Method and system for forming carbonate from steel slag

Patent metadata

Field	Value
Publication number	US-10526669-B2
Application number	US-201715658937-A
Country	US
Kind code	B2
Filing date	Jul 25, 2017
Priority date	Dec 19, 2016
Publication date	Jan 7, 2020
Grant date	Jan 7, 2020

Abstract

The present invention relates to a method and system for recovering carbonate from steel slag, in which it is possible to extract carbonate from steel slag and reuse the extracted carbonate, and to recycle steel slag and make use of CO 2 gas without emission to the atmosphere. Since unreacted metal ions and an acidic solvent are reused in the method and system, it is possible to increase carbonate extraction efficiency and reduce an amount of waste.

First claim

What is claimed is:

1. A method of forming carbonate from steel slag, comprising:
1) mixing steel slag and an acidic solvent to produce a first mixture containing metal ions;
2) separating the first mixture into a second mixture, containing the metal ions, and residues by allowing the first mixture to pass through a first filter;
3) inserting and mixing ligands into and with the second mixture to selectively extract specific metal ions of the second mixture by bonding the ligands to the specific metal ions in order to produce a third mixture containing a complex compound produced by reaction of the specific metal ions in the second mixture with the ligands;
4) separating the reacted metal ions and the reacted ligands of the complex compound from the third mixture by capacitive deionization;
5) reacting the separated metal ions and ligands of the complex compound with CO 2 to produce carbonate; and
6) separating the produced carbonate by filtration.

2. The method according to claim 1 , wherein:
the complex compound with no charge is separated from unreacted charged ligands and unreacted charged metal ions by the capacitive deionization using a single capacitive deionizer in the 4) separating the complex compound from the third mixture; and
the unreacted charged ligands and the unreacted charged metal ions are supplied to the 1) mixing steel slag and an acidic solvent.

3. The method according to claim 2 , wherein, in the 4) separating the complex compound from the third mixture:
the unreacted charged metal ions and the unreacted charged ligands are bonded to a pair of electrodes of the single capacitive deionizer; and
the acidic solvent flows to the single capacitive deionizer so that the unreacted charged ligands and the unreacted charged metal ions move from the electrodes to the acidic solvent by adjusting potentials of the electrodes.

4. The method according to claim 1 , wherein:
the complex compound with no charge is separated from unreacted charged ligands and unreacted charged metal ions by the capacitive deionization using a multistage capacitive deionizer in the 4) separating the complex compound from the third mixture;
the unreacted charged metal ions are recovered and supplied to the 1) mixing steel slag and an acidic solvent; and
the unreacted charged ligands are recovered and supplied to the 3) inserting and mixing ligands into and with the second mixture.

5. The method according to claim 4 , wherein, in the 4) separating the complex compound from the third mixture:
the unreacted charged ligands are bonded to an anode of the multistage capacitive deionizer; and
the acidic solvent flows to the multistage capacitive deionizer so that the unreacted charged ligands move from the electrodes to the acidic solvent by changing the anode to a cathode, the method further comprising:
supplying the acidic solvent containing the recovered unreacted charged ligands to the 3) inserting and mixing ligands into and with the second mixture.

6. The method according to claim 4 , wherein, in the 4) separating the complex compound from the third mixture:
the unreacted charged metal ions are bonded to a cathode of the multistage capacitive deionizer; and
the acidic solvent flows to the multistage capacitive deionizer so that the unreacted charged metal ions move from the electrodes to the acidic solvent by changing the cathode to an anode, the method further comprising:
supplying the acidic solvent containing the recovered unreacted charged metal ions to the 1) mixing steel slag and an acidic solvent.

7. The method according to claim 1 , wherein the acidic solvent is one or more selected from the group consisting of nitric acid (HNO 3 ), hydrochloric acid (HCl), sulfuric acid (H 2 SO 4 ), hydrobromide acid (HBr), hydroiodide acid (HI), perchloric acid (HClO 4 ), and phosphoric acid (H 3 PO 4 ).

8. The method according to claim 1 , wherein the metal ions of the first mixture are calcium ions (Ca 2+ ).

9. The method according to claim 1 , wherein the ligands are ligands selected from the group consisting of CH 3 COOH, C 6 H 9 NO 6 , C 6 H 5 NO 2 , HN(CH 2 CO 2 H) 2 , citrate 3+ , glutamate + , and C 2 H 2 O 4 .

10. The method according to claim 1 , wherein the carbonate is CaCO 3 .

11. The method according to claim 1 , wherein the first filter has pores with a diameter of 30 μm to 50 μm.

Assignees

• Doosan Heavy Ind & Construction Co Ltd
• Doosan Heavy Ind Constr Co Ltd

Inventors

• You Jang Yong
• Koo Ja Hyung
• Shin Kwang Hee
• Kim You Seok

Classifications

• C21B2400/02

  Physical or chemical treatment of slags · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C21B2100/80

  Interaction of exhaust gases produced during the manufacture of iron or steel with other processes · CPC title

• C01B32/60

  Preparation of carbonates or bicarbonates in general (of percarbonates C01B15/10; of specific carbonates or bicarbonates according to the cation C01B-C01G) · CPC title

• C01F11/18

  Carbonates · CPC title