Release film, laminate and method for manufacturing same, and method for manufacturing fuel cell

Patent metadata

Field	Value
Publication number	US-10622658-B2
Application number	US-201415033302-A
Country	US
Kind code	B2
Filing date	Nov 4, 2014
Priority date	Nov 14, 2013
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

A release layer of a release film for producing a membrane electrode assembly of a polymer electrolyte fuel cell comprises a cyclic olefin polymer comprising an olefin unit having a C3-10alkyl group as a side chain thereof. The release layer may have a glass transition temperature of about 210 to 350° C. The release layer may have a transition point of a dynamic storage modulus E′ in a range from −50 to 100° C. An ion exchange layer comprising an ion exchange polymer may be laminated on the release layer of the release film by a roll-to-roll processing to produce a laminate. The release film may be separated from the laminate to give the membrane electrode assembly. The release film achieves improved production of a membrane electrode assembly (an electrolyte membrane and/or an electrode membrane) of a polymer electrolyte fuel cell.

First claim

The invention claimed is:

1. A release film for producing a membrane electrode assembly of a polymer electrolyte fuel cell, wherein the release film comprises
a release layer, the release layer having a glass transition temperature of 210 to 350° C. and comprising a copolymer which comprises, as a repeating unit, (A) an olefin unit free from a C 3-10 alkyl group and (B) a chain or cyclic olefin unit having a C 4-8 alkyl group, wherein a molar ratio of the cyclic olefin unit (A) relative to the chain or cyclic olefin unit (B) is 50:50 to 99:1.

2. The release film according to claim 1 , wherein the release layer has a transition point of a dynamic storage modulus E′ in a range from −50 to 100° C.

3. The release film according to claim 1 , wherein the chain or cyclic olefin unit (B) comprises an ethylene or norbornene unit having a straight-chain C 4-8 alkyl group.

4. The release film according to claim 1 , wherein the molar ratio of the cyclic olefin unit (A) relative to the chain or cyclic olefin unit (B) is 70:25 to 90:10.

5. The release film according to claim 1 , wherein the release layer has an average thickness of 0.2 to 5 μm.

6. The release film according to claim 1 , which further comprises a substrate layer, wherein the release layer is laminated on at least one side of the substrate layer, and the substrate layer comprises at least one member selected from the group consisting of a polyolefin, a vinyl alcohol-series polymer, a polyester, a polyamide, and a cellulose derivative.

7. The release film according to claim 1 , wherein the release layer is formed by coating.

8. A laminate for producing a polymer electrolyte fuel cell, wherein the laminate comprises a release film recited in claim 1 and an ion exchange layer laminated on a release layer of the release film, and the ion exchange layer comprises an ion exchange polymer.

9. The laminate according to claim 8 , wherein the ion exchange polymer comprises a fluoropolymer comprising a side chain having a sulfonic acid group, and the ion exchange layer comprising the ion exchange polymer is an electrolyte membrane, an electrode membrane, or both.

10. The laminate according to claim 8 , which is produced by a roll-to-roll processing.

11. A process for producing a laminate recited in claim 8 , comprising: a step of laminating an ion exchange layer comprising an ion exchange polymer on a release layer of a release film.

12. The process according to claim 11 , wherein, in the laminating step, the lamination is carried out by a roll-to-roll processing.

13. A process for producing a membrane electrode assembly of a polymer electrolyte fuel cell, comprising: a step of separating a release film from a laminate recited in claim 8 .

Assignees

• Daicel Corp
• Daicel Value Coating Ltd

Inventors

• Onomichi Hiroshi
• Sumita Katsuhiko
• Okano Yoshimichi
• Nishimura Kanae
• Okada Kazuyuki
• Yaegashi Takayuki
• Suzuki Ken

Classifications

• C08J2427/18

  Homopolymers or copolymers of tetrafluoroethylene · CPC title

• C08J2300/12

  Polymers characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity · CPC title

• H01M4/881

  Electrolytic membranes · CPC title

• C08J2445/00

  Characterised by the use of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Derivatives of such polymers · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title