Organic lithium battery

Patent metadata

Field	Value
Publication number	US-10608277-B2
Application number	US-201515533491-A
Country	US
Kind code	B2
Filing date	Dec 8, 2015
Priority date	Dec 10, 2014
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

The present invention relates to the field of organic lithium batteries having high energy and power densities. In particular, the present invention relates to an organic lithium battery comprising a positive electrode based on redox organic compounds and a porous separator made of biaxially oriented polypropylene, and to its process of manufacture.

First claim

The invention claimed is:

1. Organic lithium battery comprising:
a negative electrode comprising lithium metal or an alloy of lithium metal,
a positive electrode optionally supported by a current collector, said positive electrode comprising at least one redox organic structure, at least one polymer binder P 1 and at least one agent generating an electron conductivity,
said redox organic structure being different from sulphur-comprising organic compounds having at least one S—S bond, and
a porous separator impregnated with an electrolyte,
wherein the porous separator is a biaxially oriented separator comprising at least polypropylene and the electrolyte comprises at least one liquid linear or cyclic polyether with a molar mass of less than or equal to 10 000 g·mol −1 , and at least one lithium salt L 1 ,
wherein the positive electrode of the battery of the invention comprises at least 45% by weight of redox organic structure, with respect to the total weight of said positive electrode.

2. Battery according to claim 1 , wherein the porous separator exhibits a thickness ranging from 5 μm to 50 μm.

3. Battery according to claim 1 , wherein the porous separator exhibits a porosity of greater than or equal to 50% by volume.

4. Battery according to claim 1 , wherein the porous separator exhibits pores with a mean size ranging from 50 nm to 3 μm.

5. Battery according to claim 1 , wherein the porous separator exhibits an elongation at break of at least 5 mm.

6. Battery according to claim 1 , wherein the porous separator exhibits a porosity of Gurley type ranging from 50 to 500 s/100 cm 3 .

7. Battery according to claim 1 , wherein the porous separator exhibits a heat shrinkage in the longitudinal direction and/or a heat shrinkage in the transverse direction strictly of less than 15%, whatever its thickness.

8. Battery according to claim 1 , wherein the lithium salt L 1 is chosen from lithium fluorate (LiFO 3 ), lithium bis(trifluoromethanesulphonyl)imide (LiTFSI), lithium hexafluorophosphate (LiPF 6 ), lithium fluoroborate (LiBF 4 ), lithium metaborate (LiBO 2 ), lithium perchlorate (LiClO 4 ), lithium nitrate (LiNO 3 ), lithium bis(fluorosulphonyl)imide (LiFSI), lithium bis(oxalato)borate (LiBOB or LiB(C 2 O 4 ) 2 ) and their mixtures.

9. Battery according to claim 1 , wherein the electrolyte is a gelled polymer electrolyte and it additionally comprises at least one polymer binder P 2 .

10. Battery according to claim 9 , wherein the polymer binder P 2 is chosen from homopolymers and copolymers of ethylene; homopolymers and copolymers of propylene; homopolymers and copolymers of ethylene oxide, of methylene oxide, of propylene oxide, of epichlorohydrin or of allyl glycidyl ether, and their mixtures; halogenated polymers; non-electron-conducting polymers of anionic type; polyacrylates; polymers of cationic type; and one of their mixtures.

11. Battery according to claim 9 , wherein the gelled polymer electrolyte comprises from 20 to 70% by weight of polymer binder P 2 , with respect to the total weight of the gelled polymer electrolyte.

12. Battery according to claim 9 , wherein the gelled polymer electrolyte comprises from 15 to 45% by weight of lithium salt L 1 , with respect to the total weight of the gelled polymer electrolyte.

13. Battery according to claim 9 , wherein the gelled polymer electrolyte comprises from 5 to 40% by weight of liquid linear or cyclic polyether of low molar mass, with respect to the total weight of the gelled polymer electrolyte.

