Process for modifying steel slag through acidification and carbonization coupling

Patent metadata

Field	Value
Publication number	US-11572307-B1
Application number	US-202217845175-A
Country	US
Kind code	B1
Filing date	Jun 21, 2022
Priority date	Nov 24, 2021
Publication date	Feb 7, 2023
Grant date	Feb 7, 2023

Abstract

The present invention belongs to the technical field of metallurgical solid waste resource utilization, and particularly relates to acidification and carbonization coupling modified steel slag as well as a preparation process and an application thereof. The process specifically includes the following steps of adopting acetic acid, tributyl phosphate, ethanolamine and a NaOH and Ca(OH) 2 emulsion as reaction reinforcing agents, and modifying the steel slag together with CO 2 -rich lime kiln flue gas. The process for modifying the steel slag through acidification and carbonization coupling provided in the present invention has the advantages of simple reaction conditions and no need of high-pressure CO 2 , additionally, the carbonation reaction rate can be greatly increased, and f-CaO and f-MgO in the steel slag can be effectively eliminated.

First claim

What is claimed is:

1. A process for modifying steel slag through acidification and carbonization coupling, wherein acetic acid, tributyl phosphate, ethanolamine and a NaOH and Ca(OH) 2 emulsion are used as reaction reinforcing agents, and the steel slag is modified together with CO 2 -rich lime kiln flue gas;
the process for modifying the steel slag through acidification and carbonization coupling specifically comprises the steps of sequentially adding water and acetic acid solid to the steel slag, mixing and reacting for 20-60 min, then introducing the lime kiln flue gas containing CO 2 gas, and meanwhile, and adding the tributyl phosphate, the NaOH and Ca(OH) 2 emulsion and the ethanolamine for acidification and carbonization coupling reaction;
when the water and the acetic acid solid are sequentially added to the steel slag, the water amount is controlled according to the liquid-solid ratio of 20:1 to 5:1, and the concentration of the acetic acid is controlled to be 5% to 20%;
the final total amount of the tributyl phosphate is the same as the molar mass of the added acetic acid;
the amount of the NaOH and Ca(OH) 2 emulsion is required to adjust the pH value of liquid between 8 and 11; and
the amount of the ethanolamine is 5% to 20%.

2. The process for modifying the steel slag through acidification and carbonization coupling according to claim 1 , wherein the acidification and carbonization coupling reaction time is controlled to be 15-30 min.

3. The process for modifying the steel slag through acidification and carbonization coupling according to claim 1 , wherein the flue gas pressure is controlled to be 0.1-2 MPa.

4. The process for modifying the steel slag through acidification and carbonization coupling according to claim 1 , wherein the reaction temperature is 25-100° C.

Assignees

• Univ Shandong
• Qingdao Daneng Environmental Prot Equipment Co Ltd
• Qingdao Haitai Energy Science And Tech Research Institute

Inventors

• Chang Jingcai
• Wang Yong
• Liang Xiaojie
• Wang Peng
• Li Shusheng
• Ma Chunyuan
• Liu Yanhui

Classifications

• C04B7/425

  Acids or salts thereof · CPC title

• C21B2400/02

  Physical or chemical treatment of slags · CPC title

• C21B3/04 Primary

  Recovery of by-products, e.g. slag · CPC title

• C21C7/0087

  Treatment of slags covering the steel bath, e.g. for separating slag from the molten metal · CPC title

• C04B18/142

  Steelmaking slags, converter slags · CPC title