Fuel cell production method

Patent metadata

Field	Value
Publication number	US-9496560-B2
Application number	US-201113272704-A
Country	US
Kind code	B2
Filing date	Oct 13, 2011
Priority date	Oct 20, 2010
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

A method of producing a fuel cell includes: preparing a plurality of carbon nanotubes that are aligned substantially vertically to a plane of a substrate; supporting an electrode catalyst on the carbon nanotubes; forming an electrode layer by disposing an ionomer formed of a first solid polymer electrolyte on a surface of the carbon nanotubes on which the electrode catalyst is supported; and placing the electrode layer to face an electrolyte membrane formed of a second solid polymer electrolyte, which has a glass-transition temperature lower than that of the first solid polymer electrolyte, and bonding the electrolyte membrane to the electrode layer by applying a pressure higher than 5 MPa between the electrolyte membrane and electrode layer at a temperature that is higher than the glass-transition temperature of the second solid polymer electrolyte and that is lower than the glass-transition temperature of the first solid polymer electrolyte.

First claim

What is claimed is:

1. A method of producing a fuel cell, comprising:
preparing a plurality of carbon nanotubes that are aligned vertically to a plane of a substrate;
supporting an electrode catalyst on the carbon nanotubes;
forming an electrode layer by disposing an ionomer formed of a first solid polymer electrolyte having a glass-transition temperature of at least 150° C. on a surface of the carbon nanotubes on which the electrode catalyst is supported;
placing the electrode layer to face an electrolyte membrane formed of a second solid polymer electrolyte, which has a glass-transition temperature of 100° C. to 120° C., and bonding the electrolyte membrane to the electrode layer such that the ionomer on the surface of the carbon nanotubes is not softened and a portion of the carbon nanotubes is embedded in the semi-melted electrolyte membrane, by applying a pressure of 10 MPa to 15 MPa between the electrolyte membrane and electrode layer at a temperature that is higher than or equal to 120° C. and that is lower than 150° C.; and
stopping heating, performing cooling and removing a substrate layer after the electrolyte membrane and electrode layer have been bonded to each other,
wherein the first polymer electrolyte has a weight ratio, with regard to the carbon nanotube grown on the substrate layer, of 1.6 to 2.0.

2. The method of producing a fuel cell according to claim 1 , wherein a shape in a tube length direction of the carbon nanotubes grown on the substrate layer is not a straight shape.

3. The method of producing a fuel cell according to claim 1 , wherein a shape in a tube length direction of the carbon nanotubes grown on the substrate layer is a helical shape.

4. The method of producing a fuel cell according to claim 1 , wherein the glass-transition temperature of the first polymer electrolyte is 30° C. to 50° C. higher than the glass-transition temperature of the second polymer electrolyte.

Assignees

• Hasegawa Shigeki
• Toyota Motor Co Ltd

Inventors

• Hasegawa Shigeki

Classifications

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• H01M4/8892

  Impregnation or coating of the catalyst layer, e.g. by an ionomer · CPC title

• Y02P70/56

  Cross-Sectional Technologies · mapped topic

• H01M4/926

  on carbon or graphite · CPC title

• H01M4/8814

  Temporary supports, e.g. decal · CPC title