N—H free and SI-rich per-hydridopolysilzane compositions, their synthesis, and applications

US10647578B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-10647578-B2
Application numberUS-201715661412-A
CountryUS
Kind codeB2
Filing dateJul 27, 2017
Priority dateDec 11, 2016
Publication dateMay 12, 2020
Grant dateMay 12, 2020

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Abstract

Official abstract text for this publication.

Solid or liquid N—H free, C-free, and Si-rich perhydropolysilazane compositions comprising units having the following formula [—N(SiH3)x(SiH2—)y], wherein x=0, 1, or 2 and y=0, 1, or 2 when x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 when x+y=3 are disclosed. Also disclosed are synthesis methods and applications for the same.

First claim

Opening claim text (preview).

We claim: 1. A method of synthesizing a N—H free, C-free, and Si-rich perhydropolysilazane composition, the method comprising mixing trisilylamine and a catalyst to produce the N—H free, C-free, and Si-rich perhydropolysilazane composition having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton, wherein the catalyst is selected from the group consisting of B(C 6 F 5 ) 3 , BPh 3 , PdCl 2 , Co 2 (CO) 8 , Ru 3 (CO) 12 , and Zeolite Y (H) Si:Al. 2. A method of synthesizing a N—H free, C-free, and Si-rich perhydropolysilazane composition, the method comprising mixing trisilylamine and a catalyst to produce the N—H free, C-free, and Si-rich perhydropolysilazane composition having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton, further comprising mixing trisilylamine and the catalyst at room temperature and atmospheric pressure. 3. A method of synthesizing a N—H free, C-free, and Si-rich perhydropolysilazane composition, the method comprising mixing trisilylamine and a catalyst to produce the N—H free, C-free, and Si-rich perhydropolysilazane composition having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton, wherein the catalyst is B(C 6 F 5 ) 3 , further comprising adding a quenching agent when a N—H free, C-free, and Si-rich perhydropolysilazane composition obtains the desired molecular weight.

Assignees

Inventors

Classifications

  • the material being a silicon oxynitride, e.g. SiON or SiON:H · CPC title

  • the compound being a silazane · CPC title

  • Nitrogen atoms · CPC title

  • Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes · CPC title

  • with a well-defined oxygen content, e.g. oxycarbides · CPC title

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What does patent US10647578B2 cover?
Solid or liquid N—H free, C-free, and Si-rich perhydropolysilazane compositions comprising units having the following formula [—N(SiH3)x(SiH2—)y], wherein x=0, 1, or 2 and y=0, 1, or 2 when x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 when x+y=3 are disclosed. Also disclosed are synthesis methods and applications for the same.
Who is the assignee on this patent?
Air Liquide, Air Liquide American
What technology area does this patent fall under?
Primary CPC classification C23C18/122. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue May 12 2020 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 5 related publications on this page (citations in our corpus or others sharing the same primary CPC).