Organometallic compound in solid form, process for preparing the same and use thereof

Patent metadata

Field	Value
Publication number	US-10611865-B2
Application number	US-201816105580-A
Country	US
Kind code	B2
Filing date	Aug 20, 2018
Priority date	Sep 24, 2012
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

The present invention provides a solid organomagnesium precursor having formula {Mg(OR′)X}.a{MgX 2 }.b{Mg(OR′) 2 }.c{R′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.01-0.5:0.01-0.5:0.01-5 and process for preparing the same, said process comprising contacting a magnesium source with a solvating agent, an organohalide and an alcohol to obtain the solid organomagnesium precursor. The present invention also provides a process for preparing a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins.

First claim

We claim:

1. A catalyst composition comprising a combination of 2.0 wt % to 20 wt % of an internal electron donor, 0.5 wt % to 10.0 wt % of a titanium and 10 wt % to 20 wt % of a magnesium, wherein the magnesium is an organomagnesium precursor having the formula {Mg(OR′)X}.a{MgX2}.b{Mg(OR′)2}.c{R′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.01-0.5:0.01-0.5:0.01-5; the organomagnesium precursor has been formed in a process that includes contacting a magnesium source with a solvating agent, an organohalide and an alcohol to obtain the solid organomagnesium precursor, wherein the solvating agent is selected from the group consisting of dimethyl ether, diethyl ether, dipropyl ether, diisopropyl ether, ethylmethyl ether, n-butylmethyl ether, n-butylethyl ether, di-n-butyl ether, di-isobutyl ether, isobutylmethyl ether, and isobutylethyl ether, dioxane, tetrahydrofuran, 2-methyl tetrahydrofuran, tetrahydropyran and combination thereof.

2. A process for preparation of a catalyst system, said process comprising contacting the catalyst composition as claimed in claim 1 , with at least one cocatalyst, and at least one external electron donor to obtain the catalyst system.

3. A catalyst system comprising a combination of catalyst composition as claimed in claim 1 , organoaluminium compounds cocatalyst and external electron donors, wherein:
the cocatalyst is selected from the group consisting of hydrides, organoaluminum, lithium, zinc, tin, cadmium, beryllium, magnesium, and combinations thereof; and
the external electron donor is selected from the group consisting of organosilicon compounds, diethers, alkoxy benzoates, amine, esters, carboxylate, ketone, amide, phosphine, carbamate, phosphate, sulfonate, sulfone, sulphoxide and combinations thereof.

4. The catalyst system as claimed in claim 3 , wherein:
the cocatalyst is organoaluminium compound and is selected from the group consisting of alkylaluminums, trialkenylaluminums, dialkylaluminum halides, alkylaluminum sesquihalides, dialkylaluminum hydrides, partially hydrogenated alkylaluminum, aluminoxane, diethylaluminum ethoxide and combination thereof;
the alkylaluminums is selected from the group consisting of triethylaluminum, triisopropylaluminum, triisobutylaluminum, tri-n-butylaluminum, tri-n-hexylaluminum, tri-n-octylaluminum;
the trialkenylaluminums is selected from the group consisting of triisoprenyl aluminum;
the dialkylaluminum halides is selected from the group consisting of diethylaluminum chloride, dibutylaluminum chloride, diisobutylaluminum chloride, diethyl aluminum bromide;
the alkylaluminum sesquihalides is selected from the group consisting of ethylaluminum sesquichloride, butylaluminum sesquichloride, ethylaluminum sesquibromide;
the dialkylaluminum hydrides is selected from the group consisting of diethylaluminum hydride, dibutylaluminum hydride;
the partially hydrogenated alkylaluminum is selected from the group consisting of ethylaluminum dihydride, propylaluminum dihydride; and the aluminoxane is selected from the group consisting of methylaluminoxane, isobutylaluminoxane, tetraethylaluminoxane and tetraisobutylaluminoxane.

5. The catalyst system as claimed in claim 3 , wherein ratio of catalyst composition (titanium): organoaluminum compound: external donor is in range of 1:25-500:25-100.

6. The catalyst system as claimed in claim 3 , wherein mole ratio of aluminum to titanium is from about 5:1 to about 1000:1.

