Composition for forming a silica based layer, silica based layer, and electronic device
US-2016176718-A1 · Jun 23, 2016 · US
US10647578B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10647578-B2 |
| Application number | US-201715661412-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 27, 2017 |
| Priority date | Dec 11, 2016 |
| Publication date | May 12, 2020 |
| Grant date | May 12, 2020 |
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Solid or liquid N—H free, C-free, and Si-rich perhydropolysilazane compositions comprising units having the following formula [—N(SiH3)x(SiH2—)y], wherein x=0, 1, or 2 and y=0, 1, or 2 when x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 when x+y=3 are disclosed. Also disclosed are synthesis methods and applications for the same.
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We claim: 1. A method of synthesizing a N—H free, C-free, and Si-rich perhydropolysilazane composition, the method comprising mixing trisilylamine and a catalyst to produce the N—H free, C-free, and Si-rich perhydropolysilazane composition having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton, wherein the catalyst is selected from the group consisting of B(C 6 F 5 ) 3 , BPh 3 , PdCl 2 , Co 2 (CO) 8 , Ru 3 (CO) 12 , and Zeolite Y (H) Si:Al. 2. A method of synthesizing a N—H free, C-free, and Si-rich perhydropolysilazane composition, the method comprising mixing trisilylamine and a catalyst to produce the N—H free, C-free, and Si-rich perhydropolysilazane composition having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton, further comprising mixing trisilylamine and the catalyst at room temperature and atmospheric pressure. 3. A method of synthesizing a N—H free, C-free, and Si-rich perhydropolysilazane composition, the method comprising mixing trisilylamine and a catalyst to produce the N—H free, C-free, and Si-rich perhydropolysilazane composition having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton, wherein the catalyst is B(C 6 F 5 ) 3 , further comprising adding a quenching agent when a N—H free, C-free, and Si-rich perhydropolysilazane composition obtains the desired molecular weight.
the material being a silicon oxynitride, e.g. SiON or SiON:H · CPC title
the compound being a silazane · CPC title
Nitrogen atoms · CPC title
Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes · CPC title
with a well-defined oxygen content, e.g. oxycarbides · CPC title
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