Method of ore processing using mixture including acidic leach solution and oxidizing agent

Patent metadata

Field	Value
Publication number	US-10662503-B2
Application number	US-201615241200-A
Country	US
Kind code	B2
Filing date	Aug 19, 2016
Priority date	Jan 25, 2011
Publication date	May 26, 2020
Grant date	May 26, 2020

Abstract

A method of selectively leaching a metal such as nickel from an ore or ore processing intermediate comprising the metal and cobalt. The ore or ore processing intermediate is contacted with an acidic leach solution comprising an amount of an oxidising agent sufficient to oxidise a major portion of the cobalt to thereby cause it to be stabilised in the solid phase while a major portion of the metal is dissolved for subsequent recovery.

First claim

The invention claimed is:

1. A method of selectively leaching a metal selected from the group consisting of nickel, copper and zinc from a solid ore or solid ore processing intermediate comprising the metal, cobalt and manganese, the method comprising:
a) providing a mixture comprising an acidic leach solution and an oxidizing agent; and
b) mixing the mixture with the solid ore or solid ore processing intermediate,
wherein there is sufficient oxidizing agent to stabilize greater than 95% by mass of the cobalt to cause it to be stabilized in a solid phase while greater than 50% by mass of the metal is selectively dissolved, and
wherein the oxidizing agent is present in the acidic leach solution in 70% to 500% stoichiometric equivalents to cobalt and manganese in the solid ore or solid ore processing intermediate.

2. The method of claim 1 , wherein greater than 70% by mass of the metal is selectively dissolved.

3. The method of claim 1 , wherein greater than 90% by mass of the metal is selectively dissolved.

4. The method of claim 1 , wherein the metal is nickel.

5. The method of claim 1 , wherein the solid ore or solid ore processing intermediate is a mixed nickel-cobalt hydroxide precipitate.

6. The method of claim 1 , wherein the oxidizing agent has sufficient oxidizing potential to oxidize cobalt(II) to cobalt(III).

7. The method of claim 6 , wherein the oxidizing agent has an oxidative potential of greater than 0.5 V (SHE).

8. The method of claim 6 , wherein the oxidizing agent has an oxidative potential between 0.5 V and 3.0 V (SHE).

9. The method of claim 1 , wherein the acidic leach solution has a pH from 1 to 6.

10. The method of claim 9 , wherein the acidic leach solution has a pH from 2 to 5.

11. The method of claim 8 , wherein the oxidizing agent has an oxidative potential of 0.5 V to 3.0 V (SHE) at a pH from 0 to 6.

12. The method of claim 11 , wherein the oxidizing agent has an oxidative potential of 0.5 V to 1.0 V (SHE) at a pH from 4 to 6.

13. The method of claim 11 , wherein the oxidizing agent has an oxidative potential of 1.0 V to 2.0 V (SHE) at a pH from 1 to 4.

14. The method of claim 1 , wherein the oxidizing agent is selected from the group consisting of persulphates, peroxides, permanganates, perchlorates, ozone, oxides and chlorine.

15. The method of claim 1 , further comprising controlling addition of the oxidizing agent.

16. The method of claim 1 , further comprising heating the acidic leach solution to greater than 50° C.

17. The method of claim 1 , wherein greater than 50% by mass of the metal has been leached into the acidic leach solution from the solid ore or solid ore processing intermediate after 1 to 5 hours.

18. The method of claim 1 , wherein the oxidizing agent is present in the acidic leach solution in 80% to 200% stoichiometric equivalents to combined cobalt and manganese in the solid ore or solid ore processing intermediate.

19. The method of claim 1 , wherein treatment with the amount of oxidizing agent causes a major portion of the manganese to be stabilized in a solid phase while a major portion of the metal is dissolved.

20. The method of claim 1 wherein, after leaching is complete, extracted metal is recoverable directly from the acidic leach solution by electrowinning or hydrogen reduction.

21. A method of recovering nickel and cobalt from a mixed nickel-cobalt hydroxide precipitate, wherein the mixed nickel-cobalt hydroxide precipitate comprises manganese, the method comprising:
(a) providing a mixture comprising an acidic leach solution and an oxidizing agent, wherein there is sufficient oxidizing agent to stabilize greater than 95% by mass of the cobalt to cause it to be stabilized in the solid phase while greater than 50% by mass of the nickel is selectively dissolved;
(b) mixing the mixture with the mixed nickel-cobalt hydroxide precipitate,
(c) separating the cobalt in the solid phase from the acidic leach solution containing dissolved nickel to recover the cobalt in the solid phase; and
(d) recovering the nickel from the acidic leach solution,
wherein the oxidizing agent is present in the acidic leach solution in 70% to 500% stoichiometric equivalents to cobalt and manganese in the mixed nickel-cobalt hydroxide precipitate.

22. The method of claim 21 , wherein addition of an amount of oxidizing agent also causes a major portion of the manganese to be stabilized in a solid phase.

23. The method of claim 21 , wherein there is sufficient oxidizing agent to stabilize greater than 99% by mass of the cobalt to cause it to be stabilized in a solid phase.

24. A method of selectively leaching a metal selected from the group consisting of nickel, copper, and zinc from a solid ore or solid ore processing intermediate comprising the metal, cobalt and manganese, the method comprising:
a) providing a mixture comprising an acidic leach solution and an oxidizing agent; and
b) mixing the mixture with the solid ore or solid ore processing intermediate,
wherein there is sufficient oxidizing agent to stabilize greater than 99% by mass of the cobalt to cause it to be stabilized in a solid phase while greater than 50% by mass of the metal is selectively dissolved, and
wherein the oxidizing agent is present in the acidic leach solution in 70% to 500% stoichiometric equivalents to cobalt and manganese in the solid ore or solid ore processing intermediate.

Assignees

• Univ Queensland

Inventors

• Vaughan James
• Hawker William

Classifications

• C22B23/0461

  by chemical methods · CPC title

• C22B23/043

  Sulfurated acids or salts thereof · CPC title

• C22B23/0476 Primary

  Separation of nickel from cobalt · CPC title

• C22B15/0067

  with acids or salts thereof · CPC title

• C22B23/0415

  with acids or salt solutions except ammonium salts solutions · CPC title