7. The catalyst system as claimed in claim 3 , wherein the external donor is organosilicon compounds and is selected from the group consisting of trimethylmethoxysilane, trimethylethoxysilane, dimethyldimethoxysilane dimethyldiethoxysilane, diisopropyldimethoxysilane, diisobutyldimethoxysilane, t-butylmethyldimethoxysilane, t-butylmethyldiethoxysilane, t-amylmethyldiethoxysilane, dicyclopentyldimethoxysilane, diphenyldimethoxysilane, phenylmethyldimethoxysilane, diphenyldiethoxysilane, bis-o-tolydimethoxysilane, bis-m-tolydimethoxysilane, bis-p-tolydimethoxysilane, bis-p-tolydiethoxysilane, bisethylphenyldimethoxysilane, dicyclohexyldimethoxysilane, cyclohexylmethyldimthoxysilane, cyclohexylmethyldiethoxysilane, ethyltrimethoxysilane, ethyl triethoxysilane, vinyltrimethoxysilane, methyltrimethoxysilane, n-propyltriethoxysilane, decyltrimethoxysilane, decyltriethoxysilane, phenyltrimethoxysilane, gamma-chloropropyltrimethoxysilane, methyltriethoxysilane, ethyltriethoxysilane, vinyltriethoxysilane, t-butyltriethoxysilane, n-butyltriethoxysilane, iso-butyltriethoxysilane, phenyltriethoxysilane, ethyltriisopropoxysilane, gamma-aminopropyltriethoxysilane, cholotriethoxysilane, vinyltirbutoxysilane, cyclohexyltrimethoxysilane, cyclohexyltriethoxysilane, 2-norbomanetrimethoxysilane, 2-norbomanetriethoxysilane, 2-norbomanemethyldimethoxysilane, ethyl silicate, butyl silicate, trimethylphenoxysilane, and methyltriallyloxysilane, cyclopropyltrimethoxysilane, cyclobutyltrimethoxysilane, cyclopentyltrimethoxysilane, 2-methylcyclopentyltrimethoxysilane, 2,3-dimethylcyclopentyltrimethoxysilane, 2,5-dimethylcyclopentyltrimethoxysilane, cyclopentyltriethoxysilane, cyclopentenyltrimethoxysilane, 3-cyclopentenyltrimethoxysilane, 2,4-cyclopentadienyltrimethoxysilane, indenyltrimethoxysilane and fluorenyltrimethoxysilane; dialkoxysilanes such as dicyclopentyldimethoxysilane, bis(2-methylcyclopentyl)dimethoxysilane, bis(3-tertiary butylcyclopentyl)dimethoxysilane, bis(2,3-dimethylcyclopentyl)dimethoxysilane, bis(2,5-dimethylcyclopentyl)dimethoxysilane, dicyclopentyldiethoxysilane, dicyclobutyldiethoxysilane, cyclopropylcyclobutyldiethoxysilane, dicyclopentenyldimethoxysilane, di(3-cyclopentenyl)dimethoxysilane, bi s(2,5-dimethyl-3-cyclopentenyl)dimethoxysilane, di-2,4-cyclopentadienyl)dimethoxysilane, bis(2,5-dimethyl-2,4-cyclopentadienyl)dimethoxysilane, bis(1-methyl-1-cyclopentylethyl)dimethoxysilane, cyclopentylcyclopentenyldimethoxysilane, cyclopentylcyclopentadienyldimethoxysilane, diindenyldimethoxysilane, bis(1,3-dimethyl-2-indenyl)dimethoxysilane, difluorenyldimethoxysilane, cyclopentadienylindenyldimethoxysilane, cyclopentylfluorenyldimethoxysilane and indenylfiuorenyldimethoxysilane; monoalkoxysilanes such as tricyclopentylmethoxysilane, tricyclopentenylmethoxysilane, tricyclopentadienylmethoxysilane, tricyclopentylethoxysilane, cyclopentylmethylmethoxysilane, dicyclopentylethylmethoxysilane, dicyclopentylmethylethoxysilane, cyclopentyldimethylmethoxysilane, cyclopentyldiethylmethoxysilane, cyclopentyldimethylethoxysilane, bis(2,5-dimethylcyclopentyl)cyclopentylmethoxysilane, dicyclopentylcyclopentenylmethoxysilane, dicyclopentylcyclopentenadienylmethoxysilane, diindenylcyclopentylmethoxysilane and ethylenebis-cyclopentyldimethoxysilane; aminosilanes such as aminopropyltriethoxysilane, n-(3-triethoxysilylpropyl)amine, bis[(3-triethoxysilyl)propyl] amine, aminopropyltrimethoxysilane, aminopropylmethyldiethoxysilane, hexanediaminopropyltrimethoxysilane and combination thereof.

8. The catalyst system as claimed in claim 3 , wherein the molar ratio of organoaluminum compound to the external donor is from about 0.1 to 500.

9. A process of polymerizing and/or copolymerizing olefins, said method comprising the step of contacting an olefin having C2 to C20 carbon atoms under a polymerizing condition with the catalyst system as obtained by claim 3 .

10. The polymerization process as claimed in claim 9 , wherein polymerization is carried out by slurry polymerization using an inert hydrocarbon solvent as a diluent, or bulk polymerization using the liquid monomer as a reaction medium and in gas-phase operating in one or more fluidized or mechanically agitated bed reactors.

11. The polymeri

Assignees

• Indian Oil Corp Ltd

Inventors

• Kaur Sukhdeep
• Singh Gurmeet
• Bantu Bhasker
• Kumar Naresh
• Kapur Gurpreet Singh
• Kant Shashi
• Basu Biswajit
• Malhotra Ravinder Kumar

Classifications

• C08F4/6541 Primary

  and metals of C08F4/64 or compounds thereof · CPC title

• B01J21/10

  Magnesium; Oxides or hydroxides thereof · CPC title

• C08F2/34

  Polymerisation in gaseous state · CPC title

• C08F4/16

  of silicon, germanium, tin, lead, titanium, zirconium or hafnium · CPC title

• C07F3/02 Primary

  Magnesium compounds · CPC title