Alloy powder and method for producing same

Patent metadata

Field	Value
Publication number	US-11859264-B2
Application number	US-201917258763-A
Country	US
Kind code	B2
Filing date	Jul 11, 2019
Priority date	Jul 12, 2018
Publication date	Jan 2, 2024
Grant date	Jan 2, 2024

Abstract

Provided are: an alloy powder that can be obtained from a waste lithium ion battery, wherein the alloy powder can be dissolved in an acid solution and enables recovery of metals contained in the alloy powder; and a method for producing the alloy powder. This alloy powder contains Cu and at least one of Ni and Co as constituent components, wherein a portion having a higher concentration of the at least one of Ni and Co than the average concentration in the entire alloy powder is distributed on at least the surface, and the phosphorus grade is less than 0.1% by mass. The method for producing the alloy powder includes a powdering step for powdering a molten alloy using a gas atomization method, the molten alloy containing Cu and at least one of Ni and Co as constituent components and having a phosphorus grade of less than 0.1% by mass.

First claim

The invention claimed is:

1. A method for producing an alloy powder, the method comprising:
a melting step of melting a waste lithium ion battery so as to obtain a molten material;
a slag separation step of separating slag including phosphorus from the molten material so as to recover an alloy material which contains Cu and at least one of Ni and Co; and
a powdering step of powdering, with a gas atomization method, a molten alloy which is formed of the alloy material and in which a phosphorus grade is less than 0.1% by mass, to obtain the alloy powder having, on its surface, a concentrated portion in which at least one of Ni and Co is increased,
wherein in the powdering step, the molten alloy is powdered with the gas atomization method to obtain the alloy powder which has an average particle size of 20 μm or more and 300 μm or less and which includes, on its surface, a concentrated portion in which the concentrations of nickel and cobalt are increased, and
wherein the molten alloy is formed of the alloy material, the molten alloy has a phosphorus grade of less than 0.1% by mass, and the molten alloy is a copper-nickel-cobalt alloy at a temperature of 1320° C. or more and 1600° C. or less having a Cu content of 50% by mass or more and 97% by mass or less, a Ni content of 3% by mass or more and 30% by mass or less, a Co content of 3% by mass or more and 30% by mass or less, and a total content of Ni and Co of 3% by mass or more and 50% by mass or less.

2. The method for producing an alloy powder according to claim 1 , further comprising: a pre-heating step of roasting, before the melting step, the waste lithium ion battery at such a temperature that the waste lithium ion battery is not melted.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Togashi Ryo
• Yamashita Yu

Classifications

• B09B3/70

  Chemical treatment, e.g. pH adjustment or oxidation (involving an extraction step B09B3/80) · CPC title

• B09B3/35

  Shredding, crushing or cutting · CPC title

• B09B3/40

  involving thermal treatment, e.g. evaporation (processes using mineral binders involving a melting or softening step B09B3/29; involving radiation B09B3/50) · CPC title

• B22F9/08 Primary

  by casting, e.g. through sieves or in water, by atomising or spraying (using electric discharge B22F9/14) · CPC title

• C22B7/001 Primary

  Dry processes · CPC title