Heat treatable coated article having titanium nitride and ITO based IR reflecting layers

Patent metadata

Field	Value
Publication number	US-10584058-B2
Application number	US-201916550884-A
Country	US
Kind code	B2
Filing date	Aug 26, 2019
Priority date	Feb 23, 2017
Publication date	Mar 10, 2020
Grant date	Mar 10, 2020

Abstract

Coated articles include two or more functional infrared (IR) reflecting layers optionally sandwiched between at least dielectric layers. The dielectric layers may be of or including silicon nitride or the like. At least one of the IR reflecting layers is of or including titanium nitride (e.g., TIN) and at least another of the IR reflecting layers is of or including indium-tin-oxide (ITO).

First claim

What is claimed is:

1. A coated article including a coating supported by a glass substrate, the coating comprising:
a first dielectric layer comprising silicon nitride on the glass substrate;
a first infrared (IR) reflecting layer comprising ITO on the glass substrate, wherein the first dielectric layer comprising silicon nitride is located between at least the glass substrate and the first IR reflecting layer comprising ITO;
a second dielectric layer comprising silicon nitride on the glass substrate over at least the first IR reflecting layer comprising ITO;
a second layer IR reflecting layer comprising a nitride of titanium on the glass substrate over at least the first and second dielectric layers comprising silicon nitride, so that the second dielectric layer comprising silicon nitride is located between and directly contacting the first IR reflecting layer comprising ITO and the second IR reflecting layer comprising the nitride of titanium;
a third dielectric layer comprising silicon nitride on the glass substrate over at least the second IR reflecting layer comprising the nitride of titanium;
wherein the coating contains no IR reflecting layer based on silver, and contains only two IR reflecting layers;
wherein the first IR reflecting layer comprising ITO is from 250-450 Å thick, and the second IR reflecting layer comprising the nitride of titanium is from 130-300 Å thick; and
wherein the coated article measured monolithically has: a visible transmission from about 15-80%, a film side visible reflectance no greater than 10%, a glass side visible reflectance no greater than about 30%, a glass side reflective a* value of from −10.0 to +1.6, and a light-to-solar gain ratio (LSG) of at least 1.10.

2. The coated article of claim 1 , wherein the second IR reflecting layer comprising the nitride of titanium comprises TiN x , where x is from 0.8 to 1.2.

3. The coated article of claim 1 , wherein the second IR reflecting layer comprising the nitride of titanium comprises TiN x , where x is from 0.9 to 1.1.

4. The coated article of claim 1 , wherein the second IR reflecting layer contains from 0-8% oxygen (atomic %).

5. The coated article of claim 1 , wherein the second IR reflecting layer contains from 0-5% oxygen (atomic %).

6. The coated article of claim 1 , wherein the first dielectric layer comprising silicon nitride directly contacts the glass substrate and the first IR reflecting layer.

7. The coated article of claim 6 , wherein the first dielectric layer comprising silicon nitride further comprises oxygen.

8. The coated article of claim 1 , where the second IR reflecting layer consists essentially of the nitride of titanium.

9. The coated article of claim 1 , wherein the coating further comprises an overcoat comprising an oxide of zirconium.

10. The coated article of claim 1 , wherein the coated article has a visible transmission from about 20-70%, and a light-to-solar gain ratio (LSG) of at least 1.15.

11. The coated article of claim 1 , wherein the coated article has a film side visible reflectance no greater than 5%.

12. The coated article of claim 1 , wherein the glass substrate is a clear glass substrate.

13. The coated article of claim 1 , wherein the coated article is a monolithic window.

14. A coated article including a coating supported by a glass substrate, the coating comprising:
a first dielectric layer comprising silicon nitride on the glass substrate;
a first infrared (IR) reflecting layer comprising ITO on the glass substrate, wherein the first dielectric layer comprising silicon nitride is located between at least the glass substrate and the first IR reflecting layer comprising ITO;
a second dielectric layer comprising silicon nitride on the glass substrate over at least the first IR reflecting layer comprising ITO;
a second layer IR reflecting layer comprising a nitride of titanium on the glass substrate over at least the first and second dielectric layers comprising silicon nitride, so that the second dielectric layer comprising silicon nitride is located between at least the first IR reflecting layer comprising ITO and the second IR reflecting layer comprising the nitride of titanium;
a third dielectric layer comprising silicon nitride on the glass substrate over at least the second IR reflecting layer comprising the nitride of titanium;
wherein the coating contains no IR reflecting layer based on silver, and contains only two IR reflecting layers;
wherein the coating has a normal emittance (E n ) value of no greater than 0.30;
wherein the first IR reflecting layer comprising ITO is from 250-450 Å thick, and the second IR reflecting layer comprising the nitride of titanium is from 130-300 Å thick; and
wherein the coated article measured monolithically has a visible transmission from about 15-80%.

15. A coated article including a coating supported by a glass substrate, the coating comprising:
a first dielectric layer comprising silicon nitride on the glass substrate;
a first infrared (IR) reflecting layer comprising ITO on the glass substrate, wherein the first dielectric layer comprising silicon nitride is located between at least the glass substrate and the first IR reflecting layer comprising ITO;
a second dielectric layer comprising silicon nitride on the glass substrate over at least the first IR reflecting layer comprising ITO;
a second layer IR reflecting layer comprising a nitride of titanium on the glass substrate over at least the first and second dielectric layers comprising silicon nitride, so that the second dielectric layer comprising silicon nitride is located between at least the first IR reflecting layer comprising ITO and the second IR reflecting layer comprising the nitride of titanium;
a third dielectric layer comprising silicon nitride on the glass substrate over at least the second IR reflecting layer comprising the nitride of titanium;
wherein the coating contains no IR reflecting layer based on silver, and contains only two IR reflecting layers;
wherein the first IR reflecting layer comprising ITO is from 250-450 Å thick, and the second IR reflecting layer comprising the nitride of titanium is from 130-300 Å thick; and
wherein the coated article measured monolithically has a visible transmission from about 15-80% and a light-to-solar gain ratio (LSG) of at least 1.15.

Assignees

• Guardian Glass Llc

Inventors

• Boyce Brent
• Lu Yiwei
• Ding Guowen
• Clavero Cesar
• Schweigert Daniel
• Le Minh

Classifications

• G02B5/282

  reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection · CPC title

• C03C2218/154

  by sputtering · CPC title

• C03C17/002

  for flat glass, e.g. float glass · CPC title

• C23C14/0641

  Nitrides (C23C14/0617 takes precedence) · CPC title

• C03C17/3435 Primary

  comprising a nitride, oxynitride, boronitride or carbonitride · CPC title