Gasification process and feed system

Patent metadata

Field	Value
Publication number	US-10557095-B2
Application number	US-201516061563-A
Country	US
Kind code	B2
Filing date	Dec 14, 2015
Priority date	Dec 14, 2015
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

A process for the gasification of a solid carbonaceous feed, the process comprising the steps of: introducing a batch of the solid carbonaceous feed into a sluice vessel, while an internal pressure in the sluice vessel is at a first pressure; introducing at least recycled CO2 into the sluice vessel via one or more gas inlets covered by the solid carbonaceous feed, to pressurize the sluice vessel from the first pressure to a second pressure exceeding the first pressure, during a predetermined time period; closing the one or more gas inlets; opening a feed outlet of the sluice vessel to supply the batch of the solid carbonaceous feed to a feed vessel for feeding the solid carbonaceous feed to a gasification reactor; closing the feed outlet; venting the sluice vessel to reduce the internal pressure to the first pressure; and repeating the process.

First claim

The invention claimed is:

1. A process for the gasification of a solid carbonaceous feed, the process comprising the steps of:
introducing a batch of the solid carbonaceous feed into a sluice vessel, while an internal pressure in the sluice vessel is at a first pressure;
introducing a CO 2 -containing feedback gas comprising methanol into the sluice vessel via one or more gas inlets covered by the solid carbonaceous feed, to pressurize the sluice vessel from the first pressure to a second pressure exceeding the first pressure, during a predetermined time period;
closing the one or more gas inlets;
opening a feed outlet of the sluice vessel to supply the batch of the solid carbonaceous feed to a feed vessel for feeding the solid carbonaceous feed to a gasification reactor;
closing the feed outlet;
venting the sluice vessel to reduce the internal pressure to the first pressure; and repeating the process;
wherein the CO 2 -containing feedback gas is introduced into the sluice vessel only via the one or more gas inlets which are covered by the solid carbonaceous feed, and at a flow rate which is at most 0.3 m 3 per minute for each 0.5 kg of solid carbonaceous feed in the batch.

2. The process of claim 1 , wherein the second pressure exceeds 40 bar.

3. The process of claim 1 , wherein the predetermined time period for pressurizing the sluice vessel is at least 10 minutes.

4. The process of claim 1 , wherein the CO 2 -containing feedback gas is derived from a Rectisol syngas treating process which uses methanol as an absorbent.

5. The process of claim 4 , wherein the CO 2 -containing feedback gas comprises methanol in a concentration of at least 300 to 400 ppm (volume).

6. The process of claim 1 , comprising a step of heating the walls of the sluice vessel after the step of introducing a batch of the solid carbonaceous feed.

7. The process of claim 6 , the step of heating the walls of the sluice vessel comprises heating by heat exchange with water.

8. The process of claim 6 wherein the step of heating the walls of the sluice vessel comprises heating the walls of the sluice vessel up to at least 90 degrees C.

9. The process of claim 8 , comprising a step of keeping the sluice vessel at an elevated temperature of at least 90 degrees C. and the second pressure during a second time period.

10. The process of claim 9 , wherein the second time period is at least 10 minutes.

Assignees

• Air Prod & Chem

Inventors

• Xu Jiang
• Van Den Berg Robert Erwin

Classifications

• C10K3/06

  by mixing with gases · CPC title

• C10J2300/1815

  for carbon dioxide · CPC title

• C10J2200/156

  Sluices, e.g. mechanical sluices for preventing escape of gas through the feed inlet · CPC title

• C10J3/50

  Fuel charging devices · CPC title

• C10J3/78

  High-pressure apparatus · CPC title