Pneumatic tire

Patent metadata

Field	Value
Publication number	US-10654995-B2
Application number	US-201816113249-A
Country	US
Kind code	B2
Filing date	Aug 27, 2018
Priority date	Aug 30, 2017
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

The present invention is directed to a pneumatic tire comprising a tread, the tread comprising a rubber composition comprising from 30 to 80 phr of a styrene-butadiene rubber having a Tg ranging from −70 C to −40 C, from 10 to 50 phr of a high vinyl polybutadiene having a Tg ranging from −40 C to −5 C and has an isomeric vinyl 1,2 content in a range of from 50 to 90 percent by weight, and from 10 to 30 phr of a natural rubber or synthetic polyisoprene, silica, a blocked mercaptosilane, a traction resin, and liquid plasticizer selected from the group consisting of a low molecular weight polybutadiene functionalized with a hydroxyl functional group and sunflower oil.

First claim

The invention claimed is:

1. A pneumatic tire comprising a tread, the tread comprising a rubber composition comprising from 30 to 80 phr of a styrene-butadiene rubber having a Tg ranging from −70° C. to −40° C., from 10 to 50 phr of a high vinyl polybutadiene having a Tg ranging from −40° C. to −5° C. and has an isomeric vinyl 1,2 content in a range of from 50 to 90 percent by weight, and from 10 to 30 phr of a natural rubber or synthetic polyisoprene, silica, a blocked mercaptosilane, a traction resin, and from 3 to 30 phr of a low molecular weight polybutadiene functionalized with a hydroxyl functional group and having a molecular weight Mw ranging from 1,000 to 25,000 g/mol and a Tg ranging from −50° C. to −20° C.

2. The pneumatic tire of claim 1 , wherein the styrene-butadiene rubber is functionalized with at least one functional group selected from the group consisting of alkoxysilane groups, sulfur containing functional groups, and primary amino functional groups.

3. The pneumatic tire of claim 1 , wherein the rubber composition comprises as the blocked mercaptosilane from 3 to 20 phr of S-octanoylmercaptopropyltriethoxysilane.

4. The pneumatic tire of claim 1 , further comprising a sunflower oil present in an amount ranging from 2 to 30 phr.

5. The pneumatic tire of claim 1 , wherein the rubber composition comprises from 50 to 150 phr of silica.

6. The pneumatic tire of claim 1 , wherein the first rubber composition comprises from 1 to 10 phr of carbon black.

7. The pneumatic tire of claim 1 , wherein the rubber composition includes as the traction resin from 10 to 45 phr of a resin selected from the group consisting of hydrocarbon resins, phenol/acetylene resins, rosin derived resins and mixtures thereof.

8. The pneumatic tire of claim 1 , wherein the rubber composition includes as the traction resin from 10 to 45 phr of a terpene resin.

9. The pneumatic tire of claim 1 , wherein the traction resin is a terpene resin comprising a polymer of α-pinene.

10. A pneumatic tire comprising a tread, the tread comprising a rubber composition comprising
100 phr of elastomers consisting of the following A, B, and C:
A) from 30 to 80 phr of a one styrene-butadiene rubber having a Tg ranging from −70° C. to 40° C.,
B) from 10 to 50 phr of a high vinyl polybutadiene having a Tg ranging from −40° C. to −5° C. and has an isomeric vinyl 1,2 content in a range of from 50 to 90 percent by weight, and
C) from 10 to 30 phr of a natural rubber or synthetic polyisoprene;

10 to 45 phr of a terpene resin;
3 to 30 phr of a low molecular weight polybutadiene functionalized with a hydroxyl functional group and having a molecular weight Mw ranging from 1,500 to 2,500 g/mol and a Tg ranging from
−50° C. to −20° C.;
up to 25 phr of a processing oil;
50 to 150 phr of silica;
from 3 to 20 phr of a S-octanoylmercaptopropyltriethoxysilane; and
1 to 10 phr of carbon black.

11. The pneumatic tire of claim 10 , wherein the silica comprises a blend of two silicas having a surface area between 125 and 250 m 2 /g.

12. The pneumatic tire of claim 10 , wherein terpene resin comprises a polymer of α-pinene.

Assignees

• Goodyear Tire & Rubber

Inventors

• Mejia Luisa Fernanda Munoz
• Kaes Christian Jean-Marie
• Ahrens Bodo
• Talbot William Alain
• Engeldinger Eric
• Pompei Manuela
• Schmit Philippe
• Delville Jérôme Joel Daniel

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08F212/08

  Styrene · CPC title

• C08F2500/02

  Low molecular weight, e.g. <100,000 Da. · CPC title

• C08K3/36

  Silica · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title