Gel electrolyte composition for rechargeable batteries

Patent metadata

Field	Value
Publication number	US-2016197375-A1
Application number	US-201314910640-A
Country	US
Kind code	A1
Filing date	Aug 5, 2013
Priority date	Aug 5, 2013
Publication date	Jul 7, 2016
Grant date	—

Abstract

Compositions and methods for making gel electrolytes for batteries are disclosed. The gel electrolyte composition may include a polymer with a plurality of isocyanate groups and a blocking agent contacting at least one of the plurality of isocyanate groups. At least one negative electrode and at least one positive electrode may be in contact with the gel electrolyte composition to form a battery.

First claim

1 . A battery comprising:
a gel electrolyte composition comprising:
a polymer of isocyanatoethyl methacrylate having a blocking agent reacted with an isocyanate group of the isocyanatoethyl methacrylate;
at least one negative electrodes; and
at least one positive electrode,
wherein the at least one negative electrode and the at least one positive electrode are in contact with the gel electrolyte composition.

2 .- 3 . (canceled)

4 . The battery of claim 1 , wherein the blocking agent is selected from the group consisting of an alcohol, an imidazole, a methyl imidazole, a pyrazole, a pyrrole, a pyrrolidine, a morpholine, a pyridine, a piperidine, an alkyl malonate ester, an acetoacetic ester, a cyanoacetic ester, an oxime and a caprolactam.

5 . The battery of claim 1 , wherein the blocking agent is 3,4-dimethyl-1H-pyrazole.

6 . The battery of claim 1 , wherein the gel electrolyte composition comprises a polymerization product of 2-methyl-acrylic acid 2-[(3,4-dimethyl-pyrazole-1-carbonyl)-amino]-ethyl ester.

7 . The battery of claim 1 , wherein the at least one positive electrode is selected from the group consisting of a lithium compound, a sodium compound, a potassium compound, a magnesium compound, a calcium compound, a nickel compound, an iron compound and a copper compound.

8 . (canceled)

9 . The battery of claim 1 , wherein the at least one negative electrode is selected from the group consisting of a carbon compound, a titanate, a silicon compound and a germanium compound.

10 . (canceled)

11 . The battery of claim 1 , wherein the gel electrolyte composition further comprises a solvent selected from the group consisting of glycerol, sorbitol, propylene glycol, ethylene glycol, water, dioxane, benzonitrile, allyl methyl sulfone, diethyl carbonate, dimethyl carbonate, ethyl methyl carbonate, fluoroethylene carbonate, 3-(methylsulfonyl)-1-propyne and vinylene carbonate.

12 . The battery of claim 1 , wherein the gel electrolyte composition further comprises a lithium salt selected from the group consisting of Li 2 B 4 O 7 , Li 2 ZrO 3 , Li 2 TiO 3 , Li 4 SiO 4 , LiAlO 2 , LiBO 2 , LiAlSi2O 6 , LiPF 6 , LiAsF 6 , LiClO 4 , LiBF 4 and LiCF 3 SO 3 .

13 . The battery of claim 1 , wherein an electric current generated between the at least one positive electrode and the at least one negative electrode yields a battery voltage of about 0.001 V to about 10 V.

14 . (canceled)

15 . The battery of claim 1 , wherein the polymer further comprises a coordinating metal ion selected from the group consisting of Li, Na, K, Mg, Ca, Fe, Cu, Ni, Rb and.

16 . The battery of claim 1 , wherein the battery is a Li-ion battery, a Na-ion battery, a K-ion battery, a Ni—Li battery, a Ni-MH battery, a Rb-ion battery, or a Ca-ion battery.

17 . A gel electrolyte composition comprising:
a polymer of isocyanatoethyl methacrylate having a blocking agent reacted with an isocyanate group of the isocyanatoethyl methacrylate.

18 . (canceled)

19 . The gel electrolyte composition of claim 17 , wherein the blocking agent is selected from the group consisting of an alcohol, an imidazole, a methyl imidazole, a pyrazole, a pyrrole, a pyrrolidine, a morpholine, a pyridine, a piperidine, an alkyl malonate ester, an acetoacetic ester, a cyanoacetic ester, an oxime and a caprolactam.

20 . The gel electrolyte composition of claim 17 , further comprising a solvent selected from the group consisting of glycerol, sorbitol, propylene glycol, ethylene glycol, water, dioxane, benzonitrile, allyl methyl sulfone, diethyl carbonate, dimethyl carbonate, ethyl methyl carbonate, fluoroethylene carbonate and 3-(methylsulfonyl)-1-propyne, vinylene carbonate.

21 . The gel electrolyte composition of claim 17 , further comprising a lithium salt selected from the group consisting of Li 2 B 4 O 7 , Li 2 ZrO 3 , Li 2 TiO 3 , Li 4 SiO 4 , LiAlO 2 , LiBO 2 , LiAlSi2O 6 , LiPF 6 , LiAsF 6 , LiClO 4 , LiBF 4 and LiCF 3 SO 3 .

22 . The gel electrolyte composition of claim 17 , wherein the polymer is present in the gel electrolyte composition at a concentration of about 0.01 weight percent to about 99 weight percent.

23 . The gel electrolyte composition of claim 17 , wherein the polymer further comprises a coordinating metal ion selected from the group consisting of Li, Na, K, Mg, Ca, Fe, Cu, Ni and Rb.

24 . A method of preparing a gel electrolyte composition, the method comprising:
contacting a monomer with a solvent, a cross-linker and an initiator to form a mixture, wherein the monomer comprises isocyanatoethyl methacrylate having a blocked isocyanate group; and heating the mixture.

25 . The method of claim 24 , wherein the contacting the monomer comprises contacting 2-methyl-acrylic acid 2-[(3,4-dimethyl-pyrazole-1-carbonyl)-amino]-ethyl ester.

26 . The method of claim 24 , further comprising forming the monomer by reacting an unblocked isocyanatoethyl methacrylate with a blocking agent, wherein the blocking agent reacts with an isocyanate group of the isocyanatoethyl methacrylate.

27 .- 28 . (canceled)

29 . The method of claim 26 , wherein the reacting comprises reacting with the blocking agent selected from the group consisting of an alcohol, an imidazole, a methyl imidazole, a pyrazole, a pyrrole, a pyrrolidine, a morpholine, a pyridine, a piperidine, an alkyl malonate ester, an acetoacetic ester, a cyanoacetic ester, an oxime and a caprolactam.

30 . The method of claim 26 , wherein the reacting comprises reacting with a blocking agent comprising 3,4-dimethyl-1H-pyrazole.

31 . The method of claim 24 , wherein the contacting comprises contacting with a solvent selected from the group consisting of glycerol, sorbitol, propylene glycol, ethylene glycol, water, dioxane, benzonitrile, allyl methyl sulfone, diethyl carbonate, dimethyl carbonate, ethyl methyl carbonate, fluoroethylene carbonate, 3-(methylsulfonyl)-1-propyne and vinylene carbonate.

32 . The method of claim 24 , wherein the contacting comprises contacting with a solvent further comprising a lithium salt selected from the group consisting of Li 2 B 4 O 7 , Li 2 ZrO 3 , Li 2 TiO 3 , Li 4 SiO 4 , LiAlO 2 , LiBO 2 , LiAlSi2O 6 , LiPF 6 , LiAsF 6 , LiClO 4 , LiBF 4 and LiCF 3 SO 3 .

33 . The method of claim 24 , wherein the contacting comprises contacting with a cross-linking agent selected from the group consisting of methylene(bis)acrylamide, polyethylene glycol dimethacrylate, glycerol dimethacrylate, ethylene glycol dimethacrylate, propylene glycol dimethacrylate, neopentyl glycol dimethacrylate, 1,3-butanediol dimethacrylate, bisphenol A dimethacrylate, diurethane dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, poly(propylene glycol) dimethacrylate, bisphenol A glycerolate dimethacrylate, bisphenol A ethoxylate dimethacrylate and bis(2-methacryloyl)oxyethyl disulfide.

34 . The method of claim 24 , wherein the contacting comprises contacting with an initiator selected from the group consisting of a persulfate, a peroxide and a thiosulfate.

35 . The method of claim 24 , wherein heating the mixture comprises heating at a temperature of about 50° C. to about 90° C. for about 30 minutes to about 2 hours.

36 .- 47 . (canceled)

Assignees

• Empire Technology Dev Llc

Inventors

• Carlson William Brenden
• Phelan Gregory David

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M2300/0085

  Immobilising or gelification of electrolyte · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title