Alkali source and/or sink using ion-conducting solid electrolyte and intercalation-compound electrode

Patent metadata

Field	Value
Publication number	US-10545461-B1
Application number	US-201715639391-A
Country	US
Kind code	B1
Filing date	Jun 30, 2017
Priority date	Aug 31, 2016
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

Some variations provide an alkali metal or alkaline earth metal vapor cell with a solid ionic conductor and intercalable-compound electrodes. The intercalable-compound electrodes are used as efficient sources and/or as sinks for alkali metal or alkaline earth metal atoms, thus enabling electrical control over metal atom content in the vapor cell. Some variations provide a vapor-cell system comprising: a vapor-cell region configured to allow a vapor-cell optical path into a vapor-cell vapor phase; a first electrode containing an intercalable compound capable of being intercalated by at least one element selected from Rb, Cs, Na, K, or Sr; a second electrode electrically isolated from the first electrode; and an ion-conducting layer between the first electrode and the second electrode. The ion-conducting layer is ionically conductive for at least one ionic species selected from Rb+, Cs+, Na+, K+, or Sr2+. The first intercalable compound is preferably a carbonaceous material, such as graphite.

First claim

What is claimed is:

1. A vapor-cell system comprising:
a vapor-cell region configured to allow at least one vapor-cell optical path into a vapor-cell vapor phase within said vapor-cell region;
a first electrode disposed in contact with said vapor-cell region, wherein said first electrode contains a first intercalable compound;
a second electrode that is electrically isolated from said first electrode; and
an ion-conducting layer interposed between said first electrode and said second electrode, wherein said ion-conducting layer is in ionic communication with said second electrode, and wherein said ion-conducting layer is ionically conductive for at least one ionic species selected from the group consisting of Rb + , Cs + , Na + , K + , and Sr 2+ .

2. The vapor-cell system of claim 1 , wherein said first intercalable compound is a carbonaceous material selected from the group consisting of graphite, graphene, carbon nanotubes, fullerenes, activated carbon, coke, pitch coke, petroleum coke, carbon black, amorphous carbon, glassy carbon, pyrolyzed carbon-containing molecules, pyrolyzed parylene, polyaromatic hydrocarbons, and combinations thereof.

3. The vapor-cell system of claim 2 , wherein said carbonaceous material comprises graphite.

4. The vapor-cell system of claim 2 , wherein said carbonaceous material comprises pyrolyzed parylene.

5. The vapor-cell system of claim 1 , wherein said first intercalable compound is a transition-metal oxide, a transition-metal dichalcogenide, or a combination thereof.

6. The vapor-cell system of claim 1 , wherein said first intercalable compound is intercalative for at least one element selected from the group consisting of Rb, Cs, Na, K, and Sr.

7. The vapor-cell system of claim 1 , wherein said ion-conducting layer contains said at least one ionic species selected from the group consisting of Rb + , Cs + , Na + , K + , and Sr 2+ .

8. The vapor-cell system of claim 7 , wherein said first intercalable compound is intercalated by a neutral form of said at least one ionic species selected from the group consisting of Rb + , Cs + , Na + , K + , and Sr 2+ .

9. The vapor-cell system of claim 1 , wherein said vapor-cell region contains a vapor phase comprising metal atoms that are intercalable in said first intercalable compound.

10. The vapor-cell system of claim 9 , wherein said metal atoms are selected from the group consisting of Rb, Cs, Na, K, Sr, and combinations thereof, wherein said ion-conducting layer contains said at least one ionic species selected from the group consisting of Rb + , Cs + , Na + , K + , and Sr 2+ , and wherein said metal atoms are the same element as said at least one ionic species.

11. The vapor-cell system of claim 1 , wherein said ion-conducting layer comprises β-alumina, β″-alumina, yttria-stabilized zirconia, NASICON, LISICON, KSICON, or combinations thereof.

12. The vapor-cell system of claim 1 , wherein said second electrode contains a second intercalable compound.

13. The vapor-cell system of claim 12 , wherein said second intercalable compound is a carbonaceous material selected from the group consisting of graphite, graphene, holey graphene, graphene platelets, carbon nanotubes, fullerenes, activated carbon, coke, pitch coke, petroleum coke, carbon black, amorphous carbon, glassy carbon, pyrolyzed carbon-containing molecules, pyrolyzed parylene, polyaromatic hydrocarbons, and combinations thereof.

14. The vapor-cell system of claim 13 , wherein said second intercalable compound comprises graphite, pyrolyzed parylene, or a combination thereof.

15. The vapor-cell system of claim 12 , wherein said second intercalable compound is a transition-metal oxide, a transition-metal dichalcogenide, or a combination thereof.

16. The vapor-cell system of claim 12 , wherein said second intercalable compound is intercalative for at least one element selected from the group consisting of Rb, Cs, Na, K, and Sr.

17. The vapor-cell system of claim 12 , wherein said second intercalable compound is a different material from said first intercalable compound.

18. The vapor-cell system of claim 12 , wherein said second intercalable compound is intercalated by a neutral form of said at least one ionic species selected from the group consisting of Rb + , Cs + , Na + , K + , and Sr 2+ .

19. The vapor-cell system of claim 12 , wherein said vapor-cell region contains a vapor phase comprising metal atoms that are intercalable in said second intercalable compound.

20. The vapor-cell system of claim 1 , wherein said second electrode is in contact with a reservoir region containing alkali or alkaline earth metal atoms.

21. The vapor-cell system of claim 1 , said system further comprising an atom chip.

22. The vapor-cell system of claim 1 , said system further comprising electrical traces physically located on, but electrically insulated from, said ion-conducting layer.

23. The vapor-cell system of claim 1 , wherein said vapor-cell system is configured to allow three vapor-cell optical paths within said vapor-cell vapor phase.

24. The vapor-cell system of claim 1 , wherein said vapor-cell system further includes a heater attached to said vapor-cell system, or in thermal or electromagnetic communication with said vapor-cell system.

25. A magneto-optical trap apparatus, said apparatus comprising:
a vapor-cell region configured to allow at least one vapor-cell optical path into a vapor-cell vapor phase within said vapor-cell region;
a first electrode disposed in contact with said vapor-cell region, wherein said first electrode contains a first intercalation compound that is intercalated by at least one element, in ionic or neutral form, selected from the group consisting of Rb, Cs, Na, K, and Sr;
a second electrode that is electrically isolated from said first electrode, wherein said second electrode contains a second intercalation compound that is intercalated by said at least one element, in ionic or neutral form, selected from the group consisting of Rb, Cs, Na, K, and Sr; and
an ion-conducting layer interposed between said first electrode and said second electrode, wherein said ion-conducting layer is in ionic communication with said second electrode, wherein said ion-conducting layer is ionically conductive for at least one ionic species selected from the group consisting of Rb + , Cs + , Na + , K + , and Sr 2+ , wherein said ion-conducting layer contains mobile ions comprising said at least one ionic species.

Assignees

• Hrl Lab Llc

Inventors

• Roper Christopher S
• Gross Adam F
• Rakher Matthew T
• Sorenson Logan D
• Vajo John J
• Graetz Jason A
• Mott Russell
• Kim Danny

Classifications

• G04F5/145 Primary

  using Coherent Population Trapping · CPC title

• H01P7/06

  Cavity resonators · CPC title

• H03L7/26

  using energy levels of molecules, atoms, or subatomic particles as a frequency reference · CPC title

• C22B26/10

  Obtaining alkali metals · CPC title