14. Battery according to claim 1 , wherein the electrolyte is a liquid electrolyte and the concentration of the lithium salt L 1 in the liquid electrolyte ranges from 0.5 to 8 mol/l.

15. Battery according to claim 1 , wherein the redox organic structure comprises at least two carbonyl C═O functional groups, two thione C═S functional groups or two imine C═N functional groups.

16. Battery according to claim 1 , wherein the positive electrode comprises from 1 to 30% by weight of agent generating an electron conductivity, with respect to the total weight of the positive electrode.

17. Battery according to claim 1 , wherein the agent generating an electron conductivity is chosen from carbon black, sp carbon, acetylene black, carbon fibres and nanofibres, carbon nanotubes, graphene, graphite, metal particles and fibres, and one of their mixtures.

18. Battery according to claim 1 , wherein the positive electrode comprises from 2 to 30% by weight of polymer binder P 1 , with respect to the total weight of the positive electrode.

19. Battery according to claim 1 , wherein the polymer binder P 1 is chosen from homopolymers and copolymers of ethylene; homopolymers and copolymers of propylene; homopolymers and copolymers of ethylene oxide, of methylene oxide, of propylene oxide, of epichlorohydrin or of allyl glycidyl ether, and their mixtures; halogenated polymers; polyacrylates; polyalcohols; electron-conducting polymers; polymers of cationic type; polymers of anionic type; and one of their mixtures.

20. Process for the manufacture of an organic lithium battery as defined in claim 1 , wherein said process comprises the following stages:
A) a stage of preparation of a liquid electrolyte or of a gelled polymer electrolyte,
B) a stage of assembling a positive electrode, a negative electrode and a porous separator, said process additionally comprising one or other of the following stages:
C-1) a stage of impregnation of the assembly as obtained in stage B) by the liquid electrolyte prepared in stage A), or
C-2) a stage of impregnation of the porous separator by the gelled polymer electrolyte prepared in stage A), said impregnation being prior to the assembling stage B).

21. Organic lithium battery comprising:
a negative electrode comprising lithium metal or an alloy of lithium metal,
a positive electrode optionally supported by a current collector, said positive electrode comprising at least one redox organic structure, at least one polymer binder P 1 and at least one agent generating an electron conductivity, said redox organic structure being different from sulphur-comprising organic compounds having at least one S—S bond, and
a porous separator impregnated with an electrolyte,
wherein the porous separator is a biaxially oriented separator comprising at least polypropylene, and
wherein the electrolyte is a gelled polymer electrolyte comprising at least one liquid linear or cyclic polyether with a molar mass of less than or equal to 10 000 g·mol −1 , at least one polymer binder P 2 , and from 15 to 45% by weight of at least one lithium salt L 1 , with respect to the total weight of the gelled polymer electrolyte.

22. Organic lithium battery comprising:
a negative electrode comprising lithium metal or an alloy of lithium metal,
a positive electrode optionally supported by a current collector, said positive electrode comprising at least one redox organic structure, at least one polymer binder P 1 and at least one agent generating an electron conductivity, said redox organic structure being different from sulphur-comprising organic compounds having at least one S—S bond, and
a porous separator impregnated with an electrolyte,
wherein the porous separator is a biaxially oriented separator comprising at least polypropylene, and
wherein the electrolyte is a gelled polymer electrolyte comprising at least one lithium salt L 1 , at least one polymer binder P 2 , and from 5 to 40% by weight of at least one liquid linear or cyclic pol

Assignees

• Blue Solutions
• Centre Nat Rech Scient
• Univ Nantes

Inventors

• Lecuyer Margaud
• Deschamps Marc
• Gaubicher Joël
• Poizot Philippe
• Guyomard Dominique
• Lestriez Bernard

Classifications

• H01M4/1391

  of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/60

  of organic compounds · CPC title

• H01M4/405

  Alloys based on lithium · CPC title

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title