Osmotic distillation process for concentrating a liquid containing sodium chloride

Patent metadata

Field	Value
Publication number	US-10640399-B2
Application number	US-201615740174-A
Country	US
Kind code	B2
Filing date	Jun 29, 2016
Priority date	Jul 1, 2015
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

Described is an osmotic distillation process for concentrating a liquid containing sodium chloride, and in particular a treatment process for used reaction water containing sodium chloride from the production of polymers.

First claim

The invention claimed is:

1. An osmotic distillation process for concentrating an aqueous liquid containing sodium chloride, where the liquid has a concentration of up to 20% by weight of sodium chloride, which comprises at least the following steps,
a) optionally prepurification of the liquid to remove organic secondary constituents, optionally down to a total content of the organic secondary constituents of 20 ppm,
b) introducing the optionally prepurified liquid into a first evaporation zone which is separated from a diffusion zone adjoining the first zone by a hydrophobic first membrane which is permeable to water vapor,
c) diffusion of water vapor from the liquid containing sodium chloride through the membrane into the diffusion zone,
d) further diffusion of water vapor from the diffusion zone through a second hydrophobic membrane which is permeable to water vapor into a stripping zone adjoining the diffusion zone and absorption of the water vapor in a draw solution which is continuously replaced in the stripping zone.

2. The process as claimed in claim 1 , wherein a concentrated alkaline metal hydroxide solution, having a concentration of alkaline metal hydroxide, of from 10% by weight to 50% by weight, is used as the draw solution.

3. The process as claimed in claim 1 , wherein the aqueous liquid containing sodium chloride is production wastewater from a process for preparing polymers.

4. The process as claimed in claim 1 , wherein the first membrane and the second membrane are, independently of one another, comprised of a hydrophobic polymer.

5. The process as claimed in claim 1 , wherein the evaporation zone, diffusion zone, and stripping zone are maintained independently of one another at atmospheric pressure or reduced pressure.

6. The process as claimed in claim 1 , wherein the evaporation zone, diffusion zone, and stripping zone are, independently of one another, maintained at a temperature of from 10 to 80° C.

7. The process as claimed in claim 6 , wherein the temperature in the evaporation zone is greater than in the diffusion zone and the stripping zone.

8. The process as claimed in claim 1 , wherein the liquid containing sodium chloride in the evaporation zone and the draw solution in the stripping zone are conveyed in countercurrent relative to one another past the respective membranes.

9. The process as claimed in claim 1 , wherein the aqueous liquid containing sodium chloride has turbulent flow in the evaporation zone.

10. The process as claimed in claim 1 , wherein the evaporation zone, diffusion zone, and stripping zone have been joined to one another by means of fusion bonding.

11. The process as claimed in claim 1 , wherein the process steps b), c) and d) are carried out in a plurality of stages, with at least one further evaporation zone, diffusion zone, and stripping zone being employed.

12. The process as claimed in claim 1 , wherein liquid exits from the first evaporation zone in a first arrangement made up of evaporation zone, diffusion zone, and stripping zone and is again subjected to process steps b) and c) in at least one downstream arrangement made up of evaporation zone, diffusion zone, and stripping zone and diluted draw solution exits from a second stripping zone in at least one downstream arrangement made up of evaporation zone, diffusion zone, and stripping zone is used for carrying out step d) in the first arrangement made up of evaporation zone, diffusion zone, and stripping zone.

13. The process as claimed in claim 12 , wherein a concentrated aqueous liquid containing sodium chloride exits from the evaporation zone of the first osmotic distillation arrangement and is subjected to heat exchange.

14. The process as claimed in claim 12 , wherein a draw solution exits from the stripping zone of the first arrangement and is subjected to heat exchange.

Assignees

• Covestro Deutschland Ag

Inventors

• Bulan Andreas
• Schiesser Yuliya
• Weber Rainer

Classifications

• C02F1/447 Primary

  by membrane distillation (distillation and evaporation without the use of membranes C02F1/04) · CPC title

• C02F2103/38

  Polymers · CPC title

• B01D2313/32

  Intermediate chambers · CPC title

• B01D71/36

  Polytetrafluoroethylene · CPC title

• B01D2311/04

  Specific process operations in the feed stream; Feed pretreatment · CPC title