimulus, wherein the first and second compartments contain reactants that come in contact and react to produce photons when the isolating structure ruptures.

First claim

What is claimed is:

1. A multi-compartment microcapsule comprising:
a first compartment;
a second compartment; and
an isolating structure separating first and second compartments from each other and adapted to rupture in response to a stimulus, and
wherein:
the first and second compartments contain reactants that come in contact and react to produce photons when the isolating structure ruptures, and
the multi-compartment microcapsule is a shell-in-shell microcapsule comprising an inner shell contained within an outer shell, wherein the inner shell encapsulates the first compartment, wherein the outer shell encapsulates the second compartment, wherein the inner shell defines the isolating structure, and wherein the inner shell and the outer shell are configured so that a stimulus ruptures the inner shell while the outer shell remains intact.

2. The multi-compartment microcapsule of claim 1 , wherein the first compartment contains chemiluminescent reactants and the second compartment contains an oxidant.

3. The multi-compartment microcapsule of claim 2 , wherein the oxidant is hydrogen peroxide.

4. The multi-compartment microcapsule of claim 1 , wherein a given level of compressive force ruptures the inner shell while the outer shell remains intact.

5. The multi-compartment microcapsule of claim 1 , wherein a given level of heat ruptures the inner shell while the outer shell remains intact.

6. The multi-compartment microcapsule of claim 1 , further comprising magnetic nanoparticles in the inner shell.

7. The multi-compartment microcapsule of claim 1 , wherein the outer shell comprises a polymer, and the outer shell has a transmittance of at least 90%.

8. The multi-compartment microcapsule of claim 7 , wherein the polymer comprises gelatin, arabic gum, shellac, lac, starch, dextrin, wax, rosin, sodium alginate, zein, methyl cellulose, ethyl cellulose, carboxymethyl cellulose, hydroxyethyl ethyl cellulose, polyolefins, polystyrenes, polyethers, polyesters, polyureas, polyethylene glycol, polyamides, polyimides, urea-formaldehydes, polyurethane, polyacrylate, epoxy resins, or combinations thereof.

9. A multi-compartment microcapsule comprising:
a first compartment;
a second compartment; and
an isolating structure separating first and second compartments from each other and adapted to rupture in response to a stimulus, and
wherein:
the first and second compartments contain reactants that come in contact and react to produce photons when the isolating structure ruptures, and
the multi-compartment microcapsule is a shell-in-shell microcapsule comprising an inner shell contained within an outer shell, wherein the inner shell encapsulates the first compartment, wherein the outer shell encapsulates the second compartment, wherein the inner shell defines the isolating structure, and wherein the inner shell and the outer shell are configured so that a stimulus ruptures the inner shell while the outer shell remains intact, and
the inner shell encapsulates magnetic nanoparticles.

10. The multi-compartment microcapsule of claim 9 , wherein the first compartment contains chemiluminescent reactants and the second compartment contains an oxidant.

11. The multi-compartment microcapsule of claim 10 , wherein the oxidant is hydrogen peroxide.

12. The multi-compartment microcapsule of claim 10 , wherein a given level of compressive force ruptures the inner shell while the outer shell remains intact.

13. A multi-compartment microcapsule comprising:
a first compartment;
a second compartment; and
an isolating structure separating first and second compartments from each other and adapted to rupture in response to a stimulus, and
wherein:
the first and second compartments contain reactants that come in contact and react to produce photons when the isolating structure ruptures,
the multi-compartment microcapsule is a shell-in-shell microcapsule comprising an inner shell contained within an outer shell, wherein the inner shell encapsulates the first compartment, wherein the outer shell encapsulates the second compartment, wherein the inner shell defines the isolating structure, and wherein the inner shell and the outer shell are configured so that a stimulus ruptures the inner shell while the outer shell remains intact, and
the outer shell comprises a polymer, and the outer shell has a transmittance of at least 90%.

14. The multi-compartment microcapsule of claim 13 , wherein the first compartment contains chemiluminescent reactants and the second compartment contains an oxidant.

15. The multi-compartment microcapsule of claim 14 , wherein the oxidant is hydrogen peroxide.

16. The multi-compartment microcapsule of claim 13 , wherein the polymer comprises gelatin, arabic gum, shellac, lac, starch, dextrin, wax, rosin, sodium alginate, zein, methyl cellulose, ethyl cellulose, carboxymethyl cellulose, hydroxyethyl ethyl cellulose, polyolefins, polystyrenes, polyethers, polyesters, polyureas, polyethylene glycol, polyamides, polyimides, urea-formaldehydes, polyurethane, polyacrylate, epoxy resins, or combinations thereof.

17. The multi-compartment microcapsule of claim 13 , wherein a given level of heat ruptures the inner shell while the outer shell remains intact.

18. The multi-compartment microcapsule of claim 13 , wherein a given level of compressive force ruptures the inner shell while the outer shell remains intact.

Assignees

• IBM

Inventors

• Campbell Eric J
• Czaplewski Sarah K
• Kuczynski Joseph
• Tofil Timothy J

Classifications

• B65D2401/00

  Tamper-indicating means · CPC title

• C09K11/00 Primary

  Luminescent materials, e.g. electroluminescent or chemiluminescent · CPC title

• C01G49/00

  Compounds of iron · CPC title

• C01F11/18

  Carbonates · CPC title

• C01G49/08

  Ferroso-ferric oxide [Fe3O4] · CPC title