Method of making a polymer composite

Patent metadata

Field	Value
Publication number	US-10649355-B2
Application number	US-201615215226-A
Country	US
Kind code	B2
Filing date	Jul 20, 2016
Priority date	Jul 20, 2016
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

A method of making a composite feed material for fused deposition modeling (FDM) is disclosed. The method comprises providing composite particles made by a process of emulsion aggregation, the composite particles comprising at least one thermoplastic polymer and at least one carbon particle material. A composite feed material is formed for fused deposition modeling from the composite particles. The composite feed material is in a form selected from a filament and a paste.

First claim

What is claimed is:

1. A method of making a composite feed material for fused deposition modeling (FDM), the method comprising:
providing composite particles made by a process of emulsion aggregation, the composite particles comprising at least one thermoplastic polymer and at least one carbon particle material; and
forming a composite feed material for fused deposition modeling from the composite particles, the composite feed material being in a form selected from a filament and a paste,
wherein the emulsion aggregation process comprises:
providing the at least one thermoplastic polymer in the form of a stable emulsion of latex polymer particles;
destabilizing the emulsion and aggregating the latex polymer particles in the presence of the at least one carbon particle materials and an aggregant to form a dispersion of aggregate particles, the aggregate particles comprising both the latex polymer particles and the carbon particle material;
stabilizing the dispersion to form an emulsion of the aggregate particles, thereby freezing growth of the aggregate particles at a particle size ranging from about 500 nm to about 100 microns; and
heating the aggregate particles to coalesce the latex polymer particles and form the composite particles.

2. The method of claim 1 , wherein the at least one thermoplastic polymer has a Tg of less than 100° C.

3. The method of claim 1 , wherein the at least one thermoplastic polymer has a viscosity of less than 50,000 cP, where viscosity is determined at shear of 6.28 rad/sec using a TA instruments model DHR2 rheometer with 2 parallel (25 mm) plates at a temperature of 100° C.

4. The method of claim 1 , wherein the at least one thermoplastic polymer is a latex.

5. The method of claim 1 , wherein the at least one thermoplastic polymer is selected from the group consisting of polyacrylates, polybenzimidazoles, polycarbonates, polyether sulfones, polyaryl ether ketones, polyetherimide, polyethylenes, polyphenylene oxides, polypropylenes, polystyrenes, styrene-butyl acrylate, polyesters, polyurethanes, polyamides, Poly(vinylidene fluoride) (PVDF), polyvinyl chlorides and combinations thereof.

6. The method of claim 1 , wherein the at least one thermoplastic polymer is selected from the group consisting of polyether ether ketone, polyethylene, poly(ethylene-co-vinylacetate), polypropylene, Poly(vinylidene fluoride-co-hexafluoropropylene), polystyrene, poly(styrene isoprene styrene), acrylonitrile butadiene styrene (ABS), poly(Styrene Ethylene Butylene Styrene) (SEBS), styrene n-butyl acrylate, polyethylene terephthalate, polylactic acid (PLA), polycaprolactone, poly (propoxylated bisphenol A co-fumarate), nylon and combinations thereof.

7. The method of claim 1 , wherein the at least one carbon particle material is selected from the group consisting of carbon nanotubes, graphite, graphene and combinations thereof.

8. The method of claim 1 , wherein providing the stable emulsion of latex polymer particles comprises: providing at least one monomer material;
and preparing the stable emulsion of latex polymer particles from the monomer material.

9. The method of claim 1 , wherein making the composite feed material comprises extruding the composite to form the filament.

10. The method of claim 1 , wherein making the composite feed material comprises adding a diluent to the composite particles to form the paste.

11. The method of claim 1 , wherein the carbon particle materials are in an amount of at least 5% by weight, based on the total weight of the composite particles.

12. The method of claim 1 , wherein the composite feed material has a conductivity that is greater than 0.01 S/cm.

13. A method of making composite particles, the method comprising:
providing a stable emulsion of latex thermoplastic polymer particles;
destabilizing the emulsion and aggregating the latex thermoplastic polymer particles in the presence of at least one carbon particle material and an aggregant to form a dispersion of the aggregate particles, the aggregate particles comprising both the latex thermoplastic polymer particles and the carbon particle material;
stabilizing the dispersion to form an emulsion of the aggregate particles, thereby freezing growth of the aggregate particles at a particle size ranging from about 500 nm to about 100 microns; and
heating the aggregate particles to coalesce the latex polymer particles and form composite particles comprising the coalesced latex polymer and the carbon particle material, the carbon particle material being in an amount of at least 5% by weight, based on the total weight of the composite particles.

14. The method of claim 13 , wherein the latex thermoplastic polymer particles comprise a thermoplastic material.

15. The method of claim 13 , wherein the at least one thermoplastic polymer is selected from the group consisting of polyacrylates, polybenzimidazoles, polycarbonates, polyether sulfones, polyaryl ether ketones, polyetherimide, polyethylenes, polyphenylene oxides, polypropylenes, polystyrenes, styrene-butyl acrylate, polyesters, polyurethanes, polyamides, Poly(vinylidene fluoride) (PVDF), polyvinyl chlorides and combinations thereof.

16. The method of claim 13 , wherein the at least one thermoplastic polymer is selected from the group consisting of polyether ether ketone, polyethylene, poly(ethylene-co-vinylacetate), polypropylene, Poly(vinylidene fluoride-co-hexafluoropropylene), polystyrene, poly(styrene isoprene styrene), acrylonitrile butadiene styrene (ABS), poly(Styrene Ethylene Butylene Styrene) (SEBS), styrene n-butyl acrylate, polyethylene terephthalate, polylactic acid (PLA), polycaprolactone, poly (propoxylated bisphenol A co-fumarate), nylon and combinations thereof.

17. The method of claim 13 , wherein the at least one carbon particle material is selected from the group consisting of carbon nanotubes, graphite, graphene and combinations thereof.

18. The method of claim 13 , wherein providing the stable emulsion of latex polymer particles comprises:
providing at least one monomer material; and
preparing the stable emulsion of latex polymer particles from the monomer material.

Assignees

• Xerox Corp

Inventors

• Keoshkerian Barkev
• Prestayko Rachel
• Nosella Kimberly D
• Farrugia Valerie M

Classifications

• B29C70/882

  partly or totally electrically conductive, e.g. for EMI shielding (conductive floors or floor coverings H05F3/025; EMI shielding in general H05K9/00) · CPC title

• B29K2507/04

  Carbon · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• D01F1/09

  for making electroconductive or anti-static filaments · CPC title

• B29K2007/00

  Use of natural rubber as moulding material · CPC title