Method for producing transparent ceramic, transparent ceramic, magneto-optical device and rare earth oxide powder for sintering

Patent metadata

Field	Value
Publication number	US-10642073-B2
Application number	US-201515313885-A
Country	US
Kind code	B2
Filing date	Jun 1, 2015
Priority date	Jun 4, 2014
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

A starting material powder, which contains a rare earth oxide that is composed of terbium oxide and at least one other rare earth oxide selected from among yttrium oxide, scandium oxide and oxides of lanthanide rare earth elements (excluding terbium) and a sintering assistant that is formed of an oxide of at least one element selected from among group 2 elements and group 4 elements, is produced by having (a) terbium ions, (b) ions of at least one other rare earth element selected from among yttrium ions, scandium ions and lanthanide rare earth ions (excluding terbium ions) and (c) ions of at least one element selected from among group 2 elements and group 4 elements coprecipitate in an aqueous solution containing the components (a)-(c), then filtering and separating the coprecipitate, and subjecting the separated coprecipitate to thermal dehydration.

First claim

The invention claimed is:

1. A method for producing a transparent ceramic containing terbium oxide of the chemical formula: Tb 2 O 3 and at least one other rare earth oxide selected from among yttrium oxide, scandium oxide and oxides of lanthanide rare earth elements, excluding terbium, as main components, the method comprising:
providing an aqueous solution containing (a) terbium ions, (b) ions of at least one other rare earth element selected from among yttrium ions, scandium ions and lanthanide rare earth ions, excluding terbium ions, and (c) ions of at least one element selected from among Group 2 elements and Group 4 elements;
co-precipitating the components (a), (b) and (c), thereby obtaining a co-precipitate;
filtrating and separating the co-precipitate;
thermally dehydrating the co-precipitate to form a raw material powder containing a rare earth oxide including terbium oxide and at least one other rare earth oxide selected from among yttrium oxide, scandium oxide and oxides of lanthanide rare earth elements, excluding terbium, the molar ratio of terbium oxide being at least 40 mol % and the balance being the other rare earth oxide, and a sintering aid including an oxide of at least one element selected from among Group 2 elements and Group 4 elements;
forming a molded body using the raw material powder;
then firing the molded body; and
subjecting the fired molded body to pressure firing.

2. The method for producing a transparent ceramic of claim 1 , wherein the raw material powder contains more than 0.5 parts by weight and up to 5 parts by weight of the sintering aid per 100 parts by weight of the rare earth oxide.

3. The method for producing a transparent ceramic of claim 1 , wherein the component (c) is ions of at least one element selected from among titanium ions, zirconium ions, hafnium ions, calcium ions and magnesium ions.

4. The method for producing a transparent ceramic of claim 1 , further comprising subjecting the pressure-fired molded body to a heat treatment at 1,500 to 2,000° C. in a non-oxidizing atmosphere.

5. The method for producing a transparent ceramic of claim 1 , wherein the molded body is calcined before the firing.

6. The method for producing a transparent ceramic of claim 1 , wherein the co-precipitating step is a treatment of:
adding a basic aqueous solution dropwise to an acidic aqueous solution containing the ions of the components (a), (b) and (c) to produce a hydroxide; then adding a salt containing carbonic acid ions dropwise to the hydroxide-containing solution to replace the hydroxide by a carbonate; aging the carbonate-containing solution; and thereafter adding a basic aqueous solution dropwise to the aged carbonate-containing solution to re-replace the carbonate by the hydroxide.

7. The method for producing a transparent ceramic of claim 6 , wherein the acidic aqueous solution is aqueous nitric acid solution, aqueous sulfuric acid solution or aqueous hydrochloric acid solution.

8. The method for producing a transparent ceramic of claim 6 , wherein the basic aqueous solution is aqueous ammonia (NH 4 OH), oxalic acid ((COOH) 2 ), ammonium hydrogen carbonate (NH 4 HCO 3 ), or ammonium carbonate ((NH 4 ) 2 CO 3 ).

9. The method for producing a transparent ceramic of claim 1 , wherein in the transparent ceramic, an insertion loss at a wavelength of 1,064 nm inclusive of a reflection loss at an end face in a plane of at least 90% of a measurement surface in a thickness direction of a 10 mm-thick sample is up to 0.97 dB.

Assignees

• Shinetsu Chemical Co

Inventors

• Makikawa Shinji
• Aoki Shinji
• Nojima Yoshihiro

Classifications

• C04B2235/9653

  Translucent or transparent ceramics other than alumina · CPC title

• C04B35/645

  Pressure sintering · CPC title

• G02F1/09

  based on magneto-optical elements, e.g. exhibiting Faraday effect · CPC title

• C04B2235/60

  Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms · CPC title

• C04B35/50

  based on rare-earth compounds {(non-oxide rare earth compounds C04B35/5156)} · CPC title