Electrode mixture layer

Patent metadata

Field	Value
Publication number	US-10586989-B2
Application number	US-201715730912-A
Country	US
Kind code	B2
Filing date	Oct 12, 2017
Priority date	Nov 22, 2016
Publication date	Mar 10, 2020
Grant date	Mar 10, 2020

Abstract

Provided is an electrode mixture layer capable of reducing internal resistance by use of a carbon nanotube molding. The electrode mixture layer includes an active material and a conductor of carbon nanotubes in close contact with the surface of the active material, and the number density of the carbon nanotubes is 4 tubes/μm or more. The number density is defined as a value obtained by providing measurement lines on a scanning electron microscope image of a surface of the electrode mixture layer at 0.3 μm intervals both longitudinally and laterally, measuring the total number of the carbon nanotubes being in close contact with the surface of the active material and intersecting the measurement lines, and dividing the total number of the carbon nanotubes by the total length of the measurement lines on the active material surface.

First claim

What is claimed is:

1. An electrode mixture layer comprising:
an active material; and
a conductor of carbon nanotubes in close contact with the surface of the active material,
wherein a number density of the carbon nanotubes in close contact with a surface of the active material is 4 tubes/μm or more,
the number density is defined as a value obtained by providing measurement lines on a scanning electron microscope image of a surface of the electrode mixture layer at 0.3 μm intervals both longitudinally and laterally, measuring a total number of the carbon nanotubes being in close contact with the surface of the active material and intersecting the measurement lines, and dividing the total number of the carbon nanotubes by a total length of the measurement lines on the active material surface,
the electrode mixture layer comprises a three-dimensional carbon nanotube fiber bundle skeletons in close contact with the surface of the active material,
the three-dimensional carbon nanotube fiber bundle skeletons are formed by intersection and assembly of a plurality of carbon nanotubes,
a number density of the carbon nanotubes or the three-dimensional carbon nanotube fiber bundle skeletons in close contact with the surface of the active material is 4 tubes/μm or more, and
the number density is defined as a value obtained by providing measurement lines on a scanning electron microscope image of a surface of the electrode mixture layer at 0.3 μm intervals both longitudinally and laterally, measuring a total number of the carbon nanotubes or the three-dimensional carbon nanotube fiber bundle skeletons being in close contact with the surface of the active material and intersecting the measurement lines, and dividing a total number of the carbon nanotubes or the three-dimensional carbon nanotube fiber bundle skeletons by the total length of the measurement lines on the active material surface.

2. The electrode mixture layer according to claim 1 , wherein the carbon nanotubes have a diameter in a range of 0.8 nm to 2.2 μm.

3. The electrode mixture layer according to claim 1 , wherein the three-dimensional carbon nanotube fiber bundle skeletons have a diameter in a range of 0.8 nm to 2.2 μm.

4. A battery comprising:
a positive electrode that comprises a positive electrode-side electrode mixture layer containing a positive electrode active material, and a current collector;
a negative electrode that comprises a negative electrode-side electrode mixture layer containing a negative electrode active material, and a current collector; and
an electrolyte sandwiched by the positive electrode and the negative electrode,
wherein at least one of the positive electrode-side electrode mixture layer and the negative electrode-side electrode mixture layer is the electrode mixture layer according to claim 1 .

Assignees

• Honda Motor Co Ltd

Inventors

• Tokune Toshio
• Nishinuma Takuya
• Komori Takahiro
• Inoue Kenshi
• Tanaami Kiyoshi
• Nakagawa Takashi

Classifications

• C01B32/16

  Preparation · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/8875

  Methods for shaping the electrode into free-standing bodies, like sheets, films or grids, e.g. moulding, hot-pressing, casting without support, extrusion without support · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• H01M4/625

  Carbon or graphite · CPC title