Method for ultra-fast boriding
US-9556531-B2 · Jan 31, 2017 · US
US10597784B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10597784-B2 |
| Application number | US-201715652782-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 18, 2017 |
| Priority date | Jul 18, 2017 |
| Publication date | Mar 24, 2020 |
| Grant date | Mar 24, 2020 |
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A spray nozzle has a body having a flow passage. At least along a portion of the flow passage the body has a depth-wise compositional variation having: a cemented carbide first region; and a cemented carbide second region closer to the flow passage than the first region and having a higher boron content than a boron content, if any, of the first region.
Opening claim text (preview).
What is claimed is: 1. A spray nozzle comprising: a body having a flow passage, wherein at least along a portion of the flow passage the body has a depth-wise compositional variation comprising: a cemented carbide first region; and a cemented carbide second region closer to the flow passage than the first region and having a higher boron content than a boron content, if any, of the first region. 2. The spray nozzle of claim 1 wherein: the flow passage is converging-diverging. 3. The spray nozzle of claim 1 wherein the first region has a weight percent composition of: at least 80 percent tungsten carbide; at least 5.0 percent cobalt; no more than 0.1 percent boron, if any; and other elements, if any, no more than 1.0 percent total and no more than 0.75 percent individually. 4. The spray nozzle of claim 1 wherein the second region has a boron content of at least 0.2 weight percent higher than a boron content of the first region, if any. 5. The spray nozzle of claim 1 wherein the second region has a boron content of at least 1.0 weight percent higher than a boron content of the first region, if any. 6. The spray nozzle of claim 1 wherein the second region has a boron content of at least 0.2 weight percent. 7. The spray nozzle of claim 1 wherein: a boron content at a depth in the second region is 1.0 weight percent to 10.0% weight percent. 8. A cold spray apparatus including the spray nozzle of claim 1 and further comprising: a powder source; and a carrier gas source. 9. The cold spray apparatus of claim 8 further comprising: a heater for heating the carrier gas. 10. A method for manufacturing the spray nozzle of claim 1 , the method comprising: placing a boriding powder into a passageway of a cemented carbide precursor of the spray nozzle; and heating the precursor so as to diffuse boron from the boriding powder into the precursor. 11. The method of claim 10 wherein: the cemented carbide precursor has at least 70% WC by weight. 12. The method of claim 11 wherein: the cemented carbide precursor has at least 4.0% combined Ni and Co by weight. 13. The method of claim 11 wherein the cemented carbide precursor has one or more: at least 6.0% combined Ni and Co by weight; up to 5.0% TaC, if any, by weight; up to 5.0% total other, if any by weight; and up to 2.0% individually other, if any, by weight. 14. The method of claim 10 further comprising: forming the precursor by machining the passageway. 15. The method of claim 10 wherein: the boriding powder comprises least 10 wt % B and 5.0 wt % KBF 4 . 16. The method of claim 10 wherein: the heating is to at least 850° C. 17. The method of claim 10 wherein: the heating is to 850° C. to 1000° C. 18. A method for using the spray nozzle of claim 1 , the method comprising: flowing a powder and a carrier gas through the nozzle; and directing a spray of the powder from the nozzle to a substrate. 19. The method of claim 18 further comprising: heating the carrier gas. 20. The method of claim 18 wherein the powder comprises at least one of: ceramic particles; and metallic particles.
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