Light generating microcapsules for self-healing polymer applications

Patent metadata

Field	Value
Publication number	US-10696761-B2
Application number	US-201916441948-A
Country	US
Kind code	B2
Filing date	Jun 14, 2019
Priority date	Jun 23, 2017
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

A self-healing polymeric material includes a polymeric matrix material, wherein dispersed within the polymeric matrix material is a mixture of materials that includes monomers and a photoinitiator, and a plurality of light generating microcapsules dispersed in the polymeric matrix material. Each light generating microcapsule encapsulates multiple reactants that undergo a chemiluminescent reaction. The chemiluminescent reaction generates a photon having a wavelength within a particular emission range that is consistent with an absorption range of the photoinitiator.

First claim

What is claimed is:

1. A self-healing polymeric material comprising:
a polymeric matrix material;
wherein dispersed within the polymeric matrix material is a mixture of materials that includes monomers and a photoinitiator; and
a plurality of light generating microcapsules dispersed in the polymeric matrix material, each light generating microcapsule of the plurality of light generating microcapsules encapsulating multiple reactants that undergo a chemiluminescent reaction, wherein each light generating microcapsule comprises an outer shell and an inner shell,
wherein the chemiluminescent reaction generates a photon having a wavelength within a particular emission range that is consistent with an absorption range of the photoinitiator and wherein the chemiluminescent reaction occurs without rupture of the outer shell of the light generating microcapsules.

2. The self-healing polymeric material of claim 1 , wherein a crack in the polymeric matrix material causes migration of the monomers and photoinitiator into the crack.

3. The self-healing polymeric material of claim 2 , wherein further propagation of the crack in the polymeric matrix material results in application of a compressive force to a light generating microcapsule of the plurality of light generating microcapsules, the compressive force triggering the chemiluminescent reaction within the light generating microcapsule.

4. The self-healing polymeric material of claim 3 , wherein the photon generated within the light generating microcapsule exits the light generating microcapsule into the crack to trigger the photoinitiator to initiate a polymerization reaction of the monomers within the crack, the polymerization reaction resulting in formation of a polymeric material that seals the crack.

5. The self-healing polymeric material of claim 4 , wherein the photoinitiator includes a free radical initiator, and wherein the polymerization reaction includes a free radical polymerization reaction.

6. The self-healing polymeric material of claim 1 , wherein the monomers include acrylate monomers.

7. The self-healing polymeric material of claim 1 , wherein the chemiluminescent reaction includes excitation of a dye from a ground state to an excited state and subsequent release of the photon upon relaxation from the excited state to the ground state.

8. The self-healing polymeric material of claim 7 , wherein excitation of the dye is caused by energy released during decomposition of a 1,2-dioxetanedione molecule.

9. The self-healing polymeric material of claim 8 , wherein a chemical reaction of a diphenyl oxalate molecule with a hydrogen peroxide molecule results in formation of the 1,2-dioxetanedione molecule.

10. The self-healing polymeric material of claim 7 , wherein the dye includes 9,10-diphenylanthracene.

11. The self-healing polymeric material of claim 1 , wherein each light generating microcapsule includes a multiple-compartment microcapsule that comprises:
a first compartment that contains a first reactant of the multiple reactants;
a second compartment that contains a second reactant of the multiple reactants; and
wherein the inner shell is an isolating structure separating the first compartment from the second compartment, the isolating structure adapted to rupture in response to application of a compressive force to cause the first reactant and the second reactant to undergo the chemiluminescent reaction.

12. The self-healing polymeric material of claim 11 , wherein the multiple-compartment microcapsule includes a shell-in-shell microcapsule and the inner shell is contained within the outer shell, wherein the inner shell encapsulates the first compartment, wherein the outer shell encapsulates the second compartment.

13. The self-healing polymeric material of claim 12 , wherein the outer shell comprises a polymer, and wherein the outer shell has a transmittance value of at least 90% for the wavelength within the particular emission range.

14. The self-healing polymeric material of claim 13 , wherein the polymer comprises gelatin, arabic gum, shellac, lac, starch, dextrin, wax, rosin, sodium alginate, zein, methyl cellulose, ethyl cellulose, carboxymethyl cellulose, hydroxyethyl ethyl cellulose, polyolefins, polystyrenes, polyethers, polyesters, polyureas, polyethylene glycol, polyamides, polyimides, urea-formaldehydes, polyurethane, polyacrylate, epoxy resins, and combinations thereof.

15. The self-healing polymeric material of claim 1 , wherein the outer shell remains intact during the chemiluminescent reaction, thereby preventing a reaction product of the chemiluminescent reaction from contacting the polymeric matrix material.

16. The self-healing polymeric material of claim 1 , wherein the plurality of light generating microcapsules are adapted such that a compressive force caused by a crack in the polymeric matrix material ruptures the inner shell without rupturing the outer shell, thereby causing the multiple reactants to mix and initiate the chemiluminescent reaction within the plurality of light generating microcapsules.

17. A self-healing polymeric material comprising:
a polymeric matrix material;
a mixture of monomers and a photoinitiator dispersed within the polymeric matrix material; and
a plurality of light generating microcapsules dispersed in the polymeric matrix material, each light generating microcapsule comprising an outer shell and an inner shell, wherein the inner shell is adapted to rupture in response to a compressive force that does not rupture the outer shell,
wherein each light generating microcapsule encapsulates multiple reactants that undergo a chemiluminescent reaction within the respective light generating microcapsule in response to the inner shell rupturing,
wherein the chemiluminescent reaction generates a photon having a wavelength within a particular emission range that is consistent with an absorption range of the photoinitiator, and
wherein the chemiluminescent reaction occurs without rupture of the outer shell of the light generating microcapsules.

18. The self-healing polymeric material of claim 17 , wherein the outer shell comprises a polymer, and wherein the outer shell has a transmittance value of at least 90% for the wavelength within the particular emission range.

19. The self-healing polymeric material of claim 17 , wherein the outer shell comprises a plastic that is adapted to filter the light generated by the chemiluminescent reaction such that greater than 90% of photons having a wavelength within the particular emission range pass through the outer shell, while fewer photons having a wavelength outside the particular emission range are able to pass through the outer shell.

20. The self-healing polymeric material of claim 17 , wherein the mixture of monomers and the photoinitiator are not encapsulated.

Assignees

• IBM

Inventors

• Campbell Eric J
• Czaplewski-Campbell Sarah K
• Kuczynski Joseph
• Tofil Timothy J

Classifications

• C08F2/48 Primary

  by ultraviolet or visible light · CPC title

• C08F20/18

  with acrylic or methacrylic acids · CPC title

• C08F20/06 Primary

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C07D321/00

  Heterocyclic compounds containing rings having two oxygen atoms as the only ring hetero atoms, not provided for by groups C07D317/00 - C07D319/00 · CPC title

• B01J13/04

  by physical processes, e.g. drying, spraying · CPC title