Hydrophobic porous silica aerogel composite membrane and vacuum membrane distillation method

Patent metadata

Field	Value
Publication number	US-2016257581-A1
Application number	US-201514844879-A
Country	US
Kind code	A1
Filing date	Sep 3, 2015
Priority date	Mar 3, 2015
Publication date	Sep 8, 2016
Grant date	—

Abstract

A hydrophobic porous silica aerogel composite membrane for a vacuum membrane distillation device and a vacuum distillation method are disclosed. The vacuum membrane distillation device has a case and the hydrophobic porous silica aerogel composite membrane accommodated in the case to divide a chamber defined by the case into a feed part configured to feed a first fluid containing water molecules and a permeate part configured to collect a second fluid containing the water molecules. The hydrophobic porous silica aerogel composite membrane includes a porous aluminum oxide membrane that has a plurality of first pores with average pore diameter larger than 50 nm and a porous silica aerogel membrane that has a plurality of second pores of 2 to 50 nm and is formed on at least one side of the porous aluminum oxide membrane facing the feed part by methylmethoxysilane as a precursor and a sol-gel synthetic process.

First claim

What is claimed is:

1 . A hydrophobic porous silica aerogel composite membrane, adapted for a vacuum membrane distillation device having a case and the hydrophobic porous silica aerogel composite membrane accommodated in the case to divide a chamber defined by the case into a feed part and a permeate part, wherein the feed part is configured to feed a first fluid containing water molecules and the permeate part is configured to collect a second fluid containing the water molecules, comprising:
a porous aluminum oxide membrane, having a plurality of first pores, wherein the average pore diameter of the first pores is larger than 50 nm; and a porous silica aerogel membrane, formed on at least one side of the porous aluminum oxide membrane and having a plurality of second pores, wherein the average pore diameter of the second pores is 2 to 50 nm, and the porous silica aerogel membrane is formed by methylmethoxysilane as a precursor and a sol-gel synthetic process.

2 . The hydrophobic porous silica aerogel composite membrane of claim 1 , wherein the porous silica aerogel membrane is further formed in the first pores of the porous aluminum oxide membrane.

3 . The hydrophobic porous silica aerogel composite membrane of claim 1 , wherein the average pore diameter of the porous silica aerogel membrane is 6 to 10 nm.

4 . The hydrophobic porous silica aerogel composite membrane of claim 1 , wherein the water contact angle of the porous silica aerogel membrane is 137° to 147°.

5 . The hydrophobic porous silica aerogel composite membrane of claim 1 , wherein the thickness of the porous silica aerogel membrane is 40 to 50 μm.

6 . A vacuum membrane distillation method, comprising:
providing a vacuum membrane distillation device having a case and a hydrophobic porous silica aerogel composite membrane accommodated in the case to divide a chamber defined by the case into a feed part and a permeate part, wherein the hydrophobic porous silica aerogel composite membrane has a porous aluminum oxide membrane and a porous silica aerogel membrane, the porous aluminum oxide membrane has a plurality of first pores, the average pore diameter of the first pores is larger than 50 nm, the porous silica aerogel membrane is formed on one side of the porous aluminum oxide membrane facing the feed part, the porous silica aerogel membrane has a plurality of second pores, the average pore diameter of the second pores is 2 to 50 nm, and the porous silica aerogel membrane is formed by methylmethoxysilane as a precursor and a sol-gel synthetic process; feeding a first fluid containing water molecules in the feed part; and evacuating the permeate part to collect a second fluid containing the water molecules.

7 . The vacuum membrane distillation method of claim 6 , wherein the first fluid is in the liquid phase and the second fluid is in the gas phase, the temperature of the first fluid is higher than that of the second fluid, and thereby the water molecules are transferred and passed through the hydrophobic porous silica aerogel composite membrane from the first fluid in the feed part into the permeate part.

8 . The vacuum membrane distillation method of claim 7 , wherein the temperature of the first fluid is 70° C. to 300° C.

9 . The vacuum membrane distillation method of claim 7 , wherein the pressure of the permeate part is −98 to −70 kPa.

10 . The vacuum membrane distillation method of claim 7 , wherein the salt rejection rate of the second fluid is higher than 99%.

Assignees

• Univ Nat Taiwan

Inventors

• Tung Kuo-Lun
• Yang Chung-Chin
• Ko Chia-Chieh
• Chen Chien-Hua
• Lin Yi-Feng

Classifications

• B01D71/027

  Silicium oxide · CPC title

• B01D61/364

  Membrane distillation · CPC title

• B01D69/12

  Composite membranes; Ultra-thin membranes · CPC title

• C02F1/447 Primary

  by membrane distillation (distillation and evaporation without the use of membranes C02F1/04) · